LEADER 05336nam 2200649Ia 450 001 9910877331303321 005 20200520144314.0 010 $a1-282-30826-2 010 $a9786612308260 010 $a0-470-14531-5 010 $a0-470-14552-8 035 $a(CKB)1000000000376311 035 $a(EBL)468912 035 $a(OCoLC)741345815 035 $a(SSID)ssj0000299747 035 $a(PQKBManifestationID)11204772 035 $a(PQKBTitleCode)TC0000299747 035 $a(PQKBWorkID)10241575 035 $a(PQKB)10652817 035 $a(MiAaPQ)EBC468912 035 $a(EXLCZ)991000000000376311 100 $a19931012d1993 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aReactions catalyzed by inorganic compounds /$ffounding editor J.J. Zuckerman; editor, Arlan D. Norman 210 $aNew York $cVCH$dc1993 215 $a1 online resource (686 p.) 225 0 $aInorganic reactions and methods ;$vv. 16 300 $aDescription based upon print version of record. 311 $a0-471-18666-X 320 $aIncludes bibliographical references and indexes. 327 $aInorganic Reactions and Methods; Contents; How to Use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 16; Reactions Catalyzed by Inorganic Compounds; Introduction: Principles of Catalysis; Catalysis as a Kinetic Phenomenon; Basic Processes in Molecular Catalysis; Electron Transfer; Ligand Dissociation and Association Processes; Heterolytic Ligand Dissociation.; Homolytic Ligand Dissociation.; Promotion of Nucleophilic Reactions by Electron Withdrawal from Reactants; Catalysis of Electrophilic Reactions by Proton Loss from a Coordinated Ligand 327 $aOxidative Addition/Reductive Elimination ReactionsOne-Electron Oxidative Addition.; Two-Electron Oxidative Addition.; Free Radical Chain Mechanism of Oxidative Addition.; Insertion Reactions; Types of Catalysts; Introduction; Solid Catalysts; Metallic Catalysts; Metal Crystals and Films.; Supported Metal Catalysts.; Metal Oxide and Metal Sulfide Catalysts; Soluble Catalysts; Selectivity Advantages; Process Engineering and Product Recovery Problems; Supported Metal Complexes; Polymeric Supports; Metal Oxide Supports; Phase Transfer Catalysis; Catalysis in Microscopic Phases 327 $aProduction of Catalysts and SupportsGeneral Principles; Methods of Production of Nonmetal Catalysts and Supports; Precipitation and Gel Formation.; Impregnation.; Natural Materials, Leaching, Carbon supports.; Methods of Production of Supported Metal Catalysts; Relationships between Catalyst Production and Performance; Hydrogenation Reactions; Introduction; Dihydrogen Activation; Homolytic Cleavage to Give Metal-Hydrides; Heterolytic Cleavage to Give Metal-Hydrides; Molecular Hydrogen Complexes; Classes of Soluble Catalysts; Rhodium(I) Catalysts; Cobalt Cyanide Systems 327 $aCobalt Carbonyl CatalystsChromium(0) Carbonyl Catalysts; Ziegler Catalysts; Ruthenium(lI) Catalysts; Hydrogenation of Aliphatic C-C Functions; In Simple Olefins; Isolated Double Bonds.; Olefins Conjugated to Carbonyl, Nitrile, Nitro.; Vinyl Functions.; In Conjugated Dienes; In Unconjugated Dienes; In Acetylenes and Cumulenes; In Triple Bonds.; In Allenes and Cumulenes.; By Asymmetric Hydrogenation; Hydrogenation of Arenes; By Cobalt Catalysts; By Ruthenium Catalysts; by Rhodium Catalysts; By Palladium and Platinum Catalysts; By Miscellaneous Catalysts; Hydrogenation of C=O Functions 327 $aIn AldehydesSaturated Aliphatic Aldehydes.; Aromatic Aldehydes.; Selectivity.; In Ketones; Hydrogenation to the Carbinol.; Hydrogenolysis and Miscellaneous Reactions.; Selectivity.; Stereochemistry and Asymmetric Hydrogenation.; In Carboxyl Derivatives; By Transfer Hydrogenation; Hydrogenation of Other Functional Groups; Nitrites; Hydrogenation to Primary Amines.; Coupling Reactions.; Reductive Hydrolysis.; Hydrogenolysis and Cyclizations.; Nitro Compounds; Hydrogenation to the Amine.; Selective and Partial Reductions.; Side Reactions in Polyfunctional Molecules.; Miscellaneous 327 $aAddition Reactions 330 $aFor the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.The work is indexed in a unique way by a structured system which maximizes its use 410 0$aInorganic Reactions and Methods 606 $aCatalysis 606 $aChemical reactions 615 0$aCatalysis. 615 0$aChemical reactions. 676 $a541.3/9 676 $a541.395 701 $aZuckerman$b J. J$g(Jerold J.),$f1936-1987.$0857123 701 $aNorman$b Arlen D$01343789 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910877331303321 996 $aReactions catalyzed by inorganic compounds$93068185 997 $aUNINA