LEADER 04245nam 2200649Ia 450 001 9910959217603321 005 20251117100917.0 010 $a1-61728-101-8 035 $a(CKB)2670000000388126 035 $a(EBL)3022524 035 $a(SSID)ssj0000915319 035 $a(PQKBManifestationID)11466087 035 $a(PQKBTitleCode)TC0000915319 035 $a(PQKBWorkID)10868369 035 $a(PQKB)11606061 035 $a(MiAaPQ)EBC3022524 035 $a(Au-PeEL)EBL3022524 035 $a(CaPaEBR)ebr10726563 035 $a(OCoLC)923669073 035 $a(BIP)29768814 035 $a(EXLCZ)992670000000388126 100 $a20100504d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aAsymmetric heterogeneous supported catalysis $euse of nitrogen-containing ligands /$fChristine Saluzzo and Stephane Guillarme 205 $a1st ed. 210 $aNew York $cNova Science Publishers$dc2011 215 $a1 online resource (185 p.) 225 1 $aPolymer science and technology 300 $aDescription based upon print version of record. 311 08$a1-61668-680-4 320 $aIncludes bibliographical references and index. 327 $aIntro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers. 327 $aChapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index. 330 $aHomogeneous asymmetric catalysis has been used to perform a variety of transformations under mild conditions with high enantioselectivity. This book discusses the contribution of soluble polymer-supported ligands and insoluble polymer-supported ligands to asymmetric catalysis in the field of reduction. 410 0$aPolymer science and technology series (Nova Science Publishers) 606 $aAsymmetric synthesis 606 $aEnantioselective catalysis 606 $aLigands 606 $aNitrogen compounds 615 0$aAsymmetric synthesis. 615 0$aEnantioselective catalysis. 615 0$aLigands. 615 0$aNitrogen compounds. 676 $a541/.395 700 $aSaluzzo$b Christine$01870790 701 $aGuillarme$b Ste?phane$01870791 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910959217603321 996 $aAsymmetric heterogeneous supported catalysis$94479313 997 $aUNINA