LEADER 05524nam 2200745Ia 450 001 9911019987203321 005 20200520144314.0 010 $a9786610520237 010 $a9781280520235 010 $a128052023X 010 $a9783527605088 010 $a3527605088 010 $a9783527601684 010 $a3527601686 035 $a(CKB)1000000000019224 035 $a(EBL)482160 035 $a(OCoLC)70044093 035 $a(SSID)ssj0000254850 035 $a(PQKBManifestationID)11226404 035 $a(PQKBTitleCode)TC0000254850 035 $a(PQKBWorkID)10211385 035 $a(PQKB)11733074 035 $a(MiAaPQ)EBC482160 035 $a(Perlego)2776861 035 $a(EXLCZ)991000000000019224 100 $a20010917d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSynthetic metal-containing polymers /$fIan Manners 210 $aWeinheim ;$aCambridge $cWiley-VCH$dc2004 215 $a1 online resource (291 p.) 300 $aDescription based upon print version of record. 311 08$a9783527294633 311 08$a3527294635 320 $aIncludes bibiographical references and index. 327 $aSynthetic Metal-Containing Polymers; Preface; Contents; Abbreviations; 1 Introduction; 1.1 Metal-Containing Polymers; 1.2 Fundamental Characteristics of Polymeric Materials; 1.2.1 Polymer Molecular Weights; 1.2.2 Amorphous, Crystalline, and Liquid-Crystalline Polymers: Thermal Transitions; 1.2.3 Polymers versus Oligomers: Why are High Molecular Weights Desirable?; 1.2.4 Polymer Solubility; 1.2.5 Block Copolymers; 1.2.6 Dendrimers and Hyperbranched Polymers; 1.2.7 Electrically Conducting Polymers; 1.3 Motivations for the Incorporation of Metals into Polymer Structures 327 $a1.3.1 Conformational, Mechanical, and Morphological Characteristics1.3.2 Precursors to Ceramics; 1.3.3 Magnetic, Redox, Electronic, and Optical Properties; 1.3.4 Catalysis and Bioactivity; 1.3.5 Supramolecular Chemistry and the Development of Hierarchical Structures; 1.4 Historical Development of Metal-Based Polymer Science; 1.5 Synthetic Routes to Metal-Containing Polymers; 1.5.1 The Synthesis of Side-Chain Metal-Containing Polymers; 1.5.2 Main-Chain Metal-Containing Polymers; 1.5.2.1 Why are Transition Metals in the Polymer Main Chain Desirable? 327 $a1.5.2.2 The Synthesis of Main-Chain Metal-Containing Polymers1.5.2.2.1 Addition Polymerization; 1.5.2.2.2 Polycondensations; 1.5.2.2.3 Ring-Opening Polymerization (ROP); 1.6 References; 2 Side-Chain Metal-Containing Polymers; 2.1 Introduction; 2.2 Side-Chain Polymetallocene Homopolymers and Block Copolymers; 2.2.1 Organic Polymers with Metallocene Side Groups; 2.2.1.1 Poly(vinylferrocene); 2.2.1.2 Other Organic Polymers with Metallocene-Containing Side Groups; 2.2.2 Inorganic Polymers with Metallocene Side Groups; 2.2.2.1 Polyphosphazenes with Ferrocene- or Ruthenocene-Containing Side Groups 327 $a2.2.2.2 Polysilanes, Polysiloxanes, and Polycarbosilanes with Metallocene Side Groups2.3 Other Side-Chain Metallopolymers; 2.3.1 Polymers with ?-Coordinated Metals; 2.3.2 Polymers with Pendant Polypyridyl Complexes; 2.3.3 Polymers with Other Pendant Metal-Containing Units, Including the Area of Polymer-Supported Catalysts; 2.3.4 Block Copolymers with Pendant Metal-Containing Groups; 2.3.4.1 Approaches using Ring-Opening Metathesis Polymerization (ROMP); 2.3.4.2 Coordination to Pyridyl Substituents in Preformed Blocks; 2.3.4.3 Coordination to Other Substituents in Preformed Blocks 327 $a2.4 References3 Main-Chain Polymetallocenes with Short Spacer Groups; 3.1 Introduction; 3.2 Polymetallocenylenes and Polymetallocenes with Short Spacers Obtained by Condensation Routes; 3.2.1 Polymetallocenylenes; 3.2.2 Other Polymetallocenes with Short Spacers Obtained by Polycondensation Routes; 3.3 Ring-Opening Polymerization (ROP) of Strained Metallocenophanes; 3.3.1 Thermal ROP of Silicon-Bridged [1]Ferrocenophanes; 3.3.2 Thermal ROP of Other Strained Metallocenophanes; 3.3.3 Living Anionic ROP of Strained Metallocenophanes 327 $a3.3.4 Transition Metal-Catalyzed ROP of Strained Metallocenophanes 330 $aThe development of the field of synthetic metal-containing polymers - where metal atoms form an integral part of the main chain or side group structure of a polymer - aims to create new materials which combine the processability of organic polymers with the physical or chemical characteristics associated with the metallic element or complex. This book covers the major developments in the synthesis, properties, and applications of synthetic metal-containing macromolecules, and includes chapters on the preparation and characterization of metal-containing polymers, metallocene-based polymers, rig 606 $aCopolymers$xAnalysis 606 $aMetal-filled plastics$xAnalysis 606 $aMetallic composites 606 $aPolymeric composites 606 $aPolymerization$xAnalysis 615 0$aCopolymers$xAnalysis. 615 0$aMetal-filled plastics$xAnalysis. 615 0$aMetallic composites. 615 0$aPolymeric composites. 615 0$aPolymerization$xAnalysis. 676 $a547.7 676 $a620.192 700 $aManners$b Ian$f1961-$01838240 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019987203321 996 $aSynthetic metal-containing polymers$94417189 997 $aUNINA