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010   $a9783031686467
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024 7 $a10.1007/978-3-031-68646-7
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035   $a(MiAaPQ)EBC31875819
035   $a(Au-PeEL)EBL31875819
035   $a(DE-He213)978-3-031-68646-7
035   $a(OCoLC)1493029654
035   $a(EXLCZ)9937156002500041
100   $a20250104d2024      u|         0
101 0 $aeng
135   $aur|||||||||||
181   $ctxt$2rdacontent
182   $cc$2rdamedia
183   $acr$2rdacarrier
200 10$aSupramolecular Complexes of Oxoporphyrinogens with Organic Molecules /$fby Václav B?ezina
205   $a1st ed. 2024.
210  1$aCham :$cSpringer Nature Switzerland :$cImprint: Springer,$d2024.
215   $a1 online resource (262 pages)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061
311 08$a9783031686450 
311 08$a3031686454 
327   $aIntroduction -- Quantitative description ofsupramolecular binding -- Nuclear magnetic resonancespectroscopy -- UV/vis spectroscopy -- Singular value decomposition -- Chromic and binding propertiesof OxP derivatives -- Dynamic processes and chemicalexchange in OxP derivatives -- Conclusion.
330   $aMacrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems.
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5061
606   $aAtoms
606   $aMolecules
606   $aNuclear magnetic resonance
606   $aChemical detectors
606   $aAtomic, Molecular and Chemical Physics
606   $aBio- and Macromolecules
606   $aMagnetic Resonance (NMR, EPR)
606   $aSensors
615  0$aAtoms.
615  0$aMolecules.
615  0$aNuclear magnetic resonance.
615  0$aChemical detectors.
615 14$aAtomic, Molecular and Chemical Physics.
615 24$aBio- and Macromolecules.
615 24$aMagnetic Resonance (NMR, EPR).
615 24$aSensors.
676   $a539
700   $aBr?ezina$b Va?clav$01782252
801  0$bMiAaPQ
801  1$bMiAaPQ
801  2$bMiAaPQ
906   $aBOOK
912   $a9910921009303321
996   $aSupramolecular Complexes of Oxoporphyrinogens with Organic Molecules$94308351
997   $aUNINA