LEADER 05151nam 2200637 a 450 001 9910877742303321 005 20200520144314.0 010 $a1-280-27132-9 010 $a9786610271320 010 $a0-470-30890-7 010 $a0-470-86150-9 010 $a0-470-86151-7 035 $a(CKB)111087027140028 035 $a(EBL)155659 035 $a(OCoLC)52595638 035 $a(SSID)ssj0000180884 035 $a(PQKBManifestationID)11165467 035 $a(PQKBTitleCode)TC0000180884 035 $a(PQKBWorkID)10158138 035 $a(PQKB)10187292 035 $a(MiAaPQ)EBC155659 035 $a(EXLCZ)99111087027140028 100 $a20031217d2003 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aInterfacial supramolecular assemblies /$fJohannes G. Vos, Robert J. Forster, Tia E. Keyes 210 $aChichester ;$aHoboken, NJ $cWiley$dc2003 215 $a1 online resource (331 p.) 300 $aDescription based upon print version of record. 311 $a0-471-49071-7 320 $aIncludes bibliographical references and index. 327 $aINTERFACIAL SUPRAMOLECULAR ASSEMBLIES; Acknowledgments; Contents; 1 Introduction; 1.1 Introductory Remarks; 1.2 Interfacial Supramolecular Chemistry; 1.3 Objectives of this Book; 1.4 Testing Contemporary Theory Using ISAs; 1.5 Analysis of Structure and Properties; 1.6 Formation and Characterization of Interfacial Supramolecular Assemblies; 1.7 Electron and Energy Transfer Properties; 1.8 Interfacial Electron Transfer Processes at Modified Semiconductor Surfaces; Further Reading; 2 Theoretical Framework for Electrochemical and Optical Processes; 2.1 Introduction; 2.2 Electron Transfer 327 $a2.2.1 Homogenous Electron Transfer2.2.2 Heterogeneous Electron Transfer; 2.3 Photoinduced Processes; 2.3.1 Photochemistry and Photophysics of Supramolecular Materials; 2.3.2 Photoinduced Electron Transfer; 2.3.3 Photoinduced Energy Transfer; 2.3.4 Photoinduced Molecular Rearrangements; 2.4 Photoinduced Interfacial Electron Transfer; 2.4.1 Dye-Sensitized Photoinduced Electron Transfer at Metal Surfaces; 2.4.2 Dye-Sensitized Photoinduced Electron Transfer at Semiconductor Surfaces; 2.4.3 Photoinduced Interfacial Energy Transfer; 2.5 Elucidation of Excited-State Mechanisms; 2.6 Conclusions 327 $aReferences and Notes3 Methods of Analysis; 3.1 Structural Characterization of Interfacial Supramolecular Assemblies; 3.1.1 Scanning Probe Microscopy; 3.1.2 Scanning Electrochemical Microscopy; 3.1.3 Contact Angle Measurements; 3.1.4 Mass-Sensitive Approaches; 3.1.5 Ellipsometry; 3.1.6 Surface Plasmon Resonance; 3.1.7 Neutron Reflectivity; 3.2 Voltammetric Properties of Interfacial Supramolecular Assemblies; 3.2.1 Electrochemical Properties of an Ideal Redox-Active Assembly; 3.2.2 The Formal Potential; 3.2.3 Effect of Lateral Interactions; 3.2.4 Diffusional Charge Transport through Thin Films 327 $a3.2.5 Rotating Disk Voltammetry3.2.6 Interfacial Capacitance and Resistance; 3.3 Spectroscopic Properties of Interfacial Supramolecular Assemblies; 3.3.1 Luminescence Spectroscopy; 3.3.2 Fluorescence Depolarization; 3.3.3 Epifluorescent and Confocal Microscopy; 3.3.4 Near-Field Scanning Optical Microscopy; 3.3.5 Raman Spectroscopy; 3.3.6 Second Harmonic Generation; 3.3.7 Single-Molecule Spectroscopy; 3.3.8 Spectroelectrochemistry; 3.3.9 Intensity-Modulated Photocurrent Spectroscopy; 3.4 Time-Resolved Spectroscopy of Interfacial Supramolecular Assemblies; 3.4.1 Flash Photolysis 327 $a3.4.2 Time-Resolved Luminescence Techniques3.4.3 Femtochemistry; 3.5 Conclusions; References; 4 Formation and Characterization of Modified Surfaces; 4.1 Introduction; 4.2 Substrate Choice and Preparation; 4.3 Formation of Self-Assembled Monolayers; 4.3.1 Solution-Phase Deposition; 4.3.2 Electrochemical Stripping and Deposition; 4.3.3 Thermodynamics of Adsorption; 4.3.4 Double-Layer Structure; 4.3.5 Post-Deposition Modification; 4.4 Structural Characterization of Monolayers; 4.4.1 Packing and Adsorbate Orientation; 4.4.2 Surface Properties; 4.5 Electrochemical Characterization 327 $a4.5.1 General Voltammetric Properties of Redox-Active Monolayers 330 $aDescribes the supramolecular properties of molecular assemblies that contain a solid phase, offering an integrated approach to measurement and addressibility. * Offers an integrated approach to measurement and addressibility.* Features case studies describing the major devices developed using this technology.* The prospects for the future of interfacial supramolecular assemblies are considered. 606 $aSupramolecular chemistry 606 $aSurface chemistry 615 0$aSupramolecular chemistry. 615 0$aSurface chemistry. 676 $a547.7 700 $aVos$b Johannes G$01762160 701 $aForster$b Robert J$0210849 701 $aKeyes$b Tia E$01762161 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877742303321 996 $aInterfacial supramolecular assemblies$94201936 997 $aUNINA