LEADER 04358nam 2200589 450 001 9910137223403321 005 20200520144314.0 010 $a1-118-75498-0 010 $a1-118-75495-6 010 $a1-118-75488-3 035 $a(CKB)3710000000521830 035 $a(EBL)4182965 035 $a(MiAaPQ)EBC4182965 035 $a(DLC) 2015025134 035 $a(Au-PeEL)EBL4182965 035 $a(CaPaEBR)ebr11125572 035 $a(CaONFJC)MIL878185 035 $a(OCoLC)932334514 035 $a(PPN)250378035 035 $a(EXLCZ)993710000000521830 100 $a20160105h20162016 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 00$aArene chemistry $ereaction mechanisms and methods for aromatic compounds /$fedited by Jacques Mortier 210 1$aHoboken, New Jersey :$cWiley,$d2016. 210 4$d©2016 215 $a1 online resource (990 p.) 300 $aIncludes index. 311 $a1-118-75201-5 320 $aIncludes bibliographical references and index. 327 $aTITLE PAGE ; COPYRIGHT PAGE ; CONTENTS; LIST OF CONTRIBUTORS; PREFACE; Part I Electrophilic Aromatic Substitution ; CHAPTER 1 ELECTROPHILIC AROMATIC SUBSTITUTION: MECHANISM ; 1.1 INTRODUCTION; 1.2 GENERAL ASPECTS; 1.3 ELECTROPHILES; 1.4 ARENE NUCLEOPHILES; 1.5 ?-COMPLEX INTERMEDIATES ; 1.6 ?-COMPLEX OR WHELAND INTERMEDIATES ; 1.7 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 2 FRIEDEL-CRAFTS ALKYLATION OF ARENES IN TOTAL SYNTHESIS ; 2.1 INTRODUCTION; 2.2 TOTAL SYNTHESIS INVOLVING INTERMOLECULAR FC ALKYLATIONS; 2.2.1 Synthesis of Coenzyme Q10 327 $a2.2.2 Total Synthesis of (±)-Brasiliquinone B 2.2.3 Synthesis of (2212;)-Podophyllotoxin ; 2.2.4 Synthesis of Puupehenol and Related Compounds; 2.2.5 Synthesis of (2212;)-Talaumidin ; 2.2.6 Total Synthesis of (±)-Schefferine ; 2.3 TOTAL SYNTHESIS INVOLVING INTRAMOLECULAR FC ALKYLATIONS; 2.3.1 C-C Bond Formation Leading to Homocyclic Rings ; 2.3.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.3.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.4 TOTAL SYNTHESIS THROUGH TANDEM AND CASCADE PROCESSES INVOLVING FC REACTIONS 327 $a2.4.1 C-C Bond Formation Leading to Homocyclic Rings 2.4.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.4.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.5 TOTAL SYNTHESIS INVOLVING ipso-FC REACTIONS ; 2.5.1 Synthesis of (S)-(2212;)-Xylopinine ; 2.5.2 Synthesis of Garcibracteatone; 2.6 SUMMARY AND OUTLOOK; 2.7 ACKNOWLEDGMENT; ABBREVIATIONS ; REFERENCES; CHAPTER 3 CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTIONS ; 3.1 INTRODUCTION AND HISTORICAL BACKGROUND; 3.2 CATALYTIC HOMOGENEOUS ACYLATIONS; 3.2.1 Metal Halides 327 $a3.2.2 Perfluoroalkanoic Acids, Perfluorosulfonic Acids, and Their (Metal) Derivatives 3.2.3 Miscellaneous; 3.3 CATALYTIC HETEROGENEOUS ACYLATIONS; 3.3.1 Zeolites; 3.3.2 Clays; 3.3.3 Metal Oxides; 3.3.4 Acid-Treated Metal Oxides ; 3.3.5 Heteropoly Acids (HPAs); 3.3.6 Nafion; 3.3.7 Miscellaneous; 3.4 DIRECT PHENOL ACYLATION; 3.5 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 4 THE USE OF QUANTUM CHEMISTRY FOR MECHANISTIC ANALYSES OF SEAr REACTIONS ; 4.1 INTRODUCTION; 4.1.1 Historical Overview of Early Quantum Chemistry Work 327 $a4.1.2 Current Mechanistic Understanding Based on Kinetic and Spectroscopic Studies 4.2 THE SEAr MECHANISM: QUANTUM CHEMICAL CHARACTERIZATION IN GAS PHASE AND SOLUTION; 4.2.1 Nitration and Nitrosation; 4.2.2 Halogenation; 4.2.3 Sulfonation; 4.2.4 Friedel-Crafts Alkylations and Acylations; 4.3 PREDICTION OF RELATIVE REACTIVITY AND REGIOSELECTIVITY BASED ON QUANTUM CHEMICAL DESCRIPTORS; 4.4 QUANTUM CHEMICAL REACTIVITY PREDICTION BASED ON MODELING OF TRANSITION STATES AND INTERMEDIATES; 4.4.1 Transition State Modeling; 4.4.2 The Reaction Intermediate or Sigma-Complex Approach 327 $a4.5 SUMMARY AND CONCLUSIONS 606 $aAromatic compounds 606 $aChemistry, Organic 615 0$aAromatic compounds. 615 0$aChemistry, Organic. 676 $a547/.61 702 $aMortier$b Jacques 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910137223403321 996 $aArene chemistry$91915493 997 $aUNINA LEADER 00932nam a2200253 i 4500 001 991003286949707536 008 080130s2003 it 00 0 ita d 020 $a8814107343 035 $ab13661322-39ule_inst 040 $aSet. 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