LEADER 04446nam 22006854a 450 001 9910971111803321 005 20250609111430.0 010 $a9786610204878 010 $a1-59124-820-5 010 $a1-280-20487-7 024 7 $a10.1007/0-306-46945-6 035 $a(CKB)111056485445092 035 $a(EBL)3035341 035 $a(SSID)ssj0000071356 035 $a(PQKBManifestationID)11110004 035 $a(PQKBTitleCode)TC0000071356 035 $a(PQKBWorkID)10090614 035 $a(PQKB)10087242 035 $a(DE-He213)978-0-306-46945-9 035 $a(OCoLC)55663958 035 $a(MiAaPQ)EBC3035341 035 $a(PPN)237935376 035 $a(MiAaPQ)EBC196900 035 $a(EXLCZ)99111056485445092 100 $a19991103d2000 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aActivation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes /$fby Alexander E. Shilov and Georgiy B. Shul'pin 205 $a1st ed. 2000. 210 $aDordrecht ;$aBoston $cKluwer Academic Publishers$dc2000 215 $a1 online resource (551 p.) 225 1 $aCatalysis by metal complexes ;$vv. 22 300 $aDescription based upon print version of record. 311 08$a0-7923-6101-6 311 08$a0-306-46945-6 320 $aIncludes bibliographical references and index. 327 $aProcesses of C-H Bond Activation -- Hydrocarbon Transformations That do not Involve Metals or Their Compounds -- Heterogeneous Hydrocarbon Reactions with Participation of Solid Metals and Metal Oxides -- Activation of C-H Bonds by Low-valent Metal Complexes (?The Organometallic Chemistry?) -- Hydrocarbon Activation by Metal Ions, Atoms, and Complexes in the Gas Phase and in a Matrix -- Mechanisms of C-H Bond Splitting by Low-valent Metal Complexes -- Activation of Hydrocarbons by Platinum Complexes -- Hydrocarbon Reactions with High-valent Metal Complexes -- Homogeneous Catalytic Oxidation of Hydrocarbons by Molecular Oxygen -- Homogeneous Catalytic Oxidation of Hydrocarbons by Peroxides and Other Oxygen Atom Donors -- Oxidation in Living Cells and its Chemical Models. 330 $ahemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C?H, as well as C?C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the ?noble gases of organic chemistry? and, if so, the first representative of their family ? methane ? may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning ? the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300?500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process ? but not from a chemist viewpoint. 410 0$aCatalysis by metal complexes ;$vv. 22. 606 $aAlkanes 606 $aActivation (Chemistry) 606 $aMetal complexes 606 $aCatalysis 615 0$aAlkanes. 615 0$aActivation (Chemistry) 615 0$aMetal complexes. 615 0$aCatalysis. 676 $a547/.4110459 700 $aShilov$b A. E$g(Aleksandr Evgenevich),$f1930-$01823108 701 $aShulpin$b G. B$g(Georgii Borisovich)$01823109 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910971111803321 996 $aActivation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes$94389587 997 $aUNINA