LEADER 05809nam 2200769Ia 450 001 9910975288703321 005 20251116191859.0 010 $a1-281-05706-1 010 $a9786611057060 010 $a0-08-052601-2 035 $a(CKB)1000000000363657 035 $a(EBL)311285 035 $a(OCoLC)476097568 035 $a(SSID)ssj0000097538 035 $a(PQKBManifestationID)11130677 035 $a(PQKBTitleCode)TC0000097538 035 $a(PQKBWorkID)10120633 035 $a(PQKB)10303511 035 $a(Au-PeEL)EBL311285 035 $a(CaPaEBR)ebr10190030 035 $a(CaONFJC)MIL105706 035 $a(OCoLC)704435579 035 $a(MiAaPQ)EBC311285 035 $a(PPN)152910816 035 $a(EXLCZ)991000000000363657 100 $a19990223d1999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aAdsorption by powders & porous solids $eprinciples, methodology and applications /$fFrancoise Rouquerol, Jean Rouquerol and Kenneth Sing 205 $a1st ed. 210 $aSan Diego $cAcademic Press$dc1999 215 $a1 online resource (485 p.) 300 $a"Centre de Thermodynamique et de Microcalorimetrie du CNRS and Universite de Provence, 26 rue du 141 eme RIA 13003 Marseille, France."--Title page. 311 08$a1-4933-0185-3 311 08$a0-12-598920-2 320 $aIncludes bibliographical references and indexes. 327 $aFront Cover; Adsorption by Powders and Porous Solids: Principles, Methodology and Applications; Copyright Page; Contents; Preface; List of Main Symbols; Chapter 1. Introduction; 1.1. Importance of adsorption; 1.2. Historical aspects; 1.3. General definitions and terminology; 1.4. Physisorption and chemisorption; 1.5. Adsorption interactions; 1.6. Mobility of adsorbed molecules; 1.7. Energetics of physisorption; 1.8. Types of adsorption isotherms; 1.9. Molecular modelling of adsorption; References; Chapter 2. Thermodynamics of Adsorption at the Gas-Solid Interface; 2.1. Introduction 327 $a2.2. Quantitative expression of adsorption2.3. Thermodynamic potentials of adsorption; 2.4. Thermodynamic quantities related to the adsorbed states in the Gibbs representation; 2.5. Thermodynamic quantities related to the adsorption process; 2.6. Indirect derivation of the quantities of adsorption from a series of experimental physisorption isotherms: the isosteric method; 2.7. Derivation of the adsorption quantities from calorimetric data; 2.8. Methods for the determination of differential enthalpies of adsorption; References; Chapter 3. Methodology of Adsorption at the Gas-Solid Interface 327 $a3.1. Introduction3.2. Basic aspects of methodology; 3.3. Operational procedures; 3.4. Details of the operational stages; References; Chapter 4. Interpretation of Physisorption Isotherms at the Gas-Solid Interface; 4.1. Introduction; 4.2. Physisorption isotherms on non-microporous solids; 4.3. Phase changes in physisorbed layers; 4.4. Physisorption by microporous solids; 4.5. Conclusions; References; Chapter 5. Adsorption at the Liquid-Solid Interface: Thermodynamics and Methodology; 5.1. Introduction; 5.2. Energetics of immersion of solid in pure liquid; 5.3. Adsorption from liquid solution 327 $aReferencesChapter 6. Assessment of Surface Area; 6.1. Introduction; 6.2. The BET method; 6.3. Empirical methods of isotherm analysis; 6.4. Adsorption from solution; 6.5. Immersion microcalorimetry; 6.6. The fractal approach; References; Chapter 7. Assessment of Mesoporosity; 7.1. Introduction; 7.2. Capillary condensation and the Kelvin equation; 7.3. Mesopore volume, porosity and mean pore size; 7.4. Computation of the mesopore size distribution; 7.5. Hysteresis loops; 7.6. Density functional formulation; References; Chapter 8. Assessment of Microporosity; 8.1. Introduction 327 $a8.2. Isotherm analysis8.3. Microcalorimetric methods; 8.4. Modelling micropore filling: theory and simulation; References; Chapter 9. Adsorption by Active Carbons; 9.1. Introduction; 9.2. Formation and structure of carbon blacks; 9.3. Physisorption of gases by carbon black and graphite; 9.4. Carbonization and activation; 9.5. Physisorption of gases by activated carbons; 9.6. Immersion microcalorimetry and adsorption from solution; References; Chapter 10. Adsorption by Metal Oxides; 10.1. Introduction; 10.2. Physisorption of gases by silica powders and gels 327 $a10.3. Aluminas: structure, texture and physisorption 330 $aThe declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists, who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeoli 517 3 $aAdsorption by powders and porous solids 606 $aSurface chemistry 606 $aAdsorption 606 $aPowders$xSurfaces 615 0$aSurface chemistry. 615 0$aAdsorption. 615 0$aPowders$xSurfaces. 676 $a541 676 $a541.3/3 21 676 $a541.33 676 $a541.33 700 $aRouquerol$b Franc?oise$0502782 701 $aRouquerol$b J$g(Jean)$0502783 701 $aSing$b K. S. W$01890496 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910975288703321 996 $aAdsorption by powders & porous solids$94532401 997 $aUNINA