LEADER 04089nam 22005774a 450 001 9911004743303321 005 20200520144314.0 010 $a1-281-05471-2 010 $a9786611054717 010 $a0-08-052922-4 035 $a(CKB)1000000000383933 035 $a(EBL)313598 035 $a(OCoLC)246683387 035 $a(SSID)ssj0000123972 035 $a(PQKBManifestationID)11147698 035 $a(PQKBTitleCode)TC0000123972 035 $a(PQKBWorkID)10015319 035 $a(PQKB)11322104 035 $a(MiAaPQ)EBC313598 035 $a(EXLCZ)991000000000383933 100 $a20011005d2001 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aCO? in seawater $eequilibrium, kinetics, isotopes /$fRichard E. Zeebe and Dieter Wolf-Gladrow. 210 $aAmsterdam ;$aNew York $cElsevier$d2001 215 $a1 online resource (xiii, 346 pages) $cillustrations 225 1 $aElsevier oceanography series,$x0422-9894 ;$v65 311 0 $a0-444-50579-2 320 $aIncludes bibliographical references (p. 313-340) and index. 327 $aCover; Contents; Chapter 1. Equilibrium; 1.1 The carbonate system; 1.2 Alkalinity; 1.3 pH scales; 1.4 Partial pressure and fugacity; 1.5 The Revelle factor; 1.6 Worked out problems; Chapter 2. Kinetics; 2.1 Basic concepts of kinetics; 2.2 Temperature dependence of rate constants; 2.3 Reactions and rate constants of the carbonate system; 2.4 Approaching equilibrium: the carbonate system; 2.5 Approaching isotopic equilibrium: 12C, 13C, and 14C; 2.6 Diffusion and Reaction; 2.7 Summary; Chapter 3. Stable Isotope Fractionation; 3.1 Notation, abundances, standards; 3.2 Carbon; 3.3 Oxygen; 3.4 Boron 327 $a3.5 Thermodynamic properties of isotopic substances; Appendix A: Equilibrium constants; A.1 CO2: Acidity constants K1* and K2*; A.2 Acidity constant of true carbonic acid; A.3 CO2 solubility in water (Henry's law); A.4 Ion product of water: KW*; A.5 Bisulfate ion; A.6 Hydrogen fluoride; A.7 Boric acid; A.8 Phosphoric acid; A.9 Silicic acid; A.10 Solubility product of calcite and aragonite; A.11 Effect of pressure on equilibrium constants; A.12 Chemical composition of seawater; A.13 The equation of state of seawater; Appendix B: From two to six; Appendix C: Details and Calculations 327 $aC.1 Total alkalinity and charge balance; C.2 Saturation vapor pressure of water; C.3 The fugacity of a pure gas; C.4 Equilibrium at air-sea interface and chemical potential; C.5 Change CO2 concentration while keeping pH constant; C.6 The rate constant for the hydroxylation of CO2, k+4; C.7 A formula for the equilibration time of CO2; C.8 Kinetic rate laws of the carbonate system; C.9 Derivation of oxygen isotope partitioning; C.10 Mathematical derivation of the partition function ratio; Appendix D: Answers to Exercises; Appendix E: Notation and Symbols; References; Index 330 $aCarbon dioxide is the most important greenhouse gas after water vapor in the atmosphere of the earth. More than 98% of the carbon of the atmosphere-ocean system is stored in the oceans as dissolved inorganic carbon. The key for understanding critical processes of the marine carbon cycle is a sound knowledge of the seawater carbonate chemistry, including equilibrium and nonequilibrium properties as well as stable isotope fractionation. Presenting the first coherent text describing equilibrium and nonequilibrium properties and stable isotope fractionation among the elements 410 0$aElsevier oceanography series ;$v65. 606 $aSeawater$xCarbon dioxide content 606 $aChemical oceanography 615 0$aSeawater$xCarbon dioxide content. 615 0$aChemical oceanography. 676 $a551.46/01 700 $aZeebe$b Richard E$01823931 701 $aWolf-Gladrow$b Dieter A.$f1953-$065509 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911004743303321 996 $aCO? in seawater$94390878 997 $aUNINA