LEADER 02712nam 2200673Ia 450 001 9911004764103321 005 20200520144314.0 010 $a9781628708752 010 $a1628708751 010 $a9781849730754 010 $a184973075X 035 $a(CKB)2530000000001307 035 $a(EBL)1185871 035 $a(OCoLC)642189066 035 $a(SSID)ssj0000448015 035 $a(PQKBManifestationID)12128545 035 $a(PQKBTitleCode)TC0000448015 035 $a(PQKBWorkID)10384343 035 $a(PQKB)10223543 035 $a(MiAaPQ)EBC1185871 035 $a(PPN)198467028 035 $a(MiAaPQ)EBC7424564 035 $a(Au-PeEL)EBL7424564 035 $a(Perlego)786562 035 $a(EXLCZ)992530000000001307 100 $a20090813d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aOrganic synthesis using samarium diiodide $ea practical guide /$fDavid J. Procter, Robert A. Flowers, Troels Skrydstrup 205 $a1st ed. 210 $aCambridge $cRoyal Society of Chemistry$d2010 215 $a1 online resource (221 p.) 300 $aDescription based upon print version of record. 311 08$a9781847551108 311 08$a1847551106 320 $aIncludes bibliographical references and index. 327 $a9781847551108; i_iv; v_vi; vii; viii; ix_xiii; xiv_xvi; 001_004; 005_019; 020_035; 036_068; 069_144; 145_156; 157_197; 198_204 330 $aSamarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectiv 606 $aSamarium 606 $aSamarium$xReactivity 606 $aOrganic compounds$xSynthesis 615 0$aSamarium. 615 0$aSamarium$xReactivity. 615 0$aOrganic compounds$xSynthesis. 676 $a546.415 700 $aProcter$b David J$01822361 701 $aFlowers$b Robert A$01822362 701 $aSkrydstrup$b Troels$01822363 712 02$aRoyal Society of Chemistry (Great Britain) 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911004764103321 996 $aOrganic synthesis using samarium diiodide$94388524 997 $aUNINA