LEADER 01092nas 2200397-a 450 001 9910138773803321 005 20210927213032.0 035 $a(OCoLC)637110786 035 $a(CKB)2320000000016177 035 $a(CONSER)--2010203134 035 $a(DE-599)ZDB2620855-6 035 $a(EXLCZ)992320000000016177 100 $a20100604a20109999 --- a 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aFrontiers in heat pipes 210 $aColumbia, MO $cGlobal Digital Central 215 $a1 online resource 300 $aRefereed/Peer-reviewed 311 $a2155-658X 517 1 $aFHP 531 0 $aFront. heat pipes 606 $aHeat pipes$vPeriodicals 606 $aHeat pipes$2fast$3(OCoLC)fst00953910 608 $aPeriodicals.$2fast 610 $aMechanical Engineering - General 615 0$aHeat pipes 615 7$aHeat pipes. 676 $a620 906 $aJOURNAL 912 $a9910138773803321 996 $aFrontiers in heat pipes$91957483 997 $aUNINA LEADER 05409nam 2200673Ia 450 001 9911019341703321 005 20200520144314.0 010 $a9786611239206 010 $a9781281239204 010 $a1281239208 010 $a9783527611638 010 $a3527611630 010 $a9783527611621 010 $a3527611622 035 $a(CKB)1000000000376148 035 $a(EBL)481502 035 $a(SSID)ssj0000289427 035 $a(PQKBManifestationID)11221477 035 $a(PQKBTitleCode)TC0000289427 035 $a(PQKBWorkID)10401663 035 $a(PQKB)10103723 035 $a(MiAaPQ)EBC481502 035 $a(OCoLC)181349406 035 $a(Perlego)2752110 035 $a(EXLCZ)991000000000376148 100 $a20061128d2007 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aAtmospheric degradation of organic substances $edata for persistence and long-range transport potential /$fWalter Klopffer and Burkhard O. Wagner 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley, distributor]$dc2007 215 $a1 online resource (261 p.) 300 $aDescription based upon print version of record. 311 08$a9783527316069 311 08$a352731606X 320 $aIncludes bibliographical references and index. 327 $aAtmospheric Degradation of Organic Substances; Foreword; Preface; Contents; Chapter 1 Significance of Photo-degradation in Environmental Risk Assessment; 1 Introduction; 2 Persistence and Long-range Transport Potential in Chemicals Regulation; 3 Multimedia Models as Tools to Estimate Persistence and Long-range Transport Potential; 4 Data Requirements for Multimedia Models; 5 Estimation of the Rate Constant of Organic Substances with Hydroxyl Radicals; 6 Research Requirements for Photo-degradation of Semi-volatile Substances; 7 Conclusions; References 327 $aChapter 2 Abiotic Degradation in the Atmosphere1 Introduction; 2 Photo-degradation in the Homogenous Gas Phase of the Troposphere; 2.1 Indirect Photochemical Reactions; 2.1.1 The Reaction with OH-Radicals; 2.1.1.1 Sources and Sinks of the OH-Radical; 2.1.1.2 Reactions of OH with Organic Compounds; 2.1.2 The Reaction with NO(3)-Radicals; 2.1.2.1 Sources and Sinks of the NO(3)-Radical; 2.1.2.2 Reactions of NO(3) with Organic Compounds; 2.1.3 The Reaction with Ozone; 2.1.3.1 Sources and Sinks of O(3) in the Troposphere; 2.1.3.2 Reactions of O(3) with Organic Compounds 327 $a2.2 Direct Photochemical Reactions2.2.1 Quantum Efficiency; 2.2.2 Examples of Photochemical Reactions in the Gas Phase; 3 Heterogeneous Degradation; 3.1 Degradation on Solid Surfaces; 3.1.1 Introduction; 3.1.2 Degradation on Fly Ash and Soot; 3.1.3 Degradation on Artificial Aerosols; 3.2 Degradation in Droplets; 3.2.1 Direct Photochemical Transformation; 3.2.2 Reactive Trace Compounds in Cloud, Fog and Rainwater; 3.2.3 Reactions of Organic Molecules; 3.2.4 Summary; 4 Experimental; 4.1 Indirect Photochemical Degradation; 4.1.1 Bimolecular Reaction with OH 327 $a4.1.1.1 Direct Methods for Measuring k(OH)4.1.1.2 Indirect Methods for the Measurement of k(OH); 4.1.2 Bimolecular Reaction with NO(3); 4.1.2.1 Introduction; 4.1.2.2 Absolute Measurement; 4.1.2.3 Relative Measurements; 4.1.3 Bimolecular Reaction with Ozone; 4.2 Direct Photo-transformation; 4.2.1 Determination of the Quantum Efficiency in the Gas Phase; 4.2.1.1 Gas Cuvette and Monochromatic Radiation; 4.2.1.2 Smog-chamber Method; 4.2.2 Outlook; 4.3 Degradation in the Adsorbed State; 4.3.1 Introduction; 4.3.2 Aerosol Chambers; 4.3.3 Alternative Measurements of k(OH,ads) 327 $a5 Additional Information Necessary for Calculating Lifetimes5.1 Atmospheric Lifetimes; 5.2 Indirect Photochemical Degradation; 5.2.1 Average OH Concentration in the Troposphere; 5.2.2 Average NO(3) Concentration in the Troposphere; 5.2.3 Average O(3) Concentration in the Troposphere; 5.3 Direct Photochemical Degradation; 5.3.1 Introduction; 5.3.2 Absorption Spectrum; 5.3.3 Spectral Photon Irradiance; 5.3.4 Final Comments on Direct and Indirect Photochemical Transformation; References; Chapter 3 Table of Reaction Rate Constants of Photo-Degradation Processes; 1 Content of the Table 327 $a2 Explanation of the Column Headings 330 $aThis compilation on the degradation of 1,100 commercially important chemical products is the first publication to make this knowledge publicly accessible in one book. The data and annotations have been painstakingly assembled over a 10-year period in a collaboration between academia and regulatory authorities. The work explains in detail the methods, including computational ones, for the environmental assessment of volatile and semi-volatile substances, and is rounded off with data tables of degradation rates.A key resource for manufacturers and regulators of such substances. 606 $aOrganic compounds$xBiodegradation 606 $aChemistry, Organic 615 0$aOrganic compounds$xBiodegradation. 615 0$aChemistry, Organic. 676 $a628.52 700 $aKlopffer$b Walter$f1938-$0626564 701 $aWagner$b Burkhard O$01839063 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019341703321 996 $aAtmospheric degradation of organic substances$94418188 997 $aUNINA