LEADER 01191nam0-22003011i-450- 001 990000082940403321 035 $a000008294 035 $aFED01000008294 035 $a(Aleph)000008294FED01 035 $a000008294 100 $a20011111d--------km-y0itay50------ba 101 0 $aita 105 $ay-------001yy 200 1 $aProgress in international research on thermodynamic and transport properties$epapers presented at Second symposium onthermophysical properties, Princeton university, Princeton, New Jersey, January 24-26, 1962$feditors Joseph F. Masi , Donald H. Tsai. 210 $aNew York$cThe American society of mechanical engineers$eNew York-London$cAcademic press$d1962 215 $a762 p.$cill.$d29 cm 610 0 $aTermodinamica$aCongressi$a1962 610 0 $aCongressi$aPrinceton$a1962 676 $a536.7 710 02$aSYMPOSIUM ON THERMOPHYSICAL PROPERTIES, 2., Princeton, 1962$05618 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990000082940403321 952 $a13 G 07 05$b24649$fFINBC 959 $aFINBC 996 $aProgress in international research on thermodynamic and transport properties$9110109 997 $aUNINA DB $aING01 LEADER 01153nam0 22002891i 450 001 UON00511041 005 20231205105457.993 010 $a978-95-433-6083-3 100 $a20230201d2009 |0itac50 ba 101 $abul$aCZE 102 $aBG 105 $a||||e ||||| 200 1 $a?e?ko-balgarski re?nik na sakratenite naimenovanija$fVioleta Miceva 210 $a[s.l.]$cStigmati$d2009 215 $a158 p.$d18 cm. 312 $aTitolo parallelo$9UON00511044 510 0$3UON00511044$a?esko-bulharský slovník zkratek 606 $aLingua bulgara$xAcronimi$xDizionari$3UONC100290$2FI 606 $aLingua ceca$xAcronimi$xDizionari$3UONC100291$2FI 676 $a491.803$cLINGUE SLAVE - DIZIONARI$v22 700 1$aMICEVA$bVioleta$3UONV288524$01590342 801 $aIT$bSOL$c20250516$gRICA 899 $aSIBA - SISTEMA BIBLIOTECARIO DI ATENEO$2UONSI 912 $aUON00511041 950 $aSIBA - SISTEMA BIBLIOTECARIO DI ATENEO$dSI S.C BULGARO 004 $eSI 40023 7 004 996 $a?e?ko-balgarski re?nik na sakratenite naimenovanija$93901521 997 $aUNIOR LEADER 03698nam 22006615 450 001 9910254057303321 005 20200704115054.0 010 $a3-319-03236-4 024 7 $a10.1007/978-3-319-03236-8 035 $a(CKB)3710000000492496 035 $a(EBL)4178146 035 $a(SSID)ssj0001584172 035 $a(PQKBManifestationID)16264569 035 $a(PQKBTitleCode)TC0001584172 035 $a(PQKBWorkID)14864741 035 $a(PQKB)11791328 035 $a(DE-He213)978-3-319-03236-8 035 $a(MiAaPQ)EBC4178146 035 $a(PPN)190536756 035 $a(EXLCZ)993710000000492496 100 $a20151016d2016 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 12$aA Novel Heme-Thiolate Peroxygenase AaeAPO and Its Implications for C-H Activation Chemistry /$fby Xiaoshi Wang 205 $a1st ed. 2016. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2016. 215 $a1 online resource (153 p.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $aDescription based upon print version of record. 311 $a3-319-03235-6 320 $aIncludes bibliographical references at the end of each chapters. 327 $aFrom the Contents: Hydrocarbon Oxygenation by Heme-Thiolate Enzymes -- Efficient and Selective Alkane Hydroxylation Reactions Catalyzed by the Fungal Peroxygenase AaeAPO -- Hydrocarbon Hydroxylations Catalyzed by AaeAPO: Evidence of Radical Intermediates and Kinetic Isotope Effects. 330 $aIn this thesis, Xiaoshi Wang investigates the function and mechanism of a newly discovered heme-thiolate peroxygenase, AaeAPO. This enzyme class comes from Agrocybe aegerita and is used in the conversion of inert hydrocarbons to alcohols. Xiaoshi's work focuses on an extracellular P450 enzyme which is not limited in its stability and lack of solubility and therefore is relevant for widespread industrial use. The author demonstrates that the peroxygenase catalyzes a wide range of reactions. In some cases the author even describes very difficult transformations in molecules that are highly inert. Her detailed investigations provide a mechanistic framework for how the peroxygenase catalyzes such a large number of reactions. A major highlight of this thesis is the identification of key short-lived intermediates in the catalytic cycle of the peroxygenase, using rapid kinetic and spectroscopic methods, as well as the elucidation of the thermodynamic properties of these high-energy intermediates. This work adds new insight into an important class of enzymes. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aChemistry, Organic 606 $aEnzymology 606 $aCatalysis 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 606 $aEnzymology$3https://scigraph.springernature.com/ontologies/product-market-codes/L14070 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 615 0$aChemistry, Organic. 615 0$aEnzymology. 615 0$aCatalysis. 615 14$aOrganic Chemistry. 615 24$aEnzymology. 615 24$aCatalysis. 676 $a612.1111 700 $aWang$b Xiaoshi$4aut$4http://id.loc.gov/vocabulary/relators/aut$01061405 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910254057303321 996 $aA Novel Heme-Thiolate Peroxygenase AaeAPO and Its Implications for C-H Activation Chemistry$92518743 997 $aUNINA