LEADER 05416nam 22008173u 450 001 9911007093003321 005 20230802011006.0 010 $a9780486131696 010 $a0486131696 010 $a9781621986102 010 $a1621986101 035 $a(CKB)2550000001185918 035 $a(EBL)1894914 035 $a(SSID)ssj0001002702 035 $a(PQKBManifestationID)12438247 035 $a(PQKBTitleCode)TC0001002702 035 $a(PQKBWorkID)11015660 035 $a(PQKB)10535180 035 $a(MiAaPQ)EBC1894914 035 $a(Au-PeEL)EBL1894914 035 $a(CaONFJC)MIL565296 035 $a(OCoLC)868271032 035 $a(Perlego)110957 035 $a(EXLCZ)992550000001185918 100 $a20141222d2012|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aChemical Kinetics and Reaction Dynamics 205 $a1st ed. 210 $aNewburyport $cDover Publications$d2012 215 $a1 online resource (670 p.) 225 1 $aDover Books on Chemistry 300 $aDescription based upon print version of record. 311 08$a9780486453347 311 08$a0486453340 311 08$a9781306340458 311 08$a1306340454 327 $aTitle Page; Bibliographical Note; Copyright Page; Dedication; Table of Contents; Preface; Introduction - A User's Guide to Chemical Kinetics and Reaction Dynamics; Errata; 1 - Kinetic Theory of Gases; 1.1 INTRODUCTION; 1.2 PRESSURE OF AN IDEAL GAS; 1.3 TEMPERATURE AND ENERGY; 1.4 DISTRIBUTIONS, MEAN VALUES, AND DISTRIBUTION FUNCTIONS; 1.5 THE MAXWELL DISTRIBUTION OF SPEEDS; 1.6 ENERGY DISTRIBUTIONS; 1.7 COLLISIONS: MEAN FREE PATH AND COLLISION NUMBER; 1.8 SUMMARY; appendix 1.1; appendix 1.2; appendix 1.3; appendix 1.4; suggested readings; problems; 2 - The Rates of Chemical Reactions 327 $a2.1 INTRODUCTION2.2 EMPIRICAL OBSERVATIONS: MEASUREMENT OF REACTION RATES; 2.3 RATES OF REACTIONS: DIFFERENTIAL AND INTEGRATED RATE LAWS; 2.4 REACTION MECHANISMS; 2.5 HOMOGENEOUS CATALYSIS; 2.6 FREE RADICAL REACTIONS: CHAINS AND BRANCHED CHAINS; 2.7 DETERMINING MECHANISMS FROM RATE LAWS; 2.8 SUMMARY; suggested readings; problems; 3 - Theories of Chemical Reactions; 3.1 INTRODUCTION; 3.2 POTENTIAL ENERGY SURFACES; 3.3 COLLISION THEORY; 3.5 THERMODYNAMIC INTERPRETATION OF ACT; 3.6 SUMMARY; suggested readings; problems; 4 - Transport Properties; 4.1 INTRODUCTION 327 $a4.2 THE FUNCTIONAL FORM OF THE TRANSPORT EQUATIONS4.3 THE MICROSCOPIC BASIS FOR THE TRANSPORT LAWS; 4.4 THERMAL CONDUCTIVITY; 4.5 VISCOSITY; 4.6 DIFFUSION; 4.7 TIME-DEPENDENT TRANSPORT; 4.8 SUMMARY; appendix 4.1 - The Poiseuille Formula; suggested readings; problems; 5 - Reactions in Liquid Solutions; 5.1 INTRODUCTION; 5.2 THE CAGE EFFECT, FRICTION, AND DIFFUSION CONTROL; 5.3 REACTIONS OF CHARGED SPECIES IN SOLUTION: IONIC STRENGTH AND ELECTRON TRANSFER; 5.3.1 Reaction Rates and Ionic Strength; 5.4 EXPERIMENTAL TECHNIQUES; 5.5 SUMMARY; appendix 5.1 327 $aappendix 5.2 - Diffusion with an Electrostatic Potentialsuggested readings; problems; 6 - Reactions at Solid Surfaces; 6.1 INTRODUCTION; 6.2 ADSORPTION AND DESORPTION; 6.3 REACTIONS AT SURFACES: CATALYSIS; 6.4 SURFACE DIFFUSION; 6.5 ADVANCED TOPICS IN SURFACE REACTIONS; 6.6 SUMMARY; appendix 6.1; suggested readings; problems; 7 - Photochemistry; 7.1 INTRODUCTION; 7.2 ABSORPTION AND EMISSION OF LIGHT; 7.3 PHOTOPHYSICAL PROCESSES; 7.4 ATMOSPHERIC CHEMISTRY; 7.5 PHOTODISSOCIATION DYNAMICS; 7.6 SUMMARY; suggested readings; problems; 8 - Molecular Reaction Dynamics; 8.1 INTRODUCTION 327 $a8.2 A MOLECULAR DYNAMICS EXAMPLE8.3 MOLECULAR COLLISIONS-A DETAILED LOOK; 8.4 MOLECULAR SCATTERING; 8.5 POTENTIAL ENERGY SURFACES; 8.6 MOLECULAR ENERGY TRANSFER; 8.7 MOLECULAR REACTION DYNAMICS-SOME EXAMPLES; 8.8 SUMMARY; suggested reading; problems.; Answers and Solutions to Selected Problems; Index 330 $aThis text teaches the principles underlying modern chemical kinetics in a clear, direct fashion, using several examples to enhance basic understanding. It features solutions to selected problems, with separate sections and appendices that cover more technical applications.Each chapter is self-contained and features an introduction that identifies its basic goals, their significance, and a general plan for their achievement. This text's important aims are to demonstrate that the basic kinetic principles are essential to the solution of modern chemical problems, and to show how the underlying qu 410 0$aDover Books on Chemistry 606 $aChemical kinetics 606 $aChemical reactions 606 $aChemical kinetics 606 $aChemical reactions 606 $aChemistry$2HILCC 606 $aPhysical Sciences & Mathematics$2HILCC 606 $aPhysical & Theoretical Chemistry$2HILCC 615 4$aChemical kinetics. 615 4$aChemical reactions. 615 0$aChemical kinetics. 615 0$aChemical reactions. 615 7$aChemistry 615 7$aPhysical Sciences & Mathematics 615 7$aPhysical & Theoretical Chemistry 676 $a541.394 676 $a541/.394 700 $aHouston$b Paul L$0607175 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9911007093003321 996 $aChemical kinetics and reaction dynamics$91123130 997 $aUNINA