LEADER 05285nam 2200649Ia 450 001 9910877873203321 005 20200520144314.0 010 $a1-280-51967-3 010 $a9786610519675 010 $a3-527-60355-7 010 $a3-527-60432-4 035 $a(CKB)1000000000376378 035 $a(EBL)481881 035 $a(OCoLC)68572109 035 $a(SSID)ssj0000206602 035 $a(PQKBManifestationID)11168983 035 $a(PQKBTitleCode)TC0000206602 035 $a(PQKBWorkID)10227012 035 $a(PQKB)11400277 035 $a(MiAaPQ)EBC481881 035 $a(EXLCZ)991000000000376378 100 $a20060808d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMultimetallic catalysts in organic synthesis /$fedited by Masakatsu Shibasaki and Yoshinori Yamamoto 210 $aWeinheim ;$a[Great Britain] $cWiley-VCH$dc2004 215 $a1 online resource (313 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30828-8 320 $aIncludes bibliographical references and index. 327 $aMultimetallic Catalysts in Organic Synthesis; Contents; Preface; List of Contributors; 1 Organic Synthesis with Bimetallic Systems; 1.1 Introduction; 1.2 Reactions Promoted by a Combination of Catalytic and Stoichiometric Amounts of Metals; 1.2.1 Transition Metal-Catalyzed Cross-Coupling Reactions; 1.2.2 The Wacker Reaction; 1.2.3 The Heck Reaction; 1.2.4 Reactions Involving ?-Allylpalladium Intermediates; 1.2.4.1 Electrophilic Reactions; 1.2.4.2 Nucleophilic Reactions; 1.2.5 Nickel-Catalyzed Three-Component Coupling Reaction; 1.2.6 The Nozaki-Hiyama-Kishi Reaction 327 $a1.3 Reactions Promoted by a Combination of Catalytic Amounts of Two Metals1.3.1 Transition Metal Catalyzed Cross-Coupling Reactions; 1.3.1.1 The Stille Reaction; 1.3.1.2 The Hiyama Reaction; 1.3.1.3 The Sonogashira Reaction; 1.3.2 The Wacker Reaction; 1.3.3 Reactions Involving ?-Allylpalladium Intermediates; 1.3.4 Transition Metal Catalyzed Cyclization Reactions; 1.3.4.1 [3+2] Cycloaddition Reactions; 1.3.4.2 Intramolecular [n+2] Cyclization Reactions; 1.3.4.3 Intermolecular [n+2+2] Cyclotrimerization Reactions; 1.3.4.4 [2+2+1] Cycloaddition Reactions; The Pauson-Khand Reaction 327 $a1.3.4.5 Cycloisomerization Reactions1.3.4.6 Indole-Forming Reaction; 1.3.4.7 Furan- and Pyrrole-Forming Reactions; 1.3.5 Reactions Involving Nucleophilic Addition of Carbonyl Compounds; 1.3.5.1 The Aldol Reaction; 1.3.5.2 Alkynylation Reactions; 1.3.5.3 Conjugate Addition Reactions; 1.3.6 Miscellaneous Reactions; 1.3.6.1 Transition Metal Catalyzed Reactions; 1.3.6.2 Lewis Acid Catalyzed Reactions; 1.3.6.3 Sequential Reactions; References; 2 Zinc Polymetallic Asymmetric Catalysis; 2.1 Introduction; 2.2 Asymmetric Alternating Copolymerization with Dimeric Zn Complexes 327 $a2.3 Direct Catalytic Asymmetric Aldol Reaction with Zn Polymetallic Catalysts2.3.1 Introduction; 2.3.2 Direct Catalytic Asymmetric Aldol Reaction with Methyl Ketones; 2.3.3 Direct Catalytic Asymmetric Aldol Reaction with ?-Hydroxy Ketones; 2.4 Direct Catalytic Asymmetric Mannich-Type Reactions; 2.5 Direct Catalytic Asymmetric Michael Reaction; 2.6 Nitroaldol (Henry) Reaction; 2.7 Conclusions; References; 3 Group 13-Alkali Metal Heterobimetallic Asymmetric Catalysis; 3.1 Introduction; 3.2 Catalytic Asymmetric Michael Reaction of Stabilized Carbon Nucleophiles 327 $a3.2.1 Development of ALB - The First Example of a Group 13-Alkali Metal Heterobimetallic Asymmetric Catalyst3.2.2 Development of the Second-Generation Heterobimetallic Catalysts - Self-Assembly of Heterobimetallic Catalysts and Reactive Nucleophiles; 3.3 Catalytic Asymmetric Ring-Opening Reaction of meso-Epoxides; 3.3.1 Ring-Opening Reaction with Thiols; 3.3.2 Ring-Opening Reaction with Phenolic Oxygen - Development of a Novel Linked-BINOL Complex; 3.4 Catalytic Asymmetric Mannich Reactions; 3.4.1 Direct Catalytic Asymmetric Mannich-Type Reaction of Unmodified Ketones 327 $a3.4.2 Enantio- and Diastereoselective Catalytic Nitro-Mannich Reactions 330 $aThis first book to comprehensively cover this hot topic presents the information hitherto scattered throughout smaller reviews or single book chapters to provide an introduction to this rapidly expanding field. In ten chapters, the international team of expert authors treats asymmetric syntheses, new transformations, and organometallic reactions using homo- and hetero-bimetallic catalysts. Written for advanced researchers, this very timely publication is of significant benefit to organic and organometallic chemists in both academia and industry. 606 $aOrganic compounds$xSynthesis 606 $aMetal catalysts 615 0$aOrganic compounds$xSynthesis. 615 0$aMetal catalysts. 676 $a547.1395 676 $a547.2 686 $a35.52$2bcl 686 $a35.17$2bcl 701 $aShibasaki$b Masakatsu$066604 701 $aYamamoto$b Y$g(Yoshinori)$092790 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877873203321 996 $aMultimetallic catalysts in organic synthesis$94201888 997 $aUNINA