LEADER 04852nam 2200661 a 450 001 9911006818603321 005 20200520144314.0 010 $a1-282-25314-X 010 $a9786612253133 010 $a9786612252990 010 $a9786612253140 010 $a0-08-094737-9 010 $a0-8155-1725-4 035 $a(CKB)1000000000441159 035 $a(EBL)428634 035 $a(OCoLC)244207469 035 $a(SSID)ssj0000071958 035 $a(PQKBManifestationID)11107331 035 $a(PQKBTitleCode)TC0000071958 035 $a(PQKBWorkID)10094510 035 $a(PQKB)10240098 035 $a(MiAaPQ)EBC428634 035 $a(EXLCZ)991000000000441159 100 $a20070824d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFluorinated ionomers /$fWalther Grot 210 $aNorwich, NY $cWilliam Andrew Pub.$dc2008 215 $a1 online resource (253 p.) 225 1 $aPDL handbook series 300 $aDescription based upon print version of record. 311 $a0-8155-1541-3 320 $aIncludes bibliographical references and index. 327 $aFront Cover; Fluorinated Ionomers; Copyright Page; Contents; PDL Fluorocarbon Series Editor's Preface; Preface; Acknowledgements; Chapter 1. Introduction; 1.1 Polymers; 1.2 Physical Shapes; 1.3 References; Chapter 2. History; 2.1 References; Chapter 3. Manufacture; 3.1 Introduction; 3.2 Perfluorinated Ionomers; 3.3 Polymerization; 3.4 Fabrication; 3.5 Hydrolysis and Acid Exchange; 3.6 Finishing and Testing; 3.7 Liquid Compositions; 3.8 Fluorinated Ionomers with Phosphonic or Sulfonyl Imide Functional Groups; 3.9 Partially Fluorinated Ionomers 327 $a3.10 Composite Materials of Ionomers and Inorganic Oxides3.11 Remanufactured Membranes; 3.12 References; Chapter 4. Properties; 4.1 Properties of the Precursor Polymers; 4.2 Properties of the Ionic Forms; 4.3 Morphology; 4.4 Transport Properties; 4.5 Optical Properties; 4.6 Thermal Properties; 4.7 Stability; 4.8 References; Chapter 5. Applications; 5.1 Electrolysis; 5.2 Sensors and Actuators; 5.3 Dialysis; 5.4 Gas and Vapor Diffusion; 5.5 Protective Clothing; 5.6 Catalysis; 5.7 References; Chapter 6. Fuel Cells and Batteries; 6.1 Introduction; 6.2 Operating Parameters; 6.3 Ionomer Stability 327 $a6.4 Direct Methanol Fuel Cells (DMFCs)6.5 Manufacture of MEAs; 6.6 References; 6.7 Further Reading; Chapter 7. Commercial Membrane Types; 7.1 Unreinforced Perfluorinated Sulfonic Acid Films; 7.2 Reinforced Perfluorinated Membranes; Chapter 8. Economic Aspects; 8.1 Chlor-Alkali Cells; 8.2 Fuel Cells; 8.3 References; Chapter 9. Experimental Methods; 9.1 Infrared Spectra; 9.2 Hydrolysis, Surface Hydrolysis and Staining; 9.3 Other Reactions of the Precursor Polymer; 9.4 Ion Exchange Equilibrium; 9.5 Determination of EW by Titration or Infrared Analysis; 9.6 Determining Melt Flow 327 $a9.7 Distinguishing the Precursor Polymer from Various Ionic Forms9.8 Fenton's Test for Oxidative Stability; 9.9 Examination of a Membrane; 9.10 Determining the Permselectivity; 9.11 Measuring Pervaporation Rates; 9.12 Simple Electrolytic Cells; 9.13 References; Chapter 10. Heat Sealing and Repair; 10.1 Reference; Chapter 11. Handling and Storage; 11.1 Handling the Film; 11.2 Pretreatment; 11.3 Installation; Chapter 12. Toxicology, Safety and Disposal; 12.1 Toxicology; 12.2 Safety; 12.3 Disposal; 12.4 References; Appendix A: A Chromic Acid Regeneration System 327 $aAppendix B: Laboratory Chlor-alkali CellAppendix C: Solution Cast Nafion Film; Appendix D: Plastic-Based Bipolar Plates; Suppliers and Resources; Glossary and Web Sites; Index; Plastics Design Library Founding Editor: William A. Woishnis 330 $aThe author of this unique handbook on fluorinated ionomers is also the inventor of the first commercial product known as NafionŽ (DuPont). The book covers partially fluorinated and perfluorinated polymers containing sufficient ionic groups to dominate the transport properties of the polymer. The emphasis of this book is on the practical aspects of working with fluorinated ionomers. It is intended to help the scientist and engineer in the preparation, fabrication, use, and study of these products as well as in the development of new applications and compositions. Extensive coverage has 410 0$aPDL handbook series. 606 $aIonomers 606 $aOrganofluorine compounds 606 $aElectrolytic cells 615 0$aIonomers. 615 0$aOrganofluorine compounds. 615 0$aElectrolytic cells. 676 $a668.9 700 $aGrot$b Walther$01822758 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911006818603321 996 $aFluorinated ionomers$94389122 997 $aUNINA