LEADER 05217nam 2200673Ia 450 001 9910877523303321 005 20200520144314.0 010 $a1-282-30171-3 010 $a9786612301711 010 $a0-470-18696-8 010 $a0-470-18845-6 035 $a(CKB)1000000000376552 035 $a(EBL)469845 035 $a(OCoLC)814417555 035 $a(SSID)ssj0000365763 035 $a(PQKBManifestationID)11229993 035 $a(PQKBTitleCode)TC0000365763 035 $a(PQKBWorkID)10423072 035 $a(PQKB)10681182 035 $a(MiAaPQ)EBC469845 035 $a(PPN)248095714 035 $a(EXLCZ)991000000000376552 100 $a20720131d1972 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSeven-membered heterocyclic compounds containing oxygen and sulfur /$fedited by Andre Rosowsky 205 $a99th ed. 210 $aNew York $cWiley-Interscience$d1972 215 $a1 online resource (982 p.) 225 1 $aChemistry of heterocyclic compounds ;$vv. 26 300 $aDescription based upon print version of record. 311 $a0-471-38210-8 320 $aIncludes bibliographical references. 327 $aTHE CHEMISTRY OF HETEROCYCLIC COMPOUNDS A SERIES OF MONOGRAPHS; Preface; Contents; Tables; I. Oxepins and Reduced Oxepins; A. OXEPINS; 1. Theoretical Interest; 2. Preparation; 3. Physical Properties; a. Infrared Absorption; b. Ultraviolet Absorption; c. Nuclear Magnetic Resonance; d. Thermodynamic Properties; 4. Chemical Reactions; a. Addendum; B. DIHYDROOXEPINS; 1. Introduction; 2. Preparation; 3. Physical Properties; a. Infrared Absorption; b. Ultraviolet Absorption; c. Nuclear Magnetic Resonance; 4. Chemical Reactions; C. TETRAHYDROOXEPINS; 1. Introduction; 2. Preparation 327 $a3. Physical Propertiesa. Infrared Absorption; b. Nuclear Magnetic Resonance; 4. Chemical Reactions; D. HEXAHYDROOXEPINS (OXEPANS); 1. Preparation; a. Hexamethylene Oxide; b. Substituted Oxepans; (1) Ring Closure Reactions; (2) Ring Expansion Reactions; (3) Two-Component Reactions; 2. Physical Properties of Hexamethylene Oxide; 3. Chemical Reactions of Hexamethylene Oxide; 4. Preparation and Reactions of Cyclic Acetals, Ketals, and Related Compounds; E. TABLES; I-1. Oxepins and Reduced Oxepins; F. REFERENCES; II. Oxepin Ring Systems Containing Two Rings; A. FUSED RINGS SYSTEMS 327 $a1. 2-Oxabicyclo[5.1.0]octanes2. 2-Oxabicyclo[5.2.0]nonanes; 3. 2H-Cyclopent[b]oxepins; 4. 2H-Cyclopent[d]oxepins; 5. Furo[3,4-b]oxepins; 6. Furo[3,4-d]oxepins; 7. 2H-Oxepino[2,3-b]pyrroles; 8. Thieno[3,4-d]oxepins; 9.1-Benzoxepins; a. Synthesis, Chemical Reactions, and Physical Properties of the Parent Compound; b. Synthesis and Chemical Reactions of Dihydro-l-benzoxepins; c. Synthesis and Chemical Reactions of Tetrahydro-l- benzoxepins; d. Synthesis and Chemical Reactions of Other Reduced 1-Benzoxepins; e. Physicochemical Properties of 2,3,4,5-Tetrahydro-1- benzoxepins; 10.2-Benzoxepins 327 $a11. 3-BenzoxepinsB. SPIRANS; 1. 1,7-Dioxaspiro[5.6]dodecanes; 2. 1,4,6-Trioxaspiro[4.6]undecanes; C. BRIDGED SYSTEMS; 1. 2-Oxabicyclo[3.2.2]nonanes; 2. 3-Oxabicyclo[3.2.2]nonanes; 3. 9-Oxabicyclo[3.3.2]decanes; 4. 11-Oxabicyclo[4.4.1]undecanes; a. Partly or Fully Saturated Derivatives; b. 1,6-Oxido[10]annulenes; 5. 3-Oxa-6,7-dithiabicyclo[3.2.2]nonanes; D. TABLES; II-1. Uv Data and Bromination Rate of 2,3,4,5-Tetrahydro-l-benzoxepins and Lower Ring Homologs; II-2. Solvolysis Kinetics of 7-Chloromethyl-2,3,4,5-tetrahydro-l- benzoxepin and Lower Ring Homologs 327 $aII-3. Uv Data and Bromination Rate of 2,3,4,5-Tetrahydro-l- benzoxepin-2-carboxylic Acid and Lower Ring HomologsII-4. Uv Data and Molecular Geometry of 2,3,4,5-Tetrahydro-2-(N,N-dimethylamino)methyl-1-benzoxepin Methobromide and Lower Ring Homologs; II-5. l-Benzoxepins; II-6. 2-Benzoxepins; II-7. 3-Benzoxepins; E. REFERENCES; III. Oxepin Ring Systems Containing Three Rings; A. FUSED RING SYSTEMS; 1. Cyclopenta[5.6]pyrano[4,3-b]oxepins; 2. 8H-1,3-Dioxolo[4,5-h][3]benzoxepins; 3. Dibenz[b,d]oxepins; 4. Dibenz[b,e]oxepins; 5. Dibenz[b,f]oxepins; 6. Dibenz[c,e]oxepins 327 $aa. Dibenz[c,e]oxepin-5,7-diones (Diphenic Anhydrides) 330 $aChemistry of Heterocyclic Compounds publishes articles, letters to the Editor, reviews, and minireviews on the synthesis, structure, reactivity, and biological activity of heterocyclic compounds including natural products. The journal covers investigations in heterocyclic chemistry taking place in scientific centers of all over the world, including extensively the scientific institutions in Russia, Ukraine, Latvia, Lithuania and Belarus. 410 0$aChemistry of heterocyclic compounds ;$vv. 26. 606 $aOxepins 606 $aThiepins 615 0$aOxepins. 615 0$aThiepins. 676 $a547.592 676 $a547/.59/05 676 $a547/.592 701 $aRosowsky$b Andre$093100 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877523303321 996 $aSeven-membered heterocyclic compounds containing oxygen and sulfur$94202330 997 $aUNINA