LEADER 04244nam 22006615 450 001 9910992790003321 005 20250407224230.0 010 $a9789819628889 010 $a9819628881 024 7 $a10.1007/978-981-96-2888-9 035 $a(CKB)38184514400041 035 $a(DE-He213)978-981-96-2888-9 035 $a(MiAaPQ)EBC31983363 035 $a(Au-PeEL)EBL31983363 035 $a(EXLCZ)9938184514400041 100 $a20250407d2025 u| 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aPolymer-Based Aqueous-Two Phase Systems $eFundamentals and Applications /$fby Masami Shibukawa 205 $a1st ed. 2025. 210 1$aSingapore :$cSpringer Nature Singapore :$cImprint: Springer,$d2025. 215 $a1 online resource (X, 156 p. 87 illus., 39 illus. in color.) 311 08$a9789819628872 311 08$a9819628873 327 $aIntroduction to Extraction and Chromatography with Polymer-Based Aqueous Two-Phase Systems -- Structures and Properties of the Aqueous Polyethylene Glycol Phases as Extraction Media in ATPS -- Effects of the Background Phase-Forming Electrolytes on the Partition of Ionic Solutes in PEG/Salt ATPS -- Trace Analyses of Metal Ions in Environmental Samples Based on the Separation and Preconcentration by Extraction with ATPS -- Multistep pH-Peak-Focusing Countercurrent Chromatography -- Aqueous Liquid Chromatography with Hydrophilic Polymer Gel Columns -- ATPS Chromatographic Techniques for Separation and Enrichment of Metal Ions and Inorganic Anions: Multistep pH-Peak-Focusing Liquid Chromatography and Partition/Ion-Exclusion Chromatographic Ion Stacking. 330 $aThis book presents the fundamentals of the separation mechanism of the environmentally benign polymer-based aqueous two-phase systems (ATPS) and applications of ATPS to separation and/or enrichment of inorganic compounds with batch extraction and chromatographic techniques. It first describes the structures of the aqueous polymer phases formed in the ATPS. Then the effect of the background electrolyte on the distribution of ionic solutes is discussed. A subsequent chapter shows the applications of the ATPS batch extraction to analyses of trace metal ions in environmental samples. In the following chapter, the author introduces multistep pH-peak-focusing countercurrent chromatography developed for the separation and enrichment of metal ions with a PEG/Na2SO4 ATPS. Lastly, the author explains that liquid chromatography (LC) with hydrophilic polymer gel columns using an aqueous solution as the mobile phase is regarded as an efficient separation and enrichment technique based on ATPS, and describes multi-step pH peak focusing LC and partition/ion-exclusion chromatographic ion stacking (PIEC ion stacking), newly developed ATPS chromatographic techniques for separation and enrichment of metal ions and inorganic anions in detail. This book helps researchers and engineers design and implement appropriate environmentally benign analytical methods for environmental analyses, reagent manufacturers, metal refining industry, and so on. 606 $aSeparation (Technology) 606 $aMaterials$xAnalysis 606 $aEnvironmental chemistry 606 $aChemistry, Inorganic 606 $aPolymers 606 $aSeparation Science 606 $aCharacterization and Analytical Technique 606 $aEnvironmental Chemistry 606 $aInorganic Chemistry 606 $aPolymers 615 0$aSeparation (Technology) 615 0$aMaterials$xAnalysis. 615 0$aEnvironmental chemistry. 615 0$aChemistry, Inorganic. 615 0$aPolymers. 615 14$aSeparation Science. 615 24$aCharacterization and Analytical Technique. 615 24$aEnvironmental Chemistry. 615 24$aInorganic Chemistry. 615 24$aPolymers. 676 $a543.2 700 $aShibukawa$b Masami$4aut$4http://id.loc.gov/vocabulary/relators/aut$01817366 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910992790003321 996 $aPolymer-Based Aqueous-Two Phase Systems$94375107 997 $aUNINA