LEADER 05356nam 2200685 a 450 001 9911019877103321 005 20200520144314.0 010 $a9783527647866 010 $a3527647864 010 $a9781299157262 010 $a1299157262 010 $a9783527647897 010 $a3527647899 010 $a9783527647880 010 $a3527647880 035 $a(CKB)2670000000328173 035 $a(EBL)1120421 035 $a(SSID)ssj0000904862 035 $a(PQKBManifestationID)11530055 035 $a(PQKBTitleCode)TC0000904862 035 $a(PQKBWorkID)10921479 035 $a(PQKB)10286281 035 $a(MiAaPQ)EBC1120421 035 $a(PPN)198218370 035 $a(OCoLC)826129606 035 $a(Perlego)1001826 035 $a(EXLCZ)992670000000328173 100 $a20130226d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aOrdered mesoporous materials /$fDongyuan Zhao, Ying Wan, and Wuzong Zhou 210 $aWeinheim $cWiley-VCH Verlag GmbH & Co. KGaA$d2013 215 $a1 online resource (542 p.) 300 $aDescription based upon print version of record. 311 08$a9783527326358 311 08$a3527326359 320 $aIncludes bibliographical references and index. 327 $aRelated Titles; Title page; Copyright page; Contents; Preface; Abbreviations; 1: Introduction; References; 2: Synthesis Approach of Mesoporous Molecular Sieves; 2.1 Synthesis; 2.2 Hydrothermal Synthesis; 2.2.1 Surfactant; 2.2.2 Inorganic Precursor; 2.2.3 Synthesis Temperature; 2.2.4 Synthetic Media; 2.2.5 Hydrothermal Treatment; 2.2.6 Formation Rate; 2.2.7 Separation and Drying; 2.3 Removal of Template; 2.3.1 Calcination; 2.3.2 Extraction; 2.3.3 Supercritical Fluid Extraction; 2.3.4 Microwave Irradiation; 2.3.5 Ultraviolet Irradiation; 2.3.6 Microwave Digestion 327 $a2.3.7 Oxidation of Ammonium Perchlorate2.4 Basic Synthesis; 2.5 Acidic Synthesis; 2.6 Nonaqueous Syntheses; 2.7 Postsynthesis Treatment; 2.7.1 Hydrothermal Treatment; 2.7.2 Secondary Synthesis; 2.7.3 Recrystallization; 2.8 Stability of Mesoporous Materials; 2.8.1 Thermal Stability; 2.8.2 Hydrothermal Stability; 2.8.3 Mechanical Stability; 2.9 Pore-Size Control; References; 3: Mechanisms for Formation of Mesoporous Materials; 3.1 Introduction; 3.2 Synthesis Pathways; 3.3 Mesophase Tailoring; 3.3.1 Micellar Mesostructure; 3.3.2 Critical Micelle Concentration; 3.3.3 The Packing Parameter 327 $a3.3.4 The Hydrophilic/Hydrophobic Volume Ratio3.3.5 Surfactant Phase Diagram; 3.3.6 "Acid-Base" Route; 3.4 Hard-Templating Approach; 3.4.1 Precursor; 3.4.2 Conversion of Precursors; 3.4.3 The Influence of the Template Structure; 3.4.4 Replicated Mesoporous Carbon as a Hard Template; References; 4: Structural Characterization Methods; 4.1 XRD; 4.1.1 Basic Principles of XRD; 4.1.2 XRD Measurement; 4.1.3 XRD Pattern Analysis; 4.1.4 SAXS; 4.2 Electron Microscopy; 4.2.1 TEM; 4.2.2 SAED; 4.2.3 SEM; 4.2.4 EDX; 4.2.5 STEM; 4.3 NMR; 4.4 Physical Sorption; 4.4.1 Basic Principles 327 $a4.4.2 Pore-Size Calculation4.4.3 Window-Size Calculation for Cavity-Like Pores; 4.4.4 Detection of Micropores and Mesopores; 4.4.5 Other Probes; References; 5: Representative Mesoporous Silica Molecular Sieves; 5.1 D Mesostructures; 5.1.1 MCM-41; 5.1.2 SBA-15; 5.1.3 Other 2D Phases; 5.2 3D Hexagonal Phases; 5.2.1 SBA-2; 5.2.2 SBA-12; 5.2.3 IBN-9; 5.3 Cubic Phases; 5.3.1 MCM-48, FDU-5 and KIT-6; 5.3.2 SBA-1 and SBA-6; 5.3.3 SBA-16; 5.3.4 FDU-1; 5.3.5 FDU-2; 5.3.6 FDU-12 and KIT-5; 5.3.7 SBA-11; 5.3.8 AMS-8 and AMS-10; 5.4 Disordered Mesostructures; 5.4.1 HMS and MSU; 5.4.2 KIT-1; 5.4.3 TUD-1 327 $aReferences6: Doping in Mesoporous Molecular Sieves; 6.1 Aluminum Doping; 6.2 Boron Doping; 6.3 Gallium and Indium Doping; 6.4 Germanium and Tin Doping; 6.5 Transition-Metal Doping; 6.5.1 Titanium and Zirconium Doping; 6.5.2 Vanadium and Niobium Doping; 6.5.3 Chromium and Molybdenum Doping; 6.5.4 Manganese Doping; 6.5.5 Iron and Ruthenium Doping; 6.5.6 Cobalt Doping; 6.5.7 Copper and Zinc Doping; 6.5.8 Hybrid Metal Doping; References; 7: Morphology Control; 7.1 The Methods and Techniques; 7.2 Typical Morphologies; 7.2.1 Fibers and Rods; 7.2.2 Thin Films; 7.2.3 Monoliths; 7.2.4 Spheres 327 $a7.2.5 Single Crystals 330 $aThe first book devoted to all aspects and types of mesoporous materials describes, in an in-depth and systematic manner, the step-by-step synthesis, synthesis mechanism, characterization, morphology control, hybridization, and applications of mesoporous molecular sieves. In so doing, it covers silicates, metal-doped silicates, non-silicates, and organic-inorganic hybrids. While the emphasis is on synthesis, the leading expert authors also discuss characterization and applications ranging from catalysis and biochemistry to optics and the use of these materials as templates for nanomaterial 606 $aMesoporous materials 615 0$aMesoporous materials. 676 $a620.116 700 $aZhao$b Dongyuan$01640798 701 $aWan$b Ying$01595588 701 $aZhou$b Wuzong$01841067 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019877103321 996 $aOrdered mesoporous materials$94420678 997 $aUNINA