LEADER 05291nam 22006134a 450 001 9910877986903321 005 20200520144314.0 010 $a1-280-19704-8 010 $a9786610197040 010 $a0-470-98861-4 010 $a1-4051-4479-3 035 $a(CKB)1000000000341892 035 $a(EBL)233026 035 $a(OCoLC)475939152 035 $a(SSID)ssj0000254830 035 $a(PQKBManifestationID)11213137 035 $a(PQKBTitleCode)TC0000254830 035 $a(PQKBWorkID)10213123 035 $a(PQKB)11234658 035 $a(MiAaPQ)EBC233026 035 $a(EXLCZ)991000000000341892 100 $a20040809d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSynthesis of naturally occurring nitrogen heterocycles from carbohydrates /$fEl Sayed H. El Ashry, Ahmed El Nemr 210 $aOxford, UK ;$aAmes, Iowa $cBlackwell Pub.$d2005 215 $a1 online resource (466 p.) 300 $aDescription based upon print version of record. 311 $a1-4051-2934-4 320 $aIncludes bibliographical references and indexes. 327 $aSynthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates; Contents; Preface; Author details; List of abbreviations and acronyms used in this book; Introduction; 1. Five-membered nitrogen heterocycles; 1.1 Hydroxymethylpyrrolidines; 1.1.1 2-Hydroxymethylpyrrolidines; 1.1.1.1 Synthesis from D-glucose; 1.1.1.2 Synthesis from D-mannose; 1.1.1.3 Synthesis from L-arabinose; 1.1.1.4 Synthesis from D-xylose; 1.1.1.5 Synthesis from D-threose; 1.1.1.6 Synthesis from D-lyxonolactone; 1.1.1.7 Synthesis from D-gulonolactone; 1.1.2 Dihydro-2-hydroxymethylpyrrole (nectrisine) 327 $a1.1.2.1 Synthesis from D-glucose1.1.2.2 Synthesis from D-arabinose; 1.1.2.3 Synthesis from D-glyceraldehyde; 1.1.2.4 Synthesis from L-threitol; 1.1.3 2,5-Dihydroxymethylpyrrolidines; 1.1.3.1 Synthesis from D-glucose; 1.1.3.2 Synthesis from D-glucosamine; 1.1.3.3 Synthesis from D-fructose; 1.1.3.4 Synthesis from L-sorbose; 1.1.3.5 Synthesis from D-arabinose; 1.1.3.6 Synthesis from L-xylose; 1.1.3.7 Synthesis from D-iditol; 1.1.3.8 Synthesis from D-mannitol; 1.1.3.9 Synthesis from D-glucosamic acid; 1.1.3.10 Synthesis from D-glyconolactone; 1.2 2-Carboxypyrrolidines; 1.2.1 Hydroxyprolines 327 $a1.2.1.1 Synthesis from D-glucose1.2.1.2 Synthesis from D-mannitol; 1.2.1.3 Synthesis from L-arabinono- and L-lyxono-lactones; 1.2.1.4 Synthesis from D-ribonolactone; 1.2.1.5 Synthesis from D-gulonolactones; 1.2.1.6 Synthesis from D-gluconolactone; 1.2.1.7 Synthesis from D-glucoronolactone; 1.2.1.8 Synthesis from D-xylonolactone; 1.2.2 Bulgecins; 1.2.2.1 Synthesis from D-glucose; 1.2.2.2 Synthesis from D-glucuronolactone; 1.3 2-Aralkyl pyrrolidines; 1.3.1 (-)-Anisomycin; 1.3.1.1 Synthesis from D-galactose; 1.3.1.2 Synthesis from L-arabinose; 1.3.1.3 Synthesis from D-ribose 327 $a1.3.1.4 Synthesis from L-threose1.3.1.5 Synthesis from L-threitol; 1.3.1.6 Synthesis from D-mannitol; 1.3.2 (+)-Preussin; 1.3.2.1 Synthesis from D-glucose; 1.3.2.2 Synthesis from D-mannose; 1.3.2.3 Synthesis from D-arabinose; 1.4 2-Aryl pyrrolidines; 1.4.1 Codonopsinine and codonopsine; 1.5 Miscellaneous; 1.5.1 Detoxins; 1.5.1.1 Synthesis from D-glucose; 1.5.1.2 Synthesis from L-ascorbic acid; 1.5.2 Gualamycin; 1.5.3 Lactacystin; 2. Five-membered heterocycles with two heteroatoms; 2.1 (+)-Hydantocidin; 2.1.1 Synthesis from D-fructose; 2.1.2 Synthesis from D-ribose 327 $a2.1.3 Synthesis from D-threose2.1.4 Synthesis from D-ribonolactone; 2.2 Bleomycin; 2.2.1 Synthesis from D-glucosamine; 2.2.2 Synthesis from L-rhamnose; 2.2.3 Total synthesis of bleomycin A2; 2.3 Calyculins; 2.3.1 Synthesis from D-lyxose; 2.3.2 Synthesis from D-gulonolactone; 2.3.3 Synthesis from L-idonolactone; 2.3.4 Synthesis from D-ribonolactone; 2.3.5 Synthesis from D-erythronolactone; 2.4 Acivicin; 2.5 Bengazole; 3. Six-membered nitrogen heterocycles; 3.1 Hydroxymethylpiperidines; 3.1.1 Nojirimycin; 3.1.1.1 Synthesis from D-glucose; 3.1.1.2 Synthesis from L-sorbose 327 $a3.1.1.3 Synthesis from L-threose 330 $aCarbohydrates are widely distributed in nature and widely available, and so are considered as a promising feedstock for the preparation of many organic chemical compounds. They are particularly useful in the preparation of nitrogen heterocycles because of their related structural characteristics and easy availability. Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates will review the recent literature dealing with use of carbohydrates as raw materials in the synthesis of these materials. The text contains six chapters arranged according to the comple 606 $aHeterocyclic compounds$xSynthesis 606 $aCarbohydrates 615 0$aHeterocyclic compounds$xSynthesis. 615 0$aCarbohydrates. 676 $a547/.590459 700 $aEl Ashry$b El Sayed H.$f1942-$0969036 701 $aEl-Nemr$b Ahmed$f1962-$0936000 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877986903321 996 $aSynthesis of naturally occurring nitrogen heterocycles from carbohydrates$92201514 997 $aUNINA