LEADER 05557nam 2200757Ia 450 001 9911019804503321 005 20200520144314.0 010 $a9786610286997 010 $a9781280286995 010 $a1280286997 010 $a9780470244456 010 $a0470244453 010 $a9780471773269 010 $a0471773263 010 $a9780471773252 010 $a0471773255 035 $a(CKB)1000000000355377 035 $a(EBL)242882 035 $a(SSID)ssj0000331753 035 $a(PQKBManifestationID)11295037 035 $a(PQKBTitleCode)TC0000331753 035 $a(PQKBWorkID)10331663 035 $a(PQKB)11089584 035 $a(MiAaPQ)EBC242882 035 $a(OCoLC)173155461 035 $a(Perlego)2770720 035 $a(EXLCZ)991000000000355377 100 $a20050804d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aNanoscale interactions of metal-containing polymers /$fedited by Alaa S. Abd-El-Aziz ... [et al.] 210 $aHoboken, NJ $cWiley-Interscience$dc2006 215 $a1 online resource (252 p.) 225 1 $aMacromolecules containing metal and metal-like elements,$x1545-438X ;$vv. 7 300 $aDescription based upon print version of record. 311 08$a9780471684404 311 08$a0471684406 320 $aIncludes bibliographical references (p. 198-220) and index. 327 $aMacromolecules Containing Metal and Metal-Like Elements Volume 7; Contributors; Contents; Preface; Series Preface; 1. Nanocluster Assemblies and Molecular Orbital Interactions in Macromolecule-Metal Complexes; I. Introduction; II. Methodology of Transition Metal Coordination in Polymeric Complexes; A. Polymeric Coordination Complexes with d-Block Salts that Exhibit an Increase in T(g); B. Chemical Bonding, Coordination, and Transition Metal Compatibilization; i. Ligand Field Stabilization Energy Description of the Enhancement in T(g) for Polymeric Complexes with Transition Metals 327 $aii. Energetic Ligand Field Models and the Methodology of Transition Metal CoordinationC. Well-Defined Low-Molecular-Weight Transition Metal Complexes that Increase T(g); D. Attractive Polymeric Ligands; E. Identifying Attractive Interactions via Hard and Soft Acids and Bases; F. Displacement of Weak Neutral Bases in the First-Shell Coordination Sphere by Stronger Bases; i. Anionic Ligands are the Last Ones that Should Be Displaced to the Second Shell; G. Complexes with the Same Local Symmetry Above and Below the Glass Transition; i. Complexes with Reduced Symmetry Above T(g) 327 $aH. Consideration of Interelectronic Repulsion and Ligand Field Splitting When There Is Ambiguity in the d-Electron ConfigurationIII. Jørgensen's Parametric Representation of Ligand Field Splitting and Interelectronic Repulsion; A. Polymeric Complexes with Enhanced Glass-Transition Temperatures; B. Polymeric Complexes with Reduced Glass-Transition Temperatures; C. Other Considerations; IV. Pseudo-Octahedral d(8) Nickel Complexes with Poly(4-vinylpyridine); A. Ligand Field Stabilization Energies; B. Coordination Crosslinks vs. Coordination Pendant Groups 327 $aC. Ligand Field Model of the Glass Transition in Macromolecule-Metal ComplexesD. Linear Least Squares Analysis of D(LFSE) via the Concentration Dependence of T(g) in P4VP/Ni(2+) Complexes, Subject to the Constraint that b 1; V. d(6) Molybdenum Carbonyl Complexes with Poly(vinylamine) that Exhibit Reduced Symmetry Above the Glass-Transition Temperature; A. Experimental Results; B. Ligand Field Splitting Parameters for Molybdenum Hexacarbonyl; C. Ligand Field Stabilization for Complexes of Molybdenum Hexacarbonyl and Poly(vinylamine) in the Glassy State 327 $aD. Quantum Mechanical Model Parameters and Trigonal Bipyramid 5-Coordinate d(6) Complexes of Molybdenum Hexacarbonyl and Poly(vinylamine) with D(3h) Symmetry Above T(g)E. Square Pyramid 5-Coordinate d(6) Complexes of Molybdenum Hexacarbonyl and Poly(vinylamine) with C(4v) Symmetry Above T(g); F. Pentagonal Planar 5-Coordinate d(6) Complexes of Molybdenum Hexacarbonyl and Poly(vinylamine) with D(5h) Symmetry Above T(g); G. Ligand Field Stabilization of 5-Coordinate d(6) Complexes of Molybdenum Hexacarbonyl and Poly(vinylamine) Above T(g) 327 $aVI. Cobalt, Nickel, and Ruthenium Complexes with Poly(4-vinylpyridine) and Poly(L-histidine) that Exhibit Reduced Symmetry in the Molten State 330 $aThis series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. This volume, seventh in the series, covers nanoscale interactions of metal-containing polymers. Example chapters include:* Nanoscale Clusters and Molecular Orbital Interactions in Macromolecular-Metal Complexes* Metal Oxide Clusters as Building Blocks for Inorganic-Organic Hybrid Polymers 410 0$aMacromolecules containing metal and metal-like elements ;$vv. 7. 606 $aOrganometallic polymers 606 $aNanostructured materials 606 $aMacromolecules 606 $aMetal complexes 615 0$aOrganometallic polymers. 615 0$aNanostructured materials. 615 0$aMacromolecules. 615 0$aMetal complexes. 676 $a547.7 701 $aAbd-El-Aziz$b Alaa S$01837986 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019804503321 996 $aNanoscale interactions of metal-containing polymers$94421032 997 $aUNINA