LEADER 03799oam 2200601zu 450 001 9911019089303321 005 20251116150205.0 010 $a0-470-86798-1 010 $a9786610556038 010 $a1-280-55603-X 035 $a(CKB)111082128277302 035 $a(SSID)ssj0000204963 035 $a(PQKBManifestationID)11184233 035 $a(PQKBTitleCode)TC0000204963 035 $a(PQKBWorkID)10192702 035 $a(PQKB)10577041 035 $a(MiAaPQ)EBC4956760 035 $a(Au-PeEL)EBL4956760 035 $a(CaONFJC)MIL55603 035 $a(OCoLC)52898002 035 $a(EXLCZ)99111082128277302 100 $a20160829d2003 uy 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMolecular spectroscopy of oxide catalyst surfaces 210 31$a[Place of publication not identified]$cJohn Wiley & Sons Incorporated$d2003 215 $a1 online resource (684 pages) 300 $aBibliographic Level Mode of Issuance: Monograph 311 08$a0-471-98731-X 311 08$a0-470-86487-7 330 $aAs in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules.; The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption 330 8 $aphenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides. 606 $aMetallic oxides$xSurfaces$xAnalysis 606 $aMolecular spectroscopy 606 $aChemistry$2HILCC 606 $aPhysical Sciences & Mathematics$2HILCC 606 $aPhysical & Theoretical Chemistry$2HILCC 615 0$aMetallic oxides$xSurfaces$xAnalysis. 615 0$aMolecular spectroscopy. 615 7$aChemistry 615 7$aPhysical Sciences & Mathematics 615 7$aPhysical & Theoretical Chemistry 676 $a541.3/3 700 $aDavydov$b A. A.$0350742 702 $aSheppard$b N. 801 0$bPQKB 906 $aBOOK 912 $a9911019089303321 996 $aMolecular spectroscopy of oxide catalyst surfaces$94417199 997 $aUNINA