LEADER 00745nam0-2200277---450- 001 990009999290403321 005 20150922124755.0 010 $a978-88-911-5720-1 035 $a000999929 035 $aFED01000999929 035 $a(Aleph)000999929FED01 035 $a000999929 100 $a20150922d2014----km-y0itay50------ba 101 0 $aita 102 $aIT 105 $ay-------001yy 200 1 $aCost of the war in the world globalized$fFrancesco Paolo Rosapepe 210 $aTricase$cYoucanprint$d2014 215 $a135 p.$d23 cm 700 1$aRosapepe,$bFrancesco Paolo 801 0$aIT$bUNINA$gREICAT$2UNIMARC 901 $aBK 912 $a990009999290403321 952 $aXI A 2841$b531/2015$fFSPBC 959 $aFSPBC 997 $aUNINA LEADER 00759nam0-22002651i-450- 001 990000151460403321 035 $a000015146 035 $aFED01000015146 035 $a(Aleph)000015146FED01 035 $a000015146 100 $a20011111d--------km-y0itay50------ba 101 0 $aita 105 $ay-------001yy 200 1 $aConsiderazioni sull'efficienza delle vele$fSalvatore Montuoro. 210 $aTrieste$cTecnica italiana$d1963 215 $a6 p.$cill.$d29 cm 300 $aEstr. da: "Tecnica italiana", anno 28., n. 5, maggio 1963 700 1$aMontuoro,$bSalvatore 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990000151460403321 952 $a13 MISC 522 65$b11043$fFINBC 959 $aFINBC 997 $aUNINA DB $aING01 LEADER 09996nam 22005653 450 001 9911019393103321 005 20240901090258.0 010 $a9783527842711 010 $a3527842713 010 $a9783527842704 010 $a3527842705 010 $a9783527842698 010 $a3527842691 035 $a(MiAaPQ)EBC31626302 035 $a(Au-PeEL)EBL31626302 035 $a(CKB)34512779000041 035 $a(Exl-AI)31626302 035 $a(Perlego)4532858 035 $a(EXLCZ)9934512779000041 100 $a20240901d2024 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aApplied Polyoxometalate-Based Electrocatalysis 205 $a1st ed. 210 1$aNewark :$cJohn Wiley & Sons, Incorporated,$d2024. 210 4$dİ2025. 215 $a1 online resource (381 pages) 311 08$a9783527352135 311 08$a3527352139 327 $aCover -- Title Page -- Copyright -- Contents -- Part I Fundamentals -- Chapter 1 Introduction to Polyoxometalates -- 1.1 Introduction -- 1.2 Polyoxometalate Structures -- 1.2.1 Synthetic Methodologies -- 1.2.2 Lindqvist Structure -- 1.2.3 Keggin Structure -- 1.2.4 Wells-Dawson Structure -- 1.2.5 Anderson-Evans Structure -- 1.2.6 Preyssler Structure -- 1.2.7 Other POM Structures -- 1.3 POM?based Composites and Materials -- 1.4 Conclusions -- References -- Chapter 2 Design and Strategies to Enhance the Electrochemical Properties of POM Nanomaterials for Electrocatalysis -- 2.1 Introduction -- 2.1.1 Structure Bonding and Formation -- 2.1.2 POM Archetypes: Keggin and Wells-Dawson -- 2.1.3 Factors Influencing the Catalytic Role of POMs -- 2.1.4 The Structure-Redox Relationship in POMs -- 2.2 Design Approaches via Organofunctionalization -- 2.2.1 Transition?metal?substituted POMs (TMS?POMs) -- 2.2.2 Class I Hybrid POMs -- 2.2.3 Class II Hybrid POMs -- 2.2.4 Asymmetric Systems -- 2.2.5 Supramolecular Assembly -- 2.2.6 Immobilization Techniques -- 2.2.6.1 Surface Immobilization -- 2.2.6.2 Nanoencapsulation -- 2.3 Conclusion -- References -- Part II Polyoxometalates for Oxidative Electrocatalysis -- Chapter 3 POM?based Electrocatalysts for l?Cysteine and NADH Oxidation -- 3.1 Introduction -- 3.2 The Electrocatalytic Oxidation of l?cysteine (Cys) -- 3.2.1 V?containing POMs as Electrocatalysts in Homogeneous Phase -- 3.2.2 Ce?containing POMs as Electrocatalysts in Homogeneous Phase -- 3.2.3 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Carbon Paste Electrodes -- 3.2.4 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Layer?by?layer modified Electrodes -- 3.2.5 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Layer?by?layer and Nanoparticle?modified Electrodes. 327 $a3.3 The Electrocatalytic Oxidation of Nicotinamide Adenine Dinucleotide (NADH) -- 3.3.1 V?containing POMs as Electrocatalysts in Homogeneous Phase -- 3.3.2 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Layer?by?layer and Precipitate?deposition?modified Electrodes -- 3.3.3 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Layer?by?layer and Nanoparticle?modified Electrodes -- 3.3.4 POM?containing Hybrids as Electrocatalysts in Heterogeneous Phase: Precipitate?deposition?modified Electrodes and Electro?generated Chemiluminescence -- 3.3.5 POMs in Artificial Reductase Systems for Oxidation Catalysis -- 3.4 Conclusion -- List of Abbreviations -- References -- Chapter 4 POM?based Electrocatalysts for Pharmaceutical Molecules Oxidation -- 4.1 Introduction -- 4.2 Preparation Methods of POM?based Films and (Nano)composites -- 4.3 POM?based Electrocatalysis -- 4.3.1 Electrocatalysis -- 4.3.2 Dopamine Oxidation -- 4.3.3 Ascorbic Acid Oxidation -- 4.3.4 Other Molecules -- 4.4 Conclusions -- Acknowledgments -- List of Abbreviations -- References -- Part III Polyoxometalates for Reductive Electrocatalysis -- Chapter 5 POM?based Electrocatalysts for Inorganic Water Contaminants and Hydrogen Peroxide Reduction -- 5.1 Introduction -- 5.2 Nitrite Reduction -- 5.3 Bromate Reduction -- 5.4 Iodate Reduction -- 5.5 Hydrogen Peroxide Reduction Reaction -- 5.6 Conclusions -- Acknowledgment -- List of Abbreviations -- References -- Chapter 6 POM?based Electrocatalysts for Carbon Dioxide Reduction -- 6.1 Introduction -- 6.2 Thermodynamics of CO2 Reduction -- 6.3 Appealing Properties of POMs for CO2 Reduction -- 6.3.1 A Reservoir of 'Hopping' Electrons -- 6.3.2 Proton?coupled Electron Transfer in POMs -- 6.3.3 Tuning of the Reducibility of the POMs -- 6.3.4 Massive Electron Storage in POMs -- 6.3.5 A Versatile Platform. 327 $a6.4 Coordination of CO2 by POM Compounds -- 6.5 Electrocatalytic Reduction of CO2 with Dissolved POMs -- 6.5.1 3D Transition?metal?substituted POMs as Electrocatalysts in Organic Solvents -- 6.5.2 Platinoid?containing Hybrid POMs as Electrocatalysts in Organic Solvents -- 6.5.3 POMs as Electron Relays in Aqueous Solution -- 6.6 Electrocatalytic Reduction of CO2 at POMs?modified (Semi)conducting Electrode Surfaces -- 6.6.1 Immobilization of POMs on Electrodes -- 6.6.2 POMs?modified Electrodes Electrocatalytically Active for CO2 Reduction -- 6.7 Conclusions -- References -- Part IV Polyoxometales for Fuel Cells and Electrolysers -- Chapter 7 POM?based Electrocatalysts for Oxygen Evolution Reaction -- 7.1 Introduction: The OER Process -- 7.2 Pure POMs as OER Electrocatalysts -- 7.2.1 Structural and Mechanistic Considerations -- 7.2.1.1 POMs as Platforms for Water Oxidation Electrocatalysis -- 7.2.1.2 Water Oxidation Mechanism of POMs -- 7.2.2 Homogeneous Electrocatalysis -- 7.2.3 Heterogeneous Electrocatalysis -- 7.3 POM?containing (Nano)composites as OER Electrocatalysts -- 7.3.1 POM/Carbon (Nano)composites -- 7.3.2 POMs Combined with Metals/Metal Oxides/Metal Hydroxides/Metal Complexes -- 7.3.3 POM/MOF Nanocomposites -- 7.3.4 Other Nanomaterials -- 7.4 Heterogeneous Materials Derived from POM and POM?containing Nanocomposites -- 7.4.1 Encapsulation of POMs into MOFs Structures as Precursors for WO Electrocatalysts -- 7.4.2 Other POM?based Materials -- 7.5 Concluding Remarks -- Acknowledgements -- List of Abbreviations -- References -- Chapter 8 POM?based Electrocatalysts for Hydrogen Evolution Reaction -- 8.1 Introduction: HER Process -- 8.2 Pure POMs as HER Electrocatalysts -- 8.3 Composite/Hybrid Materials -- 8.3.1 Carbon/POM -- 8.3.2 MOF/POM (POMOFs) -- 8.3.3 Transition?metal/POM Composites -- 8.3.4 Polymer/POM -- 8.4 POM?derived Electrocatalysts. 327 $a8.4.1 SACs -- 8.4.2 Transition?metal Carbides -- 8.4.3 Transition?metal Chalcogens -- 8.4.4 Transition?metal Nitrates -- 8.4.5 Transition?metal Phosphides -- 8.4.6 Transition?metal Oxides -- 8.5 Concluding Remarks -- Acknowledgements -- List of Abbreviations -- List of Symbols -- References -- Chapter 9 POM?based Electrocatalysts for Oxygen Reduction Reactions -- 9.1 Introduction -- 9.2 Fundamentals of Oxygen Reduction Reaction -- 9.3 State?of?the?Art Electrocatalysts for the ORR -- 9.4 POM?based Electrocatalysts for the ORR -- 9.5 Conclusions -- Acknowledgements -- References -- Part V Polyoxometales for Batteries and Supercapacitors -- Chapter 10 POM?based Nanomaterials for Battery Applications -- 10.1 Introduction -- 10.2 Criteria for Efficient Redox Flow Batteries -- 10.3 Electrolyte Requirements for Redox Flow Batteries (RFBs) -- 10.3.1 Wide Potential Window -- 10.3.2 Energy Density and High Solubility -- 10.3.3 Fast Electron?transfer Kinetics -- 10.3.4 High Ionic Conductivity -- 10.3.5 Mass Transfer and Viscosity of Electrolyte -- 10.3.6 Long?term Stability of Active Materials -- 10.3.7 Costs and Safety -- 10.4 Classification of POMs -- 10.5 Suitability of POMs for Energy Conversion and Storage Devices -- 10.5.1 POMs in Supercapacitors -- 10.5.2 POMs in Li?ion Batteries -- 10.5.3 POMs in Na?ion Batteries -- 10.5.4 POMs in RFBs -- 10.6 Further Possibilities -- 10.7 POM?based RFBs in Comparison with Other RFBs -- 10.7.1 Iron/Chromium RFBs -- 10.7.2 All?vanadium RFBs -- 10.7.3 Zn/Br2 RFBs -- 10.8 Conclusions -- Abbreviations and Symbols -- References -- Chapter 11 POM?based Nanomaterials for Supercapacitors -- 11.1 Introduction to Energy?storage Devices -- 11.2 Properties of POMs for Supercapacitors -- 11.2.1 POMs as Electrode Materials -- 11.2.1.1 POM/Carbon Composites -- 11.2.1.2 POMs into Conductive Polymers. 327 $a11.2.1.3 POM?based Ternary Nanohybrids (TNH) -- 11.2.1.4 POMs Within Supramolecular Structures -- 11.2.2 POMs as Electrolyte Additives -- 11.3 Conclusions and Future Perspectives -- Acknowledgements -- References -- Index -- EULA. 330 $aThis book provides a comprehensive exploration of polyoxometalates (POMs), a class of nanoscale metal-oxide clusters known for their structural and chemical versatility. The text delves into the synthesis, structure, and applications of POMs in various fields such as catalysis, biomedicine, and materials science. It covers fundamental aspects, design strategies to enhance POM properties, and their use in oxidative and reductive processes. The book also discusses POM-based nanomaterials for energy applications, including fuel cells, batteries, and electrolysis. It serves as a resource for researchers, scientists, and students interested in nanomaterials and their technological applications.$7Generated by AI. 606 $aPolyoxometalates$7Generated by AI 606 $aNanostructured materials$7Generated by AI 615 0$aPolyoxometalates 615 0$aNanostructured materials 700 $aFernandes$b Diana M$01837931 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019393103321 996 $aApplied Polyoxometalate-Based Electrocatalysis$94416789 997 $aUNINA