LEADER 05053nam 2200649 450 001 9910144723803321 005 20170810191642.0 010 $a1-282-01020-4 010 $a9786612010200 010 $a3-527-61171-1 010 $a3-527-61170-3 035 $a(CKB)1000000000377519 035 $a(EBL)481992 035 $a(OCoLC)311135073 035 $a(SSID)ssj0000167978 035 $a(PQKBManifestationID)11924611 035 $a(PQKBTitleCode)TC0000167978 035 $a(PQKBWorkID)10178920 035 $a(PQKB)10917201 035 $a(MiAaPQ)EBC481992 035 $a(EXLCZ)991000000000377519 100 $a20160816h19991999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aHandbook of oligo- and polythiophenes /$fDenis Fichou 210 1$aWeinheim, [Germany] :$cWiley-VCH,$d1999. 210 4$d©1999 215 $a1 online resource (560 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29445-7 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aHandbook of Oligo- and Polythiophenes; Contents; 1 The Chemistry of Conducting Polythiophenes: from Synthesis to Self-Assembly to Intelligent Materials; 1.1 Introduction; 1.2 Chemical Synthesis of Unsubstituted Polythiophene (PT); 1.3 Chemcial Synthesis of Polyalkylthiophenes (PATs); 1.3.1 Straight Alkyl Side Chains; 1.3.1.1 Chemical Synthesis of PATs; 1.3.1.1.1 Metal Catalyed Cross-coupling Polymerizations; 1.3.1.1.2 FeCl3 Method for the Polymerization of PATs; 1.3.1.2 Comparison of the Above Methods; 1.3.1.3 Regioregular PATs; 1.3.1.3.1 Regioregular HH-TT and TT-HH PATs 327 $a1.3.1.4 Regioregular, Head-to-Tail Coupled PATs1.3.1.4.1 The McCullough Method; 1.3.1.4.2 The Rieke Method; 1.3.1.4.3 The Mechanism and Catalyst Choice; 1.3.1.4.4 NMR Characterization of HT-PAT; 1.3.1.4.5 IR and UV-Vis; 1.3.1.4.6 Self-Assembly, X-ray, and Electrical Conductivity in HT-PATs; 1.3.1.4.7 Other Methods; 1.3.1.4.8 Random Copolymers of Alkyl Thiophenes; 1.3.1.4.9 Head-to-Tail Coupled, Random Copolymers of Alkyl Thiophenes; 1.3.1.5 Branched Alkyl PATs; 1.3.1.6 PTs with Phenyl Sidechains 327 $a1.4 Chemical Synthesis of Heteroatomic Functionalized Substituents on PTs: Recognition Sites for Self-Assembly and Chemical Sensing1.4.1 Chemical Synthesis of Alkoxy Polythiophenes; 1.4.2 Chemical Prepared Alkoxy PTs as Conducting Polymer Sensors; 1.4.3 Chiral Substituents on PT; 1.4.4 Carboxylic Acid Derivatives: Self-Assembly and Sensors; 1.4.5 Other Derivatives of PT; 1.5 Fused Rings Systems; 1.6 Conclusion; References; 2 Electronic Properties of Polythiophenes; 2.1 General Aspects of Conducting Polymers; 2.2 Structure and Conformation of Polythiophenes 327 $a2.2.1 Morphology and Crystal Structure2.2.2 Conformational Features; 2.3 Electronic Processes of Polythiophenes; 2.3.1 Charge Excitations in Polythiophenes; 2.3.2 Charge Transport in Polythiophenes; 2.3.3 Carrier Recombination: Photoluminescence and Electroluminescence; 2.3.4 Spectroscopic Studies of the Charged States; 2.3.4.1 Charge Storage Configurations in Solids and their Anisotropic Properties; 2.3.4.2 Properties in Solutions; 2.4 Concluding Remarks and Future Outlook; Acknowledgments; References; 3 The Synthesis of Oligothiphenes; 3.1 Introduction; 3.2 Synthesis of Oligothiophenes 327 $a3.2.1 Unsubstituted Oligothiphenes3.2.1.1 Arene/arene-Coupling Methods by Oxidative Couplings; 3.2.1.2 Transition Metal Catalyzed Coupling Methods; 3.2.1.3 Ring Closure Reactions from Acyclic Precursors; 3.2.1.4 Physical Properties of ?-Oligothiophenes and Isomers; 3.2.2 Substituted Oligothiophenes; 3.2.2.1 ß,ß-Substituted Oligothiophenes; 3.2.2.2 ?,?'-Substituted Oligothiophenes; 3.2.2.3 ?,?-Substituted Oligothiophenes; 3.2.2.4 Functionalized Oligothiophenes; 3.2.2.5 Amphiphilic Oligothiophenes; 3.2.2.6 Transition Metal Complexes of Oligothiophenes; 3.3 Conclusion; Acknowledgement 327 $aReferences 330 $aThis first concise handbook on this important new class of organic conducting materials gives a broad survey over this emerging field of research.The physical background is covered as well as the synthesis, electronic and nonlinear optical properties and applications of these advanced materials. This information will be of high value for graduate students, researchers and practitioners working in the interdisciplinary field of materials science, polymer and organic chemistry and applied physics. 606 $aThiophenes 606 $aPolythiophenes 608 $aElectronic books. 615 0$aThiophenes. 615 0$aPolythiophenes. 676 $a547.594 676 $a547.7 700 $aFichou$b Denis$0958311 701 $aFichou$b Denis$0958311 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144723803321 996 $aHandbook of oligo- and polythiophenes$92171220 997 $aUNINA LEADER 02713nam 2200661Ia 450 001 9911004892803321 005 20251116210055.0 010 $a9786613085085 010 $a9781283085083 010 $a1283085089 010 $a9781935308348 010 $a1935308343 035 $a(CKB)2560000000015393 035 $a(EBL)690475 035 $a(OCoLC)667271535 035 $a(SSID)ssj0000427284 035 $a(PQKBManifestationID)11306269 035 $a(PQKBTitleCode)TC0000427284 035 $a(PQKBWorkID)10406935 035 $a(PQKB)11059883 035 $a(MiAaPQ)EBC690475 035 $a(MiAaPQ)EBC686347 035 $a(Au-PeEL)EBL690475 035 $a(CaPaEBR)ebr10404250 035 $a(CaONFJC)MIL308508 035 $a(Perlego)532578 035 $a(Au-PeEL)EBL686347 035 $a(EXLCZ)992560000000015393 100 $a20100210d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe right to earn a living $eeconomic freedom and the law /$fTimothy Sandefur 205 $a1st ed. 210 $aWashington, D.C. $cCato Institute$d2010 215 $a1 online resource (399 p.) 300 $aDescription based upon print version of record. 311 08$a9781935308331 311 08$a1935308335 320 $aIncludes bibliographical references and index. 327 $aTable of Contents; Acknowledgments; Preface; 1. "The Most Precious Liberty Man Possesses"; 2. "Corporations" and "Monopolies,"Part I: 1602-1870; 3. "Corporations" and "Monopolies,"Part II: 1870 to the Present; 4. The Contracts Clause: Victim of the Living Constitution; 5. The Era of Substantive Due Process: Slaughterhouse to Lochner; 6. The Rational Basis Test; 7. Protectionism and the Law; 8. The Dormant Commerce Clause; 9. Commercial Speech; 10. The Manipulation of Contracts; 11. The Abuse of Tort Law; 12. Regulatory Takings; 13. The Future of Economic Liberty; Notes; Index 327 $aAbout the AuthorCato Institute 330 $aExplores the legal and constitutional history of the right to earn a living without unreasonable government interference, and reveals the many ways in which that right is threatened today. 606 $aEconomic liberties (U.S. Constitution) 606 $aConstitutional law$xEconomic aspects$zUnited States 615 0$aEconomic liberties (U.S. Constitution) 615 0$aConstitutional law$xEconomic aspects 676 $a342.7308/5 700 $aSandefur$b Timothy$01648916 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911004892803321 996 $aThe right to earn a living$94388088 997 $aUNINA