LEADER 01132nam0-22003371i-450- 001 990006946010403321 005 20160427102928.0 035 $a000694601 035 $aFED01000694601 035 $a(Aleph)000694601FED01 035 $a000694601 100 $a20010904d1950----km-y0itay50------ba 101 0 $ager 102 $aDE 105 $ay-------011yy 200 1 $aFestschrift für Julius von Gierke$ezu seinen goldenen Doctor-Jubiläum am 25. Oktober 1948$fdargenbracht von der Rechts- und Staatswissenscaftlichen Fakultät Göttingen$g[Günther Beitzke, Paul Bockelmann, Walter Bogs...et al.] 210 $aBerlin$cWalter De Gruyter$d1950 215 $a367 p.$d24 cm 702 1$aBeitzke,$bGünther 702 1$aBockelmann,$bPaul 702 1$aGierke,$bJulius Von 712 01$aGöttingen,$bRechts- und Staatswissenscaftlichen Fakultät 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990006946010403321 952 $aDPR 36-55$b030504$fDEC 952 $aONORANZE G 21$b32484$fFGBC 959 $aDEC 959 $aFGBC 996 $aFestschrift für Julius von Gierke$9701523 997 $aUNINA LEADER 11783nam 22006013 450 001 9911019731103321 005 20251116145142.0 010 $a9783527844470 010 $a3527844473 010 $a9783527844494 010 $a352784449X 035 $a(CKB)31073521300041 035 $a(MiAaPQ)EBC31227187 035 $a(Au-PeEL)EBL31227187 035 $a(Exl-AI)31227187 035 $a(Perlego)4367294 035 $a(OCoLC)1428260796 035 $a(EXLCZ)9931073521300041 100 $a20240328d2024 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aGreen Chemical Synthesis with Microwaves and Ultrasound 205 $a1st ed. 210 1$aNewark :$cJohn Wiley & Sons, Incorporated,$d2024. 210 4$d©2024. 215 $a1 online resource (409 pages) 311 08$a9783527352975 311 08$a352735297X 327 $aCover -- Title Page -- Copyright -- Contents -- About the Editors -- Preface -- Chapter 1 Ultrasound Irradiation: Fundamental Theory, Electromagnetic Spectrum, Important Properties, and Physical Principles -- 1.1 Introduction -- 1.2 Cavitation History -- 1.2.1 Basics of Cavitation -- 1.2.2 Types of Cavitation -- 1.3 Application of Ultrasound Irradiation -- 1.3.1 Sonoluminescence and Sonophotocatalysis -- 1.3.2 Industrial Cleaning -- 1.3.3 Material Processing -- 1.3.4 Chemical and Biological Reactions -- 1.4 Conclusion -- Acknowledgments -- References -- Chapter 2 Fundamental Theory of Electromagnetic Spectrum, Dielectric and Magnetic Properties, Molecular Rotation, and the Green Chemistry of Microwave Heating Equipment -- 2.1 Introduction -- 2.1.1 Historical Background -- 2.1.2 Green Chemistry Principles for Sustainable System -- 2.2 Fundamental Concepts of the Electromagnetic Spectrum Theory -- 2.3 Electrical, Dielectric, and Magnetic Properties in Microwave Irradiation -- 2.4 Microwave Irradiation Molecular Rotation -- 2.5 Fundamentals of Electromagnetic Theory in Microwave Irradiation -- 2.5.1 Electromagnetic Radiations and Microwave -- 2.5.2 Heating Mechanism of Microwave: Conventional Versus Microwave Heating -- 2.6 Physical Principles of Microwave Heating and Equipment -- 2.7 Green Chemistry Through Microwave Heating: Applications and Benefits -- 2.8 Conclusion -- References -- Chapter 3 Conventional Versus Green Chemical Transformation: MCRs, Solid Phase Reaction, Green Solvents, Microwave, and Ultrasound Irradiation -- 3.1 Introduction -- 3.2 A Brief Overview of Green Chemistry -- 3.2.1 Definition and Historical Background -- 3.2.2 Significance -- 3.3 Multicomponent Reactions -- 3.4 Solid Phase Reactions -- 3.5 Microwave Induced Synthesis -- 3.6 Ultrasound Induced Synthesis -- 3.7 Green Chemicals and Solvents. 327 $a3.8 Conclusions and Outlook -- References -- Chapter 4 Metal?Catalyzed Reactions Under Microwave and Ultrasound Irradiation -- 4.1 Ultrasonic Irradiation -- 4.1.1 Iron?Based Catalysts -- 4.1.2 Copper?Based Catalysts -- 4.1.2.1 Dihydropyrimidinones by Cu?Based Catalysts -- 4.1.2.2 Dihydroquinazolinones by Cu?Based Catalysts -- 4.1.3 Misalliances Metal?Based Catalysts -- 4.2 Microwave?Assisted Reactions -- 4.2.1 Solid Acid and Base Catalysts -- 4.2.1.1 Condensation Reactions -- 4.2.1.2 Cyclization Reactions -- 4.2.1.3 Multi?component Reactions -- 4.2.1.4 Friedel-Crafts Reactions -- 4.2.1.5 Reaction Involving Catalysts of Biological Origin -- 4.2.1.6 Reduction -- 4.2.1.7 Oxidation -- 4.2.1.8 Coupling Reactions -- 4.2.1.9 Micelliances Reactions -- 4.2.1.10 Click Chemistry -- 4.3 Conclusion -- Acknowledgments -- References -- Chapter 5 Microwave? and Ultrasonic?Assisted Coupling Reactions -- 5.1 Introduction -- 5.2 Microwave -- 5.2.1 Microwave?Assisted Coupling Reactions -- 5.2.2 Ultrasound?Assisted Coupling Reactions -- 5.3 Conclusion -- References -- Chapter 6 Synthesis of Heterocyclic Compounds Under Microwave Irradiation Using Name Reactions -- 6.1 Introduction -- 6.2 Classical Methods for Heterocyclic Synthesis Under Microwave Irradiation -- 6.2.1 Piloty-Robinson Pyrrole Synthesis -- 6.2.2 Clauson-Kaas Pyrrole Synthesis -- 6.2.3 Paal-Knorr Pyrrole Synthesis -- 6.2.4 Paal-Knorr Furan Synthesis -- 6.2.5 Paal-Knorr Thiophene Synthesis -- 6.2.6 Gewald Reaction -- 6.2.7 Fischer Indole Synthesis -- 6.2.8 Bischler-Möhlau Indole Synthesis -- 6.2.9 Hemetsberger-Knittel Indole Synthesis -- 6.2.10 Leimgruber-Batcho Indole Synthesis -- 6.2.11 Cadogan-Sundberg Indole Synthesis -- 6.2.12 Pechmann Pyrazole Synthesis -- 6.2.13 Debus-Radziszewski Reaction -- 6.2.14 van Leusen Imidazole Synthesis -- 6.2.15 van Leusen Oxazole Synthesis. 327 $a6.2.16 Robinson-Gabriel Reaction -- 6.2.17 Hantzsch Thiazole Synthesis -- 6.2.18 Einhorn-Brunner Reaction -- 6.2.19 Pellizzari Reaction -- 6.2.20 Huisgen Reaction -- 6.2.21 Finnegan Tetrazole Synthesis -- 6.2.22 Four?component Ugi?azide Reaction -- 6.2.23 Kröhnke Pyridine Synthesis -- 6.2.24 Bohlmann-Rahtz Pyridine Synthesis -- 6.2.25 Boger Reaction -- 6.2.26 Skraup Reaction -- 6.2.27 Gould-Jacobs Reaction -- 6.2.28 Friedländer Quinoline Synthesis -- 6.2.29 Povarov Reaction -- 6.3 Conclusion -- Acknowledgments -- References -- Chapter 7 Microwave? and Ultrasound?Assisted Enzymatic Reactions -- 7.1 Introduction -- 7.2 Influence Microwave Radiation on the Stability and Activity of Enzymes -- 7.3 Principle of Ultrasonic?Assisted Enzymolysis -- 7.4 Applications of Ultrasonic?Assisted Enzymolysis -- 7.4.1 Proteins and Other Plant Components Can Be Transformed and Extracted -- 7.4.2 Modification of Protein Functionality -- 7.4.3 Enhancement of Biological Activity -- 7.4.4 Ultrasonic?Assisted Acceleration of Hydrolysis Time -- 7.5 Enzymatic Reactions Supported by Ultrasound -- 7.5.1 Lipase -- 7.5.2 Protease -- 7.5.3 Polysaccharide Enzymes -- 7.6 Biodiesel Production via Ultrasound?Supported Transesterification -- 7.6.1 Homogenous Acid?Catalyzed Ultrasound?Assisted Transesterification -- 7.6.2 Transesterification with Ultrasound Assistance and Homogenous Base Catalysis -- 7.6.3 Heterogeneous Acid?Catalyzed Ultrasound?Assisted Transesterification -- 7.6.4 Heterogeneous Base?Catalyzed Ultrasound?Assisted Transesterification -- 7.6.5 Enzyme?Catalyzed Ultrasound?Assisted Transesterification -- 7.7 Conclusions -- Acknowledgments -- References -- Chapter 8 Microwave? and Ultrasound?Assisted Synthesis of Polymers -- 8.1 Introduction -- 8.2 Microwave?Assisted Synthesis of Polymers -- 8.3 Ultrasound?Assisted Synthesis of Polymers -- 8.4 Conclusion -- References. 327 $aChapter 9 Synthesis of Nanomaterials Under Microwave and Ultrasound Irradiation -- 9.1 Introduction -- 9.2 Synthesis of Metal Nanoparticles -- 9.3 Synthesis of Carbon Dots -- 9.4 Synthesis of Metal Oxides -- 9.5 Synthesis of Silicon Dioxide -- 9.6 Conclusion -- References -- Chapter 10 Microwave? and Ultrasound?Assisted Synthesis of Metal?Organic Frameworks (MOF) and Covalent Organic Frameworks (COF) -- 10.1 Introduction -- 10.2 Principles -- 10.2.1 Principles of Microwave Heating -- 10.2.2 Principle of Ultrasound?Assisted Techniques -- 10.2.3 Advantages and Disadvantages of Microwave? and Ultrasound?Assisted Techniques -- 10.3 MOF Synthesis by Microwave and Ultrasound Method -- 10.3.1 Microwave?Assisted Synthesis of MOF -- 10.3.2 Ultrasound?Assisted Synthesis of MOFs -- 10.4 Factors That Affect MOF Synthesis -- 10.4.1 Solvent -- 10.4.2 Temperature and pH -- 10.5 Application of MOF -- 10.6 COF Synthesis by Microwave and Ultrasound Method -- 10.6.1 Ultrasound?Assisted Synthesis of COFs -- 10.6.2 Microwave?Assisted Synthesis of COF -- 10.6.3 Structure of COF (2D and 3D) -- 10.7 Factors Affecting the COF Synthesis -- 10.8 Applications of COFs -- 10.9 Future Predictions -- 10.10 Summary -- Acknowledgments -- References -- Chapter 11 Solid Phase Synthesis Catalyzed by Microwave and Ultrasound Irradiation -- 11.1 Introduction -- 11.2 Wastewater Treatment -- 11.3 Biodiesel Production -- 11.4 Oxygen Reduction Reaction -- 11.5 Alcoholic Fuel Cells -- 11.6 Conclusion and Future Plans -- References -- Chapter 12 Comparative Studies on Thermal, Microwave?Assisted, and Ultrasound?Promoted Preparations -- 12.1 Introduction -- 12.1.1 Background on Preparative Techniques in Chemistry -- 12.1.2 Overview of Thermal, Microwave?Assisted, and Ultrasound?Promoted Preparations -- 12.1.3 Significance of Comparative Studies in Enhancing Synthetic Methodologies. 327 $a12.1.3.1 Optimization of Conditions -- 12.1.3.2 Efficiency Improvement -- 12.1.3.3 Methodological Advances -- 12.1.3.4 Sustainability and Green Chemistry -- 12.2 Fundamentals of Thermal, Microwave?Assisted, and Ultrasound?Assisted Reactions -- 12.2.1 Explanation of Thermal Reactions and Their Advantages and Limitations -- 12.2.2 Introduction to Microwave?Assisted Reactions and How They Differ from Traditional Method -- 12.2.3 Understanding the Principles and Mechanisms of Ultrasound?Promoted Reactions -- 12.3 Case Studies in Organic Synthesis -- 12.3.1 Examining Examples of Organic Reactions Performed Under Thermal Conditions -- 12.3.1.1 Esterification Reaction Under Thermal Conditions -- 12.3.1.2 Dehydration of Alcohols -- 12.3.1.3 Oxidation of Aldehydes to Carboxylic Acids Using Water -- 12.3.2 Case Studies Showcasing the Application of Microwave?Assisted Reactions -- 12.3.2.1 Microwave?Assisted C C Bond Formation -- 12.3.2.2 Microwave?Assisted Cyclization -- 12.3.2.3 Microwave?Assisted Dehydrogenation Reactions -- 12.3.2.4 Microwave?Assisted Organic Synthesis -- 12.3.3 Highlighting Successful Instances of Ultrasound?Promoted Organic Synthesis -- 12.3.3.1 Ultrasound?Promoted in Organic Synthesis -- 12.3.3.2 Ultrasound?Promoted Oxidations -- 12.3.3.3 Ultrasound?Promoted Esterification -- 12.3.3.4 Ultrasound?Promoted Cyclization -- 12.4 Scope and Limitations -- 12.4.1 Discussing the Applicability of Each Method to Different Reaction Types -- 12.4.2 Identifying the Limitations and Challenges Faced by Each Technique -- 12.4.3 Opportunities for Combining Approaches to Overcome Specific Limitations -- 12.5 Future Directions and Emerging Trends -- 12.5.1 Overview of Recent Advancements and Ongoing Research in Thermal, Microwave, and Ultrasound?Assisted Preparations -- 12.5.1.1 Food Processing Technologies. 327 $a12.5.1.2 Chemical Routes to Materials: Thermal Oxidation of Graphite for Graphene Preparation. 330 $aThis book, edited by Dakeshwar Kumar Verma, Chandrabhan Verma, and Paz Otero, delves into the application of microwave and ultrasound irradiation in green chemical synthesis. It explores how these technologies can improve the efficiency and environmental impact of chemical reactions. The book covers fundamental theories, contemporary trends, and practical applications, including the synthesis of heterocycles, polymers, and nanomaterials. It aims to provide insights into reducing energy consumption and minimizing hazardous waste in chemical processes. The intended audience includes researchers, scientists, and students in the field of chemistry and chemical engineering.$7Generated by AI. 606 $aGreen chemistry$7Generated by AI 606 $aMicrowave heating$7Generated by AI 615 0$aGreen chemistry 615 0$aMicrowave heating 676 $a660.0286 700 $aVerma$b Dakeshwar Kumar$01750922 701 $aVerma$b Chandrabhan$01837358 701 $aOtero$b Paz$01884825 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019731103321 996 $aGreen Chemical Synthesis with Microwaves and Ultrasound$94519508 997 $aUNINA