LEADER 04389nam 22006495 450 001 9911020413903321 005 20250812130244.0 010 $a3-031-90702-7 024 7 $a10.1007/978-3-031-90702-9 035 $a(CKB)40259099300041 035 $a(MiAaPQ)EBC32260215 035 $a(Au-PeEL)EBL32260215 035 $a(DE-He213)978-3-031-90702-9 035 $a(EXLCZ)9940259099300041 100 $a20250812d2025 u| 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aFrom Experimental Kinetic Data to Reaction Mechanisms /$fby Carlos Bravo-Diaz, Sonia Losada-Barreiro, José G. Santos, Margarita E. Aliaga 205 $a1st ed. 2025. 210 1$aCham :$cSpringer Nature Switzerland :$cImprint: Springer,$d2025. 215 $a1 online resource (330 pages) 225 1 $aPhysical Chemistry in Action,$x2197-4357 311 08$a3-031-90701-9 327 $aIntroduction -- Techniques and methods to monitor chemical reactions -- Basic Kinetic Concepts -- Rates of some complex reactions and simplification of reaction schemes: steady-state and pre-equilibrium approximations -- Reactions in solution -- Catalysis -- Modeling chemical reactivity in multiphasic systems: microemulsions and emulsions -- Analysis of Kinetic Data: Effects of Solution Composition -- Non-linear regression analyses. 330 $aThis textbook offers a deep dive into practical kinetics in solution, providing a comprehensive overview of the techniques and methods used to monitor chemical reactions. It addresses fundamental questions about reaction rates, rate laws, and the intricate dynamics of chemical processes. By connecting various experimental aspects required for kinetic and mechanistic research, it guides students on how to obtain, treat, and interpret experimental data to gain realistic mechanistic insights. Divided into nine chapters, the textbook begins with an introduction to the basic concepts of chemical kinetics and an experimental perspective on monitoring chemical reactions. Subsequent chapters cover complex reactions, offering insights into simplifying reaction schemes through steady-state and pre-equilibrium approximations. Special attention is given to reactions in solution, highlighting diffusion-controlled and activation-controlled reactions, as well as the role of catalysis. The authors provide expert analyses of chemical reactivity in multiphasic systems, such as microemulsions and emulsions, offering a detailed understanding of these complex environments. The textbook also focuses on the analysis of kinetic data, including the effects of solution composition. It explores non-linear regression analyses, residuals, dataset size, noise, fitting functions, and the limits of fitting algorithms. Additionally, it presents comparisons between fitting data and experimental data, providing readers with valuable insights. This textbook is an invaluable resource for upper-undergraduate and graduate students conducting research in reaction kinetics. It is also essential for researchers and practitioners in chemistry, particularly those interested in reaction kinetics and chemical reactivity. With contributions from leading experts, this volume is a must-read for anyone looking to advance their understanding of chemical kinetics. . 410 0$aPhysical Chemistry in Action,$x2197-4357 606 $aChemical kinetics 606 $aChemistry, Physical and theoretical 606 $aCatalysis 606 $aMaterials 606 $aReaction Kinetics 606 $aPhysical Chemistry 606 $aCatalysis 606 $aCatalytic Materials 615 0$aChemical kinetics. 615 0$aChemistry, Physical and theoretical. 615 0$aCatalysis. 615 0$aMaterials. 615 14$aReaction Kinetics. 615 24$aPhysical Chemistry. 615 24$aCatalysis. 615 24$aCatalytic Materials. 676 $a541.394 700 $aBravo Diaz$b Carlos$01840309 701 $aLosada-Barreiro$b Sonia$01840310 701 $aSantos$b José G$01840311 701 $aAliaga$b Margarita E$01840312 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911020413903321 996 $aFrom Experimental Kinetic Data to Reaction Mechanisms$94419857 997 $aUNINA