LEADER 05153nam 2200613Ia 450 001 9910877876103321 005 20200520144314.0 010 $a1-281-75869-8 010 $a9786611758691 010 $a3-527-61553-9 010 $a3-527-61552-0 035 $a(CKB)1000000000376822 035 $a(EBL)482276 035 $a(OCoLC)261559573 035 $a(SSID)ssj0000120434 035 $a(PQKBManifestationID)11142893 035 $a(PQKBTitleCode)TC0000120434 035 $a(PQKBWorkID)10092814 035 $a(PQKB)11294570 035 $a(MiAaPQ)EBC482276 035 $a(EXLCZ)991000000000376822 100 $a19941123d1995 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aChemical kinetics of solids /$fHermann Schmalzried 210 $aWeinheim ;$aNew York $cVCH$dc1995 215 $a1 online resource (452 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29094-X 320 $aIncludes bibliographical references and indexes. 327 $aChemical Kinetics of Solids; Preface; Table of Contents; Symbols and Definitions; 1 Introduction; 1.1 Scope; 1.2 Historical Remarks; 1.3 Four Basic Kinetic Situations; 1.3.1 Homogeneous Reactions: Point Defect Relaxation; 1.3.2 Steady State Flux of Point Defects in a Binary Compound; 1.3.3 The Kinetics of an Interface Reaction; 1.3.4 Kinetics of Compound Formation: A + B = AB; References; 2 Thermodynamics of Point Defects; 2.1 Introduction; 2.2 Thermodynamics of Crystals; 2.2.1 Phenomenological Approach; 2.2.2 Remarks on Statistical Thermodynamics of Point Defects 327 $a2.3 Some Practical Aspects of Point Defect Thermodynamics2.4 Point Defects in Solid Solutions; 2.5 Conclusions; References; 3 One- and Two-Dimensional Defects in Crystals; 3.1 Introduction; 3.2 Dislocations; 3.2.1 Strain, Stress, and Energy; 3.2.2 Kinetic Effects Due to Dislocations; 3.3 Grain Boundaries; 3.3.1 Structure and Energy of Grain Boundaries; 3.3.2 Phase Boundaries in Solids; 3.4 Mobility of Dislocations, Grain Boundaries, and Phase Boundaries; References; 4 Basic Kinetic Concepts and Situations; 4.1 Introduction; 4.1.1 Systematics of Solid State Chemical Processes 327 $a4.2 The Concepts of Irreversible Thermodynamics4.2.1 Structure Element Fluxes; 4.3 Diffusion; 4.3.1 Introduction; 4.3.2 Fickian Transport; 4.3.3 Chemical Diffusion; 4.4 Transport in Ionic Solids; 4.4.1 Introduction; 4.4.2 Transport in Binary Ionic Crystals AX; 4.5 Transport Across Phase Boundaries; 4.5.1 Introduction. Equilibrium Phase Boundaries; 4.5.2 Non-Equilibrium Phase Boundaries; 4.6 Transport in Semiconductors; Junctions; 4.6.1 Introduction; 4.6.2 The (p-n) Junction; 4.7 Basic Rate Equations for Homogeneous Reactions; 4.7.1 Introduction; 4.7.2 Rate Equations; References 327 $a5 Kinetics and Dynamics. Local Equilibrium5.1 Introduction; 5.1.1 Linear Response; 5.1.2 Transition State; 5.1.3 Brownian Motion; 5.2 Kinetic Parameters and Dynamics; 5.2.1 Phenomenological Coefficients and Kinetic Theory; 5.2.2 Correlation of Atomic Jumps; 5.2.3 Conductivity of Ionic Crystals: Frequency Dependence; 5.2.4 Diffusive Motion and Phonons; 5.3 Relaxation of Irregular Structure Elements; 5.3.1 Introduction; 5.3.2 Relaxation of Structure Elements in Nonstoichiometric Compounds A1-?0; 5.3.3 Relaxation of Intrinsic Disorder; 5.4 Defect Equilibration During Interdiffusion 327 $a5.4.1 The Atomistics of Interdiffusion5.4.2 The Kirkendall Effect; 5.4.3 Local Defect Equilibration During Interdiffusion; 5.4.4 Interdiffusion of Heterovalent Compounds; References; 6 Heterogeneous Solid State Reactions; 6.1 Introduction; 6.2 Nucleation and Initial Growth; 6.2.1 Introductory Remarks; 6.2.2 Nucleation Kinetics; 6.2.3 Early Growth; 6.3 Compound Formation; 6.3.1 Formation Kinetics of Double Salts; 6.3.2 Formation of Multiphase Products; 6.4 Displacement Reactions; 6.5 Powder Reactions; 6.5.1 General; 6.5.2 Self-propagating Exothermic Powder Reactions; 6.6 Interface Rate Control 327 $a6.7 Thermal Decomposition of Solids 330 $aMany different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available.The topics covered in this book go far beyond diffusional tra 606 $aSolid state chemistry 606 $aChemical kinetics 615 0$aSolid state chemistry. 615 0$aChemical kinetics. 676 $a541.0421 676 $a541.394 700 $aSchmalzried$b Hermann$018113 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877876103321 996 $aChemical kinetics of solids$92002551 997 $aUNINA