LEADER 05215nam 2200625Ia 450 001 9911019484103321 005 20200520144314.0 010 $a1-280-52073-6 010 $a9786610520732 010 $a3-527-60383-2 010 $a3-527-60579-7 035 $a(CKB)1000000000376381 035 $a(EBL)482195 035 $a(OCoLC)68941580 035 $a(SSID)ssj0000240350 035 $a(PQKBManifestationID)11191355 035 $a(PQKBTitleCode)TC0000240350 035 $a(PQKBWorkID)10265805 035 $a(PQKB)10655801 035 $a(MiAaPQ)EBC482195 035 $a(EXLCZ)991000000000376381 100 $a20040618d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aRuthenium in organic synthesis /$fShun-Ichi Murahashi (Ed.) 210 $aWeinheim ;$a[Great Britain] $cWiley-VCH$dc2004 215 $a1 online resource (401 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30692-7 320 $aIncludes bibliographical references and index. 327 $aRuthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols 327 $a3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and ?-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations 327 $a4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion 327 $a5 Carbon-Carbon Bond Formation via ?-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of ?-Allylruthenium Complexes; 5.2.1 ?-Allylruthenium(II) Complexes; 5.2.2 ?-Allylruthenium(IV) Complexes; 5.2.3 ?-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (?-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via ?-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via ?-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via ?-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction 327 $a6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions 327 $a8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates 330 $aIn this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.From the contents:Introduction (S.-I. Murahashi)Hydrogenation and Transfer Hydrogenation (M. K 606 $aOrganometallic chemistry 606 $aOrganoruthenium compounds 606 $aRuthenium 615 0$aOrganometallic chemistry. 615 0$aOrganoruthenium compounds. 615 0$aRuthenium. 676 $a547.05632 701 $aMurahashi$b Shunichi$f1937-$01840048 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019484103321 996 $aRuthenium in organic synthesis$94419529 997 $aUNINA