LEADER 03612nam 22006613u 450 001 9911006616203321 005 20230802010943.0 010 $a0-486-15115-8 010 $a1-62198-592-X 035 $a(CKB)2550000001188294 035 $a(EBL)1909645 035 $a(SSID)ssj0001002744 035 $a(PQKBManifestationID)12461043 035 $a(PQKBTitleCode)TC0001002744 035 $a(PQKBWorkID)11016244 035 $a(PQKB)11231068 035 $a(MiAaPQ)EBC1909645 035 $a(Au-PeEL)EBL1909645 035 $a(CaONFJC)MIL567662 035 $a(OCoLC)868966226 035 $a(EXLCZ)992550000001188294 100 $a20150105d2012|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aIntroduction to Stereochemistry 205 $a1st ed. 210 $aNewburyport $cDover Publications$d2012 215 $a1 online resource (262 p.) 225 1 $aDover Books on Chemistry 300 $aDescription based upon print version of record. 311 08$a0-486-42530-4 311 08$a1-306-36411-6 327 $aDOVER BOOKS ON CHEMISTRY; Title Page; Copyright Page; PREFACE TO THE DOVER EDITION; PREFACE; Table of Contents; 1 - STRUCTURE AND SYMMETRY; 1-1 Introduction; 1-2 Bonding Geometries in Carbon Compounds; 1-3 Bonding Orbitals in Carbon Compounds; 1-4 Reflection Symmetry-Point Groups; 1-5 Molecular Deformations and Strain Energies; 1-6 Molecular Models; 1-7 Exercises; 2 - STEREOISOMERISM; 2-1 Classification of Structural Isomerism Enantiomeric and Diastereomeric Relationships; 2-2 Optical Activity; 2-3 Diastereomers and Racemic Forms; 2-4 Torsional Stereoisomerism 327 $a2-5 Stereoisomerism Resulting from Asymmetric Atoms Designation of Configuration at Asymmetric Atoms2-6 Torsional Stereoisomerism in the Presence of Asymmetric Atoms; 2-7 Macromolecules; 2-8 Topological Isomerism; 2-9 Exercises; 3 - SEPARATION AND CONFIGURATION OF STEREOISOMERS; 3-1 Separation of Enantiomers and Diastereomers; 3-2 Optical Activation; 3-3 Asymmetric Synthesis and Kinetic Resolution; 3-4 Absolute Configuration; 3-5 Configurational Correlations by Chemical Methods; 3-6 Configurational Correlations by Physical Methods; 3-7 Exercises; ANSWERS TO EXERCISES; BIBLIOGRAPHY; INDEX 330 $a Molecular shape, form, and symmetry play a central role in organic chemistry, and this text presents a brief introduction to the conceptual basis of stereochemistry. Its focus lies in the fundamentals of structural stereochemistry, rather than the dynamic aspects that are more relevant to reaction mechanisms. The three-part treatment deals with structure and symmetry, stereoisomerism, and the separation and configuration of stereoisomers.The first section reviews molecular architecture, relating empirical bonding geometries to the hybridization of the central carbon atom. Students receive a n 410 0$aDover Books on Chemistry 606 $aStereochemistry 606 $aStereochemistry 606 $aChemistry$2HILCC 606 $aPhysical Sciences & Mathematics$2HILCC 606 $aPhysical & Theoretical Chemistry$2HILCC 615 4$aStereochemistry. 615 0$aStereochemistry. 615 7$aChemistry 615 7$aPhysical Sciences & Mathematics 615 7$aPhysical & Theoretical Chemistry 676 $a547/.1223 700 $aMislow$b Kurt Martin$f1923-$01861148 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9911006616203321 996 $aIntroduction to Stereochemistry$94467205 997 $aUNINA