LEADER 03657nam 22004573 450 001 9911019505503321 005 20231016084512.0 010 $a9783527839254 035 $a(MiAaPQ)EBC30786520 035 $a(CKB)28495738600041 035 $a(Au-PeEL)EBL30786520 035 $a(Exl-AI)30786520 035 $a(OCoLC)1405925999 035 $a(EXLCZ)9928495738600041 100 $a20231016d2023 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aCatalysis in Confined Frameworks $eSynthesis, Characterization, and Applications 205 $a1st ed. 210 1$aNewark :$cJohn Wiley & Sons, Incorporated,$d2023. 210 4$dİ2024. 215 $a1 online resource (499 pages) 311 08$a9783527350896 327 $aCover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Engineering of Metal Active Sites in MOFs -- 1.1 Metal Node Engineering -- 1.1.1 Frameworks with Intrinsically Active Metal Nodes -- 1.1.1.1 Metal?Organic Frameworks with Only One Metal -- 1.1.1.2 Metal?Organic Frameworks with more than One Metal in its Cluster -- 1.1.2 Introducing Defectivity as a Powerful Tool to Tune Metal?node Catalytic Properties in MOFs -- 1.1.3 Incorporating Metals to Already?Synthetized Metal?Organic Frameworks: Isolating the Catalytic Site -- 1.1.4 Metal Exchange -- 1.1.5 Attaching Metallic Units to the MOF -- 1.1.6 Grafting of Organometallic Complexes into the MOF Nodes -- 1.2 Ligand Engineering -- 1.2.1 Ligands as Active Metal Sites -- 1.2.1.1 Creating Metal Sites in the Organic Linkers. Types of Ligands -- 1.2.1.2 Cooperation Between Single?Metal Sites and Metalloligands -- 1.2.1.3 Ligand Accelerated Catalysis (LAC) -- 1.2.2 Introduction of Metals by Direct Synthesis -- 1.2.2.1 In?situ Metalation -- 1.2.2.2 Premetalated Linker -- 1.2.2.3 Postgrafting Metal Complexes -- 1.2.3 Introduction of Metals by Post?synthetic Modifications -- 1.2.3.1 Post?synthetic Exchange or Solvent?Assisted Linker Exchange (SALE) -- 1.2.3.2 Post?synthetic Metalation -- 1.3 Metal?Based Guest Pore Engineering -- 1.3.1 Encapsulation Methodologies in As?Made Metal?Organic Frameworks -- 1.3.1.1 Incipient Wetness Impregnation$7Generated by AI. 330 $aThis book, edited by Hermenegildo Garcia and Amarajothi, delves into the synthesis and applications of catalysis within confined frameworks, focusing particularly on metal-organic frameworks (MOFs) and other porous materials. It explores the engineering of metal active sites, porosity, and the use of mixed linkers in MOFs to enhance catalytic efficiency. The text covers various aspects such as the structure, chemical environment, and confinement effects on catalysis, providing insights into the mechanisms and applications in fields like oil refining and pollutant degradation. Intended for researchers and professionals in chemistry and materials science, it aims to present advanced methodologies and their practical applications in catalysis.$7Generated by AI. 606 $aMetal-organic frameworks$7Generated by AI 606 $aCatalysis$7Generated by AI 615 0$aMetal-organic frameworks 615 0$aCatalysis 676 $a541.395 700 $aGarcia$b Hermenegildo$01842789 701 $aDhakshinamoorthy$b Amarajothi$01842790 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 912 $a9911019505503321 996 $aCatalysis in Confined Frameworks$94423011 997 $aUNINA