LEADER 05427nam 2200709 a 450 001 9911019926603321 005 20200520144314.0 010 $a9786611940119 010 $a9781281940117 010 $a1281940119 010 $a9780470723425 010 $a0470723424 010 $a9780470723418 010 $a0470723416 035 $a(CKB)1000000000551018 035 $a(EBL)366783 035 $a(OCoLC)298944860 035 $a(SSID)ssj0000155884 035 $a(PQKBManifestationID)11149564 035 $a(PQKBTitleCode)TC0000155884 035 $a(PQKBWorkID)10122161 035 $a(PQKB)11010998 035 $a(MiAaPQ)EBC366783 035 $a(Perlego)2767998 035 $a(EXLCZ)991000000000551018 100 $a20080623d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFlash chemistry $efast organic synthesis in microsystems /$fJun-ichi Yoshida 210 $aHoboken, N.J. $cWiley$d2008 215 $a1 online resource (248 p.) 300 $aDescription based upon print version of record. 311 08$a9780470035863 311 08$a0470035862 320 $aIncludes bibliographical references and index. 327 $aFlash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase 327 $a2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 327 $a5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 327 $a6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 327 $a7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 327 $a8 Applications of Flash Chemistry in Organic Synthesis 330 $aHave you ever wished you could speed up your organic syntheses without losing control of the reaction? Flash Chemistry is a new concept which offers an integrated scheme for fast, controlled organic synthesis. It brings together the generation of highly reactive species and their reactions in Microsystems to enable highly controlled organic syntheses on a preparative scale in timescales of a few seconds or less. Flash Chemistry: Fast Organic Synthesis in microsystems is the first book to describe this exciting new technique, with chapters covering:an introduction to f 606 $aOrganic compounds$xSynthesis 606 $aIntermediates (Chemistry) 606 $aMicroreactors 606 $aOrganic reaction mechanisms 615 0$aOrganic compounds$xSynthesis. 615 0$aIntermediates (Chemistry) 615 0$aMicroreactors. 615 0$aOrganic reaction mechanisms. 676 $a547/.2 700 $aYoshida$b Junichi$f1952-$0855535 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019926603321 996 $aFlash chemistry$94421516 997 $aUNINA LEADER 03726oam 2200541Mu 450 001 9910954003703321 005 20251116172653.0 010 $a1-351-72210-7 010 $a1-351-72211-5 010 $a1-315-18136-3 035 $a(CKB)4100000009965789 035 $a(MiAaPQ)EBC5992836 035 $a(OCoLC)1130901332 035 $a(OCoLC-P)1130901332 035 $a(FlBoTFG)9781315181363 035 $a(EXLCZ)994100000009965789 100 $a20191214d2020 uy 0 101 0 $aeng 135 $aurnn|---|nn|n 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aAdvanced Studies in Multi-Criteria Decision Making 205 $a1st ed. 210 $aMilton $cCRC Press LLC$d2020 215 $a1 online resource (275 pages) 225 0 $aSeries in Operations Research 300 $aDescription based upon print version of record. 300 $aChapter 11: Analyzing the Relationship between Human Development and Competitiveness Using DEA and Cluster AnalysisINDEX 311 08$a1-138-74388-7 327 $aCover; Half Title; Series Page; Title Page; Copyright Page; Table of Contents; Foreword; Preface; Editors; Contributors; Chapter 1: Implications of World Mega Trends for MCDM Research; Chapter 2: MCDA/M in Telecommunication Networks: Challenges and Trends; Chapter 3: SISTI: A Multicriteria Approach to Structure Complex Decision Problems; Chapter 4: Applying Intangible Criteria in Multiple-Criteria Optimization Problems: Challenges and Solutions; Chapter 5: Some Methods and Algorithms for Constructing Smart-City Rankings 327 $aChapter 6: Agricultural Supply Chains Prioritization for Development of Affected Areas by the Colombian ConflictChapter 7: Decision Making and Robust Optimization for Medicines Shortages in Pharmaceutical Supply Chains; Chapter 8: Using Spatial Decision Models for Rank Ordering Chocolates; Chapter 9: Multi-Criteria Decision Planning with Anticipatory Networks to Ensuring the Sustainability of a Digital Knowledge Platform; Chapter 10: A Robust Approach for Course of Action Comparison and Selection in Operation Planning Process 330 $aWith contributions from some of the top academics and scientists in the field, Advanced Studies in Multi-Criteria Decision Making presents an updated view of the landscape of Decision Sciences, current research topics, the interaction with other sciences and fields, as well as the prospects and challenges at an international level. Given that Decision Sciences are recognized today as indispensable for confronting the major societal challenges in science and technology, this book would be of interest to decision-makers, managers, and researchers from academia, and industrial/services companies that would like a fresh insight into MCDM. Features Integrates a wide range of scientific fields with a general reader approach, including applied researchers from the social, business, enterprise sciences Suitable for academics and professionals Presents a broad coverage of MCDM tools either in industry or in services companies and systems Provides a fresh overview on MCDM studies promoted by prestigious R&D institutions 606 $aDecision making 606 $aOperations research 615 0$aDecision making. 615 0$aOperations research. 676 $a658.403 701 $aBen Amor$b Sarah$01875163 701 $aMiranda$b Joa?o Luis de$01875164 701 $aAktas?$b Emel$01740411 701 $aAlmeida$b Adiel Teixeira de$01253350 801 0$bOCoLC-P 801 1$bOCoLC-P 906 $aBOOK 912 $a9910954003703321 996 $aAdvanced Studies in Multi-Criteria Decision Making$94486101 997 $aUNINA