LEADER 05354nam 2200661Ia 450 001 9910877657103321 005 20200520144314.0 010 $a1-280-92171-4 010 $a9786610921713 010 $a3-527-61100-2 010 $a3-527-61101-0 035 $a(CKB)1000000000376508 035 $a(EBL)481337 035 $a(SSID)ssj0000165598 035 $a(PQKBManifestationID)11162878 035 $a(PQKBTitleCode)TC0000165598 035 $a(PQKBWorkID)10143400 035 $a(PQKB)11600979 035 $a(MiAaPQ)EBC481337 035 $a(OCoLC)181349576 035 $a(PPN)19060655X 035 $a(EXLCZ)991000000000376508 100 $a20060529d2007 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aGreen chemistry and catalysis /$fRoger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld 210 $aWeinheim $cWiley-VCH$dc2007 215 $a1 online resource (451 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30715-X 320 $aIncludes bibliographical references and index. 327 $aGreen Chemistry and Catalysis; Contents; Preface; Foreword; 1 Introduction: Green Chemistry and Catalysis; 1.1 Introduction; 1.2. E Factors and Atom Efficiency; 1.3 The Role of Catalysis; 1.4 The Development of Organic Synthesis; 1.5 Catalysis by Solid Acids and Bases; 1.6 Catalytic Reduction; 1.7 Catalytic Oxidation; 1.8 Catalytic C-C Bond Formation; 1.9 The Question of Solvents: Alternative Reaction Media; 1.10 Biocatalysis; 1.11 Renewable Raw Materials and White Biotechnology; 1.12 Enantioselective Catalysis; 1.13 Risky Reagents; 1.14 Process Integration and Catalytic Cascades; References 327 $a2 Solid Acids and Bases as Catalysts2.1 Introduction; 2.2 Solid Acid Catalysis; 2.2.1 Acidic Clays; 2.2.2 Zeolites and Zeotypes: Synthesis and Structure; 2.2.3 Zeolite-catalyzed Reactions in Organic Synthesis; 2.2.3.1 Electrophilic Aromatic Substitutions; 2.2.3.2 Additions and Eliminations; 2.2.3.3 Rearrangements and Isomerizations; 2.2.3.4 Cyclizations; 2.2.4 Solid Acids Containing Surface SO(3)H Functionality; 2.2.5 Heteropoly Acids; 2.3 Solid Base Catalysis; 2.3.1 Anionic Clays: Hydrotalcites; 2.3.2 Basic Zeolites; 2.3.3 Organic Bases Attached to Mesoporous Silicas; 2.4 Other Approaches 327 $aReferences3 Catalytic Reductions; 3.1 Introduction; 3.2 Heterogeneous Reduction Catalysts; 3.2.1 General Properties; 3.2.2 Transfer Hydrogenation Using Heterogeneous Catalysts; 3.2.3 Chiral Heterogeneous Reduction Catalysts; 3.3 Homogeneous Reduction Catalysts; 3.3.1 Wilkinson Catalyst; 3.3.2 Chiral Homogeneous Hydrogenation Catalysts and Reduction of the C= C Double Bond; 3.3.3 Chiral Homogeneous Catalysts and Ketone Hydrogenation; 3.3.4 Imine Hydrogenation; 3.3.5 Transfer Hydrogenation using Homogeneous Catalysts; 3.4 Biocatalytic Reductions; 3.4.1 Introduction 327 $a3.4.2 Enzyme Technology in Biocatalytic Reduction3.4.3 Whole Cell Technology for Biocatalytic Reduction; 3.5 Conclusions; References; 4 Catalytic Oxidations; 4.1 Introduction; 4.2 Mechanisms of Metal-catalyzed Oxidations: General Considerations; 4.2.1 Homolytic Mechanisms; 4.2.1.1 Direct Homolytic Oxidation of Organic Substrates; 4.2.2 Heterolytic Mechanisms; 4.2.2.1 Catalytic Oxygen Transfer; 4.2.3 Ligand Design in Oxidation Catalysis; 4.2.4 Enzyme Catalyzed Oxidations; 4.3 Alkenes; 4.3.1 Epoxidation; 4.3.1.1 Tungsten Catalysts; 4.3.1.2 Rhenium Catalysts; 4.3.1.3 Ruthenium Catalysts 327 $a4.3.1.4 Manganese Catalysts4.3.1.5 Iron Catalysts; 4.3.1.6 Selenium and Organocatalysts; 4.3.1.7 Hydrotalcite and Alumina Systems; 4.3.1.8 Biocatalytic Systems; 4.3.2 Vicinal Dihydroxylation; 4.3.3 Oxidative Cleavage of Olefins; 4.3.4 Oxidative Ketonization; 4.3.5 Allylic Oxidations; 4.4 Alkanes and Alkylaromatics; 4.4.1 Oxidation of Alkanes; 4.4.2 Oxidation of Aromatic Side Chains; 4.4.3 Aromatic Ring Oxidation; 4.5 Oxygen-containing Compounds; 4.5.1 Oxidation of Alcohols; 4.5.1.1 Ruthenium Catalysts; 4.5.1.2 Palladium-catalyzed Oxidations with O(2); 4.5.1.3 Gold Catalysts 327 $a4.5.1.4 Copper Catalysts 330 $aThis first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect:? Numerous catalytic reductions and oxidations methods? Solid-acid and solid-base catalysis? C-C bond formation reactions? Biocatalysis? Asymmetric catalysis? Novel reaction media like e.g. ionic liquids, supercritical CO2? Renewable raw materialsWritten by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable s 606 $aCatalysis 606 $aEnvironmental chemistry$xIndustrial applications 606 $aSustainable development 615 0$aCatalysis. 615 0$aEnvironmental chemistry$xIndustrial applications. 615 0$aSustainable development. 676 $a660.2995 700 $aSheldon$b Roger A$0605461 701 $aArends$b Isabel$0505547 701 $aHanefeld$b Ulf$0505548 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877657103321 996 $aGreen chemistry and catalysis$94203486 997 $aUNINA