LEADER 05404nam 2200697 a 450 001 9911019365203321 005 20251116151932.0 010 $a9786610519798 010 $a9781280519796 010 $a1280519797 010 $a9783527603909 010 $a3527603905 010 $a9783527604494 010 $a3527604499 035 $a(CKB)1000000000376382 035 $a(EBL)481350 035 $a(OCoLC)68570700 035 $a(SSID)ssj0000167566 035 $a(PQKBManifestationID)11924596 035 $a(PQKBTitleCode)TC0000167566 035 $a(PQKBWorkID)10177673 035 $a(PQKB)11394222 035 $a(MiAaPQ)EBC481350 035 $a(PPN)155908480 035 $a(Perlego)2761303 035 $a(EXLCZ)991000000000376382 100 $a20041019d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aHandbook of fluorous chemistry /$fJohn A. Gladysz, Dennis P. Curran, Istvan T. Horvath (Eds.) 210 $aWeinheim $cWiley-VCH$dc2004 215 $a1 online resource (627 p.) 300 $aDescription based upon print version of record. 311 08$a9783527306176 311 08$a352730617X 320 $aIncludes bibliographical references and index. 327 $aHandbook of Fluorous Chemistry; Contents; Preface; Contributors; 1 Fluorous Chemistry: Scope and Definition; 1.1 The Birth of a Term; 1.2 The Definition of Fluorous Today; 1.3 Other Definitions within the Fluorous Repertoire; 1.4 Present Scope of Fluorous Chemistry; References; 2 A Personal View of the History of Fluorous Chemistry; References; 3 Fluorous Solvents and Related Media; 3.1 Introductory Remarks; 3.2 Commercial Fluorous Solvents; 3.3 Related Solvents and Media; 3.3.1 Amphiphilic or Hybrid Solvents; 3.3.2 Fluorous Ionic Liquids; 3.3.3 ""Faux Fluorous"" Solvents 327 $a3.3.4 Fluorous Greases3.3.5 Bonded Fluorous Phases; 3.4 Polarities of Fluorous Solvents; 3.5 Solubilities of Solutes in Fluorous Solvents; 3.5.1 General Aspects; 3.5.2 Gas Solubilities; 3.6 Fluorous/Non-fluorous Solvent Miscibilities; 3.7 Special Reactivity Phenomena in Fluorous Solvents; References; 4 Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation; 4.1 Introduction; Basic Recycling Concepts; 4.2 Fluorous/Non-Fluorous Liquid/Liquid Biphase Catalysis; 4.3 Fluorous Catalysis in Amphiphilic or Hybrid Solvents 327 $a4.4 Fluorous Catalysis Without Non-Fluorous Solvents4.5 Fluorous Catalysis Without Fluorous Solvents; 4.5.1 Thermomorphic Catalysts; 4.5.2 Other Approaches; 4.6 Fluorous Catalysis Without Solvents; 4.7 Recovery of Fluorous Catalysts using Supports; 4.8 Criteria for Recoverability; 4.8.1 Yield as a Function of Cycle; 4.8.2 TOF as a Function of Cycle; 4.8.3 Catalyst Inventory; 4.9 Slanting Data: How to Make a Non-recoverable Catalyst Appear Recoverable; 4.10 Prospects; References; 5 Ponytails: Structural and Electronic Considerations; 5.1 Introduction; 5.2 Structural Aspects of Ponytails 327 $a5.3 NMR Characterization of Ponytails5.4 Electronic Effects: Introduction; 5.5 Electronic Effects: IR Data; 5.6 Electronic Effects: Gas Phase Ionization Data; 5.7 Electronic Effects: Calorimetry; 5.8 Electronic Effects: Solution Equilibria; 5.9 Electronic Effects: Computational Data; 5.10 Electronic Effects: Reactivity; 5.11 Electronic Effects: Additional Probes; 5.12 Electronic Effects: Conclusions; References; 6 Partition Coefficients Involving Fluorous Solvents; 6.1 Introduction; 6.2 Literature Data; 6.3 Trends with Respect to Functional Groups; 6.3.1 Non-Aromatic Hydrocarbons 327 $a6.3.2 Non-Aromatic Monofunctional Compounds6.3.3 Simple Monoarenes; 6.3.4 Triarylphosphines; 6.3.5 Pyridines; 6.3.6 Metal Complexes; 6.4 General Trends and Special Situations; 6.5 Quantitative Analysis and Prediction of Partition Coefficients; 6.6 Future Directions; 6.7 Sample Experimental Determinations; References; 7 Separations with Fluorous Silica Gel and Related Materials; 7.1 Introduction; 7.1.1 Fluorous Silica Gel; 7.1.2 Types and Sources of Fluorous Silica Gel Materials and Products; 7.2 Fluorous Solid Phase Extraction (FSPE) 327 $a7.2.1 Fluorous Solid Phase Extraction and its Relationship to Chromatography and Liquid/Liquid Extraction 330 $aEdited by the leading experts John Gladysz, Dennis Curran, and Istv?n Horv?th, this handbook is the first to summarize all the essential aspects of this emerging field of chemistry. Whether the reader is seeking an introduction to the concept of fluorous biphase catalysis, summaries of partition coefficients involving fluorous and organic solvents, or information on the latest fluorous mixture separation techniques, this authoritative compilation of contributions, written by the world's top authors, provides key information needed for successfully working with the diverse and fascinating famil 606 $aFluorine compounds 606 $aFluorine 615 0$aFluorine compounds. 615 0$aFluorine. 676 $a546/.731 701 $aGladysz$b John A$01839437 701 $aCurran$b Dennis P$092868 701 $aHorva?th$b Istva?n T$01839438 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019365203321 996 $aHandbook of fluorous chemistry$94418659 997 $aUNINA