LEADER 05167nam 2200673Ia 450 001 9911019550903321 005 20200520144314.0 010 $a9786612022012 010 $a9781282022010 010 $a1282022016 010 $a9783527625468 010 $a3527625461 010 $a9783527625475 010 $a352762547X 035 $a(CKB)1000000000724717 035 $a(EBL)481631 035 $a(SSID)ssj0000096887 035 $a(PQKBManifestationID)11113119 035 $a(PQKBTitleCode)TC0000096887 035 $a(PQKBWorkID)10083081 035 $a(PQKB)11659861 035 $a(MiAaPQ)EBC481631 035 $a(OCoLC)412767799 035 $a(Perlego)2750303 035 $a(EXLCZ)991000000000724717 100 $a20080923d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aActivating unreactive substrates $ethe role of secondary interactions /$fedited by Carsten Bolm and F. Ekkehardt Hahn 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (483 p.) 300 $aDescription based upon print version of record. 311 08$a9783527318230 311 08$a3527318232 320 $aIncludes bibliographical references and index. 327 $aActivating Unreactive Substrates: The Role of Secondary Interactions; Contents; Preface; List of Contributors; 1 Chemistry of Metalated Container Molecules; 1.1 Introduction; 1.2 Metalated Container Molecules: A Brief Overview; 1.3 Metalated Container Molecules of Binucleating Supporting Ligands; 1.3.1 Synthesis; 1.3.2 Coordination Chemistry of Binucleating Supporting Ligands; 1.3.3 Effects of N-alkylation on the Molecular and Electronic Structures of the Complexes; 1.3.4 The Ligand Matrix as a Medium; 1.3.5 Variation, Coordination Modes and Activation of Coligands 327 $a1.3.6 Reactivity of the Complexes1.4 Conclusions; References; 2 The Chemistry of Superbasic Guanidines; 2.1 Properties of the Guanidine Functionality; 2.2 Design of Superbasic Proton Sponges; 2.3 Some Perspectives in Proton Sponge Chemistry; 2.4 Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations; 2.5 The Chemistry of Guanidine Copper Complexes; 2.6 The Chemistry of Guanidine Zinc Complexes; 2.7 Conclusions; References; 3 Iron Complexes and Dioxygen Activation; 3.1 Introduction; 3.2 Dinuclear Iron Peroxo Complexes; 3.3 Tripodal Tetradentate Ligands and Derivatives 327 $a3.3.1 Tmpa3.3.2 Uns-penp; 3.4 Mononuclear Iron Peroxo Complexes; 3.5 Mononuclear Iron Oxo Species; 3.6 Work in Progress; 3.7 Conclusions; References; 4 Tuning of Structures and Properties of Bispidine Complexes; 4.1 Introduction; 4.2 Jahn-Teller Isomerism with Copper(II) Bispidines; 4.3 Stabilization of High-spin Ferryl Complexes; 4.4 Jahn-Teller-distorted Cobalt(III) Complexes; 4.5 Conclusions; References; 5 Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis; 5.1 Introduction; 5.2 Phosphine Ligands 327 $a5.2.1 Cooperative Effects for Ligand Self-organization5.2.2 Phosphines with Pyrazole and Pyrimidine Substituents; 5.3 Nitrogen Donor Ligands Without Phosphorus Sites; 5.4 Conclusion; References; 6 Square-Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected; 6.1 Introduction; 6.2 Polyphosphine Ligands with Three and Four Coordinating Arms; 6.3 C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands; 6.4 Mechanistic Considerations; 6.5 Conclusion; References 327 $a7 Regioselective Catalytic Activity of Complexes with NH,NR-substituted Heterocyclic Carbene Ligands7.1 Introduction; 7.2 Concept of Regioselective Substrate Activation; 7.3 Synthesis of Complexes with NH,NR-stabilized NHC Ligands; 7.4 Preparation of Substrates for Catalytic Experiments; 7.5 Catalysis Experiments; 7.6 Conclusions and Summary; References; 8 Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-supramolecular Chemistry; 8.1 Introduction 327 $a8.2 Syntheses and Electronic Structures of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes 330 $aThe use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community.A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics. 606 $aCatalysis 606 $aActivation (Chemistry) 615 0$aCatalysis. 615 0$aActivation (Chemistry) 676 $a541.395 701 $aBolm$b Carsten$0542970 701 $aHahn$b F. Ekkehardt$01842606 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019550903321 996 $aActivating unreactive substrates$94422786 997 $aUNINA