LEADER 05469nam 2200709Ia 450 001 9911020083703321 005 20200520144314.0 010 $a9786610366170 010 $a9781280366178 010 $a1280366176 010 $a9780470242452 010 $a0470242450 010 $a9780471458449 010 $a0471458449 010 $a9780471224457 010 $a0471224456 035 $a(CKB)111056485574462 035 $a(EBL)152114 035 $a(OCoLC)56137202 035 $a(SSID)ssj0000179638 035 $a(PQKBManifestationID)11154646 035 $a(PQKBTitleCode)TC0000179638 035 $a(PQKBWorkID)10138744 035 $a(PQKB)11639904 035 $a(MiAaPQ)EBC152114 035 $a(Perlego)2762265 035 $a(EXLCZ)99111056485574462 100 $a20000821d2001 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aInorganic and organometallic polymers /$fRonald D. Archer 210 $aNew York $cWiley-VCH$dc2001 215 $a1 online resource (261 p.) 225 1 $aSpecial topics in inorganic chemistry 300 $aDescription based upon print version of record. 311 08$a9780471241874 311 08$a0471241873 320 $aIncludes bibliographical references and index. 327 $aINORGANIC AND ORGANOMETALLIC POLYMERS; CONTENTS; Preface; 1 INORGANIC POLYMERS AND CLASSIFICATION SCHEMES; 1.1 Introduction; 1.1.1 What Is an Inorganic Polymer?; 1.2 Classifications by Connectivities; 1.2.1 Connectivities of 1; 1.2.2 Connectivities of 2; 1.2.3 Connectivities of 3; 1.2.4 Mixed Connectivities of 2 and 3; 1.2.5 Connectivities of 4; 1.2.6 Mixed Connectivities of 3 and 4; 1.2.7 Connectivities of 6; 1.2.8 Mixed Connectivities of 4 and 6; 1.2.9 Connectivities of 8; 1.3 Classifications by Dimensionality; 1.3.1 1-D Polymeric Structures; 1.3.2 2-D Polymeric Structures 327 $a1.3.3 3-D Polymeric Structures1.4 The Metal/Backbone Classification of Metal-Containing Polymers; 1.4.1 Type I Metal-Backbone Polymers; 1.4.2 Type II Metal-Enmeshed Polymers; 1.4.3 Type III Anchored Metal Polymers; 1.5 Linear Inorganic Polymers-The Thrust of this Book; 1.5.1 Metal-Containing Polymers; 1.5.2 Main Group Inorganic Polymers; References; Exercises; 2 INORGANIC POLYMER SYNTHESES; 2.1 Step-Growth Syntheses; 2.1.1 Step Condensation Synthesis Generalities; 2.1.2 Step Condensation Syntheses of Metal-Containing Polymers; 2.1.3 Main Group Step Condensation Polymer Syntheses 327 $a2.1.4 Step Addition Syntheses2.2 Chain Polymerizations; 2.2.1 Radical Polymerizations; 2.2.2 Cationic Polymerizations; 2.2.3 Anionic Polymerizations; 2.3 Ring-Opening Polymerizations; 2.3.1 Metal-Coordination ROP; 2.3.2 Organometallic ROP; 2.3.3 Main Group ROP; 2.4 Reductive Coupling and Other Redox Polymerization Reactions; 2.4.1 Reductive Coupling; 2.4.2 Oxidative Addition Polymerizations; 2.5 Condensation (Desolvation) Oligomerizations/Polymerizations; 2.5.1 Cationic Aggregations; 2.5.2 Anionic Aggregations; 2.5.3 Desolvation at Elevated Temperature; 2.5.4 Solvolysis-Desolvation Reactions 327 $a2.6 Miscellaneous Synthesis Comments2.6.1 Solubility; 2.6.2 Telechelic Polymers; 2.6.3 Catalyzed Dehydrogenation Reactions; References; Exercises; 3 INORGANIC POLYMER CHARACTERIZATION; 3.1 Average Molecular Masses and Degrees of Polymerization; 3.2 Methods of Characterizing Average Molecular Masses; 3.2.1 Gel Permeation Chromatography; 3.2.2 Viscosity; 3.2.3 Universal Calibration; 3.2.4 Light Scattering for Absolute Molecular Mass and Size Measurements; 3.2.5 Colligative Properties (Vapor Pressure Lowering, Boiling Point Elevation, Melting Point Lowering, and Osmotic Pressure) 327 $a3.2.6 End-Group Analyses3.2.7 Mass Spectroscopy; 3.2.8 Ultracentrifugation; 3.3 Determinations of Thermal Parameters; 3.3.1 Glass Transition Temperature Measurements; 3.3.2 Other Thermal Parameters; 3.4 Spectroscopic Characterizations Specific to Inorganic Polymers; 3.4.1 Nuclear Magnetic Resonance Spectroscopy; 3.4.2 Electron Paramagnetic Resonance Spectroscopy; 3.4.3 Electronic Spectroscopies; 3.4.4 Vibrational Spectroscopies; 3.4.5 Mo?ssbauer Spectroscopy; 3.4.6 Other Spectroscopic Methods; 3.5 Viscoelasticity Measurements; 3.6 Crystallization Characterization; 3.6.1 Birefringent Microscopy 327 $a3.6.2 Wide-Angle X-Ray Scattering 330 $aA balanced and concise coverage of inorganic polymers Inorganic polymers contain elements other than carbon as part of their principal backbone structure and are known to exhibit a wide range of composition and structure. Emphasizing physical properties, chemical synthesis, and characterization of inorganic polymers, Inorganic and Organometallic Polymers presents valuable and informative coverage of the field. With numerous examples of real-world practical applications and end-of-chapter exercises, Inorganic and Organometallic Polymers is suitable for use as a text in special topics 410 0$aSpecial topics in inorganic chemistry. 606 $aInorganic polymers 606 $aOrganometallic polymers 615 0$aInorganic polymers. 615 0$aOrganometallic polymers. 676 $a541.2/254 700 $aArcher$b Ronald D$0128809 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911020083703321 996 $aInorganic and organometallic polymers$94417699 997 $aUNINA