LEADER 00806oam 2200181z- 450 001 996388071703316 005 20200818222521.0 035 $a(CKB)4940000000092255 035 $a(EEBO)2248543583 035 $a(EXLCZ)994940000000092255 100 $a20191209c1652uuuu -u- - 101 0 $aeng 200 14$aThe weekly intelligencer of the Common-wealth Faithfully communicating all affairs both martial and civil. | Collected by the same hand which drew up the Kingdoms weekly intelligencer. [Issue 68] 210 $cPrinted for R.C$aEngland 906 $aBOOK 912 $a996388071703316 996 $aThe weekly intelligencer of the Common-wealth Faithfully communicating all affairs both martial and civil. | Collected by the same hand which drew up the Kingdoms weekly intelligencer.$92299295 997 $aUNISA LEADER 05500nam 2200697Ia 450 001 9911019244803321 005 20200520144314.0 010 $a9786610854134 010 $a9781280854132 010 $a1280854138 010 $a9783527606726 010 $a3527606726 010 $a9783527607051 010 $a3527607056 035 $a(CKB)1000000000376052 035 $a(EBL)481716 035 $a(OCoLC)70114281 035 $a(SSID)ssj0000253731 035 $a(PQKBManifestationID)11216065 035 $a(PQKBTitleCode)TC0000253731 035 $a(PQKBWorkID)10207710 035 $a(PQKB)11635924 035 $a(MiAaPQ)EBC481716 035 $a(Perlego)2776179 035 $a(EXLCZ)991000000000376052 100 $a20060620d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSupercritical carbon dioxide in polymer reaction engineering /$fedited by Maartje F. Kemmere and Thierry Meyer 210 $aWeinheim $cWiley-VCH$dc2005 215 $a1 online resource (361 p.) 300 $aDescription based upon print version of record. 311 08$a9783527310920 311 08$a3527310924 320 $aIncludes bibliographical references and index. 327 $aSupercritical Carbon Dioxide; Foreword; Preface; Contents; List of Contributors; 1 Supercritical Carbon Dioxide for Sustainable Polymer Processes; 1.1 Introduction; 1.2 Strategic Organic Solvent Replacement; 1.3 Physical and Chemical Properties of Supercritical CO(2); 1.4 Interactions of Carbon Dioxide with Polymers and Monomers; 1.5 Concluding Remarks and Outlook; Notation; References; 2 Phase Behavior of Polymer Systems in High-Pressure Carbon Dioxide; 2.1 Introduction; 2.2 General Phase Behavior in Polymer/Solvent Systems; 2.3 Polymer Solubility in CO(2); 2.4 Thermodynamic Modeling 327 $a2.5 ConclusionsNotation; References; 3 Transport Properties of Supercritical Carbon Dioxide; 3.1 Introduction; 3.2 Hydrodynamics and Mixing; 3.2.1 Laser-Doppler Velocimetry and Computational Fluid Dynamics; 3.2.2 Flow Characteristics; 3.3 Heat Transfer; 3.3.1 Specific for Near-Critical Fluids: the Piston Effect; 3.3.2 Reaction Calorimetry; 3.3.3 Heat Transfer in Stirred Vessel with SCFs; 3.4 Conclusions; Notation; References; 4 Kinetics of Free-Radical Polymerization in Homogeneous Phase of Supercritical Carbon Dioxide; 4.1 Introduction; 4.2 Experimental; 4.3 Initiation; 4.4 Propagation 327 $a4.4.1 Propagation Rate Coefficients4.4.2 Reactivity Ratios; 4.5 Termination; 4.6 Chain Transfer; 4.7 Conclusions; Notation; References; 5 Monitoring Reactions in Supercritical Media; 5.1 Introduction; 5.2 On-line Analytical Methods Used in SCF; 5.2.1 Spectroscopic Methods; 5.2.1.1 FTIR; 5.2.1.2 Raman Spectroscopy; 5.2.1.3 UV/Vis; 5.2.1.4 NMR; 5.2.2 Reflectometry; 5.2.3 Acoustic Methods; 5.3 Calorimetric Methods; 5.3.1 Power Compensation Calorimetry; 5.3.2 Heat Flow Calorimetry; 5.3.2.1 Heat Balance Equations [27]; 5.3.2.2 Determination of Physico-Chemical Parameters 327 $a5.3.2.3 Calorimeter Validation by Heat Generation Simulation5.4 MMA Polymerization as an Example; 5.4.1 Calorimetric Results; 5.4.2 The Coupling of Calorimetry and On-Line Analysis; 5.5 Conclusions; Notation; References; 6 Heterogeneous Polymerization in Supercritical Carbon Dioxide; 6.1 Introduction; 6.2 Literature Review; 6.3 Modeling of the Process; 6.4 Case Study I: MMA Dispersion Polymerization; 6.5 Case Study II: VDF Precipitation Polymerization; 6.6 Concluding Remarks and Outlook; Notation; References; 7 Inverse Emulsion Polymerization in Carbon Dioxide; 7.1 Introduction 327 $a7.2 Inverse Emulsion Polymerization in CO(2): Design Constraints7.3 Surfactant Design for Inverse Emulsion Polymerization; 7.3.1 Designing CO(2)-philic Compounds: What Can We Learn from Fluoropolymer Behavior?; 7.3.2 Non-Fluorous CO(2)-Philes: the Role of Oxygen; 7.4 Inverse Emulsion Polymerization in CO(2): Results; 7.5 Future Challenges; References; 8 Catalytic Polymerization of Olefins in Supercritical Carbon Dioxide; 8.1 Introduction; 8.2 Phase Behavior of Polyolefin-Monomer-CO(2) Systems; 8.2.1 Cloud-Point Measurements on the PEP-Ethylene-CO(2) System 327 $a8.2.2 SAFT Modeling of the PEP-Ethylene-CO(2) System 330 $aRecently, supercritical fluids have emerged as more sustainable alternatives for the organic solvents often used in polymer processes. This is the first book emphasizing the potential of supercritical carbon dioxide for polymer processes from an engineering point of view. It develops a state-of-the-art overview on polymer fundamentals, polymerization reactions and polymer processing in supercritical carbon dioxide. The book covers topics in a multidisciplinary approach starting from polymer chemistry and thermodynamics, going through monitoring, polymerization processes and ending with polymer 606 $aLiquid carbon dioxide 606 $aPolymerization 606 $aSupercritical fluid extraction 615 0$aLiquid carbon dioxide. 615 0$aPolymerization. 615 0$aSupercritical fluid extraction. 676 $a660.284248 701 $aKemmere$b Maartje F$01841847 701 $aMeyer$b Thierry$f1961-$01284457 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911019244803321 996 $aSupercritical carbon dioxide in polymer reaction engineering$94421725 997 $aUNINA