LEADER 05256nam 2200673Ia 450 001 9911019993503321 005 20200520144314.0 010 $a9786612118500 010 $a9781282118508 010 $a1282118501 010 $a9783527627332 010 $a3527627332 035 $a(CKB)1000000000774668 035 $a(EBL)481887 035 $a(OCoLC)413003441 035 $a(SSID)ssj0000204230 035 $a(PQKBManifestationID)11172511 035 $a(PQKBTitleCode)TC0000204230 035 $a(PQKBWorkID)10196082 035 $a(PQKB)10724196 035 $a(MiAaPQ)EBC481887 035 $a(PPN)152499741 035 $a(Perlego)2771632 035 $a(EXLCZ)991000000000774668 100 $a20081027d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern arylation methods /$fedited by Lutz Ackermann 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (563 p.) 300 $aDescription based upon print version of record. 311 08$a9783527627325 311 08$a3527627324 311 08$a9783527319374 311 08$a3527319379 320 $aIncludes bibliographical references and index. 327 $aModern Arylation Methods; Contents; Preface; List of Contributors; 1 Arylation Reactions: A Historical Perspective; 1.1 Structure and Bonding of Benzene; 1.2 Syntheses of Substituted (Hetero)Arenes, and the Contents of this Book; Abbreviations; References; 2 Metal-Catalyzed Coupling Reactions with Aryl Chlorides, Tosylates and Fluorides; 2.1 Introduction; 2.2 Coupling Reactions of Aryl Chlorides; 2.2.1 Nickel-Catalyzed Cross-Couplings of Aryl Chlorides; 2.2.2 Palladium-Catalyzed Cross-Coupling Reactions; 2.2.2.1 Suzuki Reaction; 2.2.2.2 Stille Reaction; 2.2.2.3 Hiyama Coupling 327 $a2.2.2.4 Negishi Coupling2.2.2.5 Kumada Coupling; 2.3 Coupling Reactions of Aryl Fluorides; 2.4 Coupling Reactions of Aryl Tosylates; 2.5 Conclusions; Abbreviations; References; 3 Palladium-Catalyzed Arylations of Amines and ?-C-H Acidic Compounds; 3.1 Introduction; 3.2 Palladium-Catalyzed Arylations of Amines; 3.2.1 Historical Development; 3.2.2 Catalytic Systems; 3.2.2.1 Palladium Sources; 3.2.2.2 Ligands; 3.2.2.3 Bases; 3.2.2.4 Solvents; 3.2.3 Aryl Halides; 3.2.4 Arylsulfonic Acid Esters; 3.2.5 Heteroaromatic Electrophiles; 3.2.6 Amines as Nucleophiles 327 $a3.2.7 Amine Derivatives as Nucleophiles3.2.8 Applications; 3.2.9 Mechanistic Aspects; 3.2.10 Chirality; 3.3 Palladium-Catalyzed Arylations of ?-C-H Acidic Compounds; 3.3.1 Historical Development; 3.3.2 Catalytic Systems; 3.3.3 ?-Arylations of Esters; 3.3.4 ?-Arylations of Malonates and ?-Cyano Esters; 3.3.5 ?-Arylations of Ketones; 3.3.6 ?-Arylations of Amides; 3.3.7 ?-Arylations of Nitriles; 3.4 Summary and Conclusions; Abbreviations; References; 4 Copper-Catalyzed Arylations of Amines and Alcohols with Boron-Based Arylating Reagents; 4.1 Introduction 327 $a4.2 Discovery and Development of a New O-H Bond Arylation Reaction: From Stoichiometric to Catalytic in Copper4.3 Mechanistic Considerations; 4.4 Miscellaneous Applications; 4.4.1 Additional Applications with ArB(OH)(2); 4.4.2 Alternatives to ArB(OH)(2); 4.4.3 Alternatives to Phenols; 4.5 Development of a New N-H Bond Arylation Reaction; 4.5.1 Stoichiometric in Copper; 4.5.2 Alternatives to Boronic Acids; 4.6 Development of a New N-H Bond Arylation Reaction: Catalytic in Copper; 4.6.1 Proposed Mechanism; 4.6.2 Additional Important Non-N-H Arylation Examples; 4.7 Summary and Conclusions 327 $aAbbreviationsReferences; 5 Metal-Catalyzed Arylations of Nonactivated Alkyl (Pseudo)Halides via Cross-Coupling Reactions; 5.1 Introduction; 5.2 Palladium-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.3 Nickel-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.4 Iron-Catalyzed Arylations of Alkyl (Pseudo)Halides; 5.5 Copper- and Cobalt-Catalyzed Arylations of Alkyl (Pseudo)Halides; Abbreviations; References; 6 Arylation Reactions of Alkynes: The Sonogashira Reaction; 6.1 Introduction; 6.2 Palladium-Catalyzed Reactions: Ligands and Reaction Protocols; 6.2.1 Phosphine-Based Ligands 327 $a6.2.1.1 Copper-Free Catalytic Systems 330 $aToday, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information 606 $aArylation 606 $aOrganic compounds$xSynthesis 615 0$aArylation. 615 0$aOrganic compounds$xSynthesis. 676 $a541.39 701 $aAckermann$b Lutz$01837868 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019993503321 996 $aModern arylation methods$94416710 997 $aUNINA LEADER 03501nam 2200721Ia 450 001 9910970919603321 005 20251117005351.0 010 $a1-136-54096-2 010 $a1-136-54097-0 010 $a1-282-72654-4 010 $a9786612726545 010 $a1-84977-517-6 024 7 $a10.4324/9781849775175 035 $a(CKB)2670000000032744 035 $a(EBL)554803 035 $a(OCoLC)651601620 035 $a(SSID)ssj0000425330 035 $a(PQKBManifestationID)11322967 035 $a(PQKBTitleCode)TC0000425330 035 $a(PQKBWorkID)10364402 035 $a(PQKB)11630355 035 $a(OCoLC)659730279 035 $a(MiAaPQ)EBC554803 035 $a(Au-PeEL)EBL554803 035 $a(CaPaEBR)ebr10408544 035 $a(CaONFJC)MIL272654 035 $a(OCoLC)659732168 035 $a(EXLCZ)992670000000032744 100 $a20100121d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe placemakers' guide to building community /$fNabeel Hamdi 205 $a1st ed. 210 $aLondon ;$aSterling, VA $cEarthscan$d2010 215 $a1 online resource (273 p.) 225 0 $aTools for community planning The placemakers' guide to building community 300 $aDescription based upon print version of record. 311 08$a1-84407-803-5 311 08$a1-84407-802-7 320 $aIncludes bibliographical references and index. 327 $aCover; The Placemaker's Guide to Building Community; Copyright; Contents; Acknowledgements; Acronyms and Abbreviations; Prologue; 1. The Evolution of Development and the Placemaker's Tools; Part I: Place, Time and Clutter: Learning from Practice Reflection: Listening to Communicate; 2. The Bad, the Good and the Ugly; 3. Profiling Vulnerability; Part II: Placemaking and the Architecture of Opportunity Reflection: Getting Answers to Questions You Don't Ask - Anshu Sharma; Introduction to Part II; 4. Toolkits; 5. Knowledge; 6. Participation in Practice 327 $a7. Interventions: Site Plans and House Plans, Buffaloes and MushroomsPart III: Placemakers: Responsible Practice and the Question of Scale Reflection: The Invisible Stakeholder - Charles Parrack; Introduction to Part III; 8. PEAS and the Sociable Side of Practice; 9. Reasoning to Scale; 10. Targeting Constraints; 11. Learning and Communication; 12. Reducing Dependency, Cultivating Ownership; 13. Building Livelihoods; Part IV: Teaching Reflection: The Mess of Practice - Rumana Kabir; 14. The Interventions Studio; 15. The Placemaker's Code; Notes and References; Index 330 8 $aThis is a guide to placemaking, packed with practical skills and tools that architects, planners, urban designers and other built environment specialists need in order to engage effectively with development work in any context. 606 $aCommunity development$zDeveloping countries 606 $aEconomic development$zDeveloping countries 606 $aHuman settlements$zDeveloping countries 606 $aCity planning$zDeveloping countries 615 0$aCommunity development 615 0$aEconomic development 615 0$aHuman settlements 615 0$aCity planning 676 $a720.1/03 700 $aHamdi$b Nabeel$0123564 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910970919603321 996 $aThe placemakers' guide to building community$94494617 997 $aUNINA