LEADER 05309nam 2200649Ia 450 001 9911006892403321 005 20200520144314.0 010 $a1-282-71157-1 010 $a9786612711572 010 $a0-08-093204-5 035 $a(CKB)1000000000555992 035 $a(EBL)369481 035 $a(OCoLC)476204841 035 $a(SSID)ssj0000204823 035 $a(PQKBManifestationID)11221210 035 $a(PQKBTitleCode)TC0000204823 035 $a(PQKBWorkID)10208883 035 $a(PQKB)10257654 035 $a(MiAaPQ)EBC369481 035 $a(EXLCZ)991000000000555992 100 $a20080918d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMolecular characterization and analysis of polymers /$fedited by John M. Chalmers, Robert J. Meier 210 $aAmsterdam ;$aLondon $cElsevier$d2008 215 $a1 online resource (784 p.) 225 1 $aComprehensive analytical chemistry ;$vv. 53 300 $aDescription based upon print version of record. 311 $a0-444-53056-8 320 $aIncludes bibliographical references and index. 327 $aFront cover; Copyright page; Comprehensive Analytical Chemistry: Molecular Characterization and Analysis of Polymers; Contents; Contributors to Volume 53; Volumes in the series; Preface; Series Editor's Preface; Section I: Introduction; Chapter 1. Introduction; 1. The Analytical Competence; 2. Contents and Structure; 3. Practical Considerations in the Multi-Technique Approach; References; Chapter 2. Polymer Chemistry and Microstructure; 1. Introduction; 2. Polymer: Definitions; 3. From Molecules to Macromolecules; 4. Fundamentals of Polymer Chemistry; 5. Polymer Degradation; 6. Summary 327 $aReferencesChapter 3. Polymeric Materials: Composition, Uses and Applications; 1. Introduction; 2. Mode of Polymerisation; 3. Polymer materials: Types and forms; 4. Polymer Additives; 5. Summary; Bibliography; Section II: Polymer Chain Analysis; Chapter 4. Chain Structure Characterization; 1. Introduction to Structure in Synthetic Macromolecules; 2. Local Structure and Its Ramifications; 3. Summary; References; Chapter 5. Chain End Characterisation; 1. Introduction; 2. End Groups in Free Radical Polymers; 3. End Groups in Condensation Polymers 327 $a4. End Groups in Polymers from Ionic Polymerisation5. Closing Remarks; Acknowledgements; References; Chapter 6. Determination of Molecular Weights and Their Distributions; 1. Introduction; 2. Distribution Functions and Averages; 3. Methods Based on Colligative Properties; 4. Viscometry; 5. Scattering Techniques; 6. Liquid Chromatography; 7. Analytical Ultracentrifuge; 8. Other Methods; 9. Practical Examples; 10. Conclusion; Acknowledgements; References; Section III: Polymer Morphology and Structure; Chapter 7. Phase Structure and Morphology; 1. Phase Structure and Morphology 327 $a2. Supermolecular Morphology3. Concluding Remarks; Acknowledgements; References; Chapter 8. Characterization of Molecular Orientation; 1. Introduction; 2. Theory; 3. Birefringence; 4. Infrared Linear Dichroism (IRLD); 5. Raman Spectroscopy and Microspectroscopy; 6. Fluorescence Spectroscopy; 7. NMR Spectroscopy; 8. X-Ray Diffraction and Absorption; 9. Conclusion; References; Chapter 9. Polymer Networks: Elastomers; 1. Introduction; 2. Structure of a Typical Network; 3. Elementary and More Advanced Molecular Theories; 4. Phenomenological Theories; 5. Some Relevant Simulations 327 $a6. Swelling of Networks and Responsive Gels7. Enthalpic and Entropic Contributions to Rubber Elasticity: The Force-Temperature Relations; 8. Multimodal Elastomers; 9. Liquid-Crystalline Elastomers; 10. Novel Reinforced Elastomers; 11. Further Comments on Some Characterization Techniques; Acknowledgement; References; Section IV: Polymer Degradation; Chapter 10. Polymer Degradation and Oxidation: An Introduction; 1. Introduction; 2. Standard Tests and Comparative Methods; 3. Spectroscopic Techniques; 4. Thermal Methods; 5. Chromatographic Analysis; 6. Closing Remarks; Acknowledgement 327 $aReferences 330 $aWritten by expert contributors from the academic and industrial sectors, this book presents traditional and modern approaches to polymer characterization and analysis. The emphasis is on pragmatics, problem solving and property determination; real-world applications provide a context for key concepts. The characterizations focus on organic polymer and polymer product microstructure and composition.-Approaches molecular characterization and analysis of polymers from the viewpoint of problem-solving and polymer property characterization, rather than from a technique championing appro 410 0$aComprehensive analytical chemistry ;$vv. 53. 606 $aPolymers$xAnalysis 606 $aChemistry 615 0$aPolymers$xAnalysis. 615 0$aChemistry. 676 $a547.70442 686 $aVG 2400$2rvk 686 $aVG 4520$2rvk 701 $aChalmers$b John M$01682916 701 $aMeier$b Robert J$0102516 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911006892403321 996 $aMolecular characterization and analysis of polymers$94390413 997 $aUNINA