LEADER 05167nam 2200661Ia 450 001 9910876692503321 005 20200520144314.0 010 $a1-282-30147-0 010 $a9786612301476 010 $a0-470-18662-3 010 $a0-470-18812-X 035 $a(CKB)1000000000376521 035 $a(EBL)469091 035 $a(SSID)ssj0000366981 035 $a(PQKBManifestationID)11265654 035 $a(PQKBTitleCode)TC0000366981 035 $a(PQKBWorkID)10418497 035 $a(PQKB)11147878 035 $a(MiAaPQ)EBC469091 035 $a(PPN)241335477 035 $a(OCoLC)212119675 035 $a(EXLCZ)991000000000376521 100 $a19831013d1959 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$as-Triazines and derivatives /$fEdwin M. Smolin and Lorence Rapoport 210 $aNew York $cInterscience Publishers$d1959 215 $a1 online resource (670 p.) 225 1 $aThe chemistry of heterocyclic compounds ;$v13 300 $aDescription based upon print version of record. 311 $a0-470-37884-0 320 $aIncludes bibliography. 327 $as-Triazines and Derivatives; Contents; Introduction; I. General; II. s-Triazine; 1. General; 2. Synthesis; 3. Reactions; A. Salt Formation; B. Hydrolysis; C. Reaction with Hydrogen Chloride; D. Reaction with Amines; E. Reaction with Halogens; F. Reaction with Sodamide; G. Hydrogenation; H. Friedel-Crafts Reaction of s-Triazine and Its Hydrochloride Derivatives; I. Grignard Reaction; I. Cyanuric Acid and Derivatives; I. Introduction; II. Cyanuric Acid; 1. Historical; 2. Physical Properties; A. General; B. Density; C. Thermal Properties; D. Heat of Neutralization; E. Dissociation Constant 327 $aF. Percentage Dissociated at 35°G. Conductivity; H. Viscosity and Density of Solutions; I. Specific Heat; J. Magnetic Susceptibility; K. Raman, Infrared, and Ultraviolet Spectra; L. Polarographic Behavior; M. Crystallography and Miscellaneous Properties; 3. Synthesis and Occurrence; A. Natural Occurrence; B. From Cyanuric Halides; C. Polymerization of Cyanic Acid; D. From Urea and Urea Derivatives; E. From Uric Acid; F. From Allophanates and Carbamyl Chlorides; G. From Carbonyl Diurethane and Carbethoxybiuret; H. From Formamide Electrolytically; I. From Acetoxamide 327 $aJ. From Carbaminothioglycolic Acid AnilideK. Miscellaneous Preparations; 4. Structure; 5. Salts of Cyanuric Acid; 6. Reactions of Cyanuric Acid; A. Hydrolysis; B. Reaction with Active Halogen Compounds; C. Thermal Action; D. Reaction with Ammonia; E. Esterification; F. Acetylation; G. Reaction with Fatty Acids; H. Reaction with ?-Haloacids; I. Rearrangement .; 7. Applications of Cyanuric Acid; A. Physiological and Technical Significance; B. Melamine Formation; C. Rubber Manufacture; D. Resins; III. Cyanuric Halides; 1. Cyanuric Chloride; A. History; B. Physical Properties 327 $aC. Synthetic Methods(1) From Cyanogen Chloride; (2) From Hydrocyanic Acid; (3) From Cyanuric Acid; (4) Miscellaneous Methods; D. Structure; E. Reactions; (1) Hydrolysis and Alcoholysis; (2) Reaction with Hydroxy Compounds; (3) Reaction with Amino Compounds; (4) Reaction with Sulfhydryl Compounds; (5) Reaction with Salts of Hydrazoic Acid; (6) Reaction with Silver Nitrate; (7) Grignard Reaction; (8) Wurtz-Fittig Reaction; (9) Friedel-Crafts Reaction; (10) Reaction with Carboxylic Acids and Salts; (11) Reaction with Malonic Ester; (12) Reaction with Hydriodic Acid; (13) Reduction 327 $a(14) Reaction with BenzamideF. Physiological Properties; 2. Cyanuric Bromide; A. Synthesis; (1) Polymerization of Cyanogen Bromide; (2) From Bromine and Potassium Ferrocyanide; B. Reactions and Structure; (1) Hydrolysis; (2) Reaction with Amines; (3) With Acetic Acid; (4) Reaction with Urea; 3. Cyanuric Iodide; 4. Cyanuric Fluoride; 5. 2-Bromo-4,6-dichloro-s-triazine; 6. 2-Chloro-4,6-diiodo-s-triazine; IV. Cyanuric Acid Esters; 1. Alkyl Esters; A. Methyl Esters; (1) Trimethyl Ester; (2) Diethyl Ester; (3) Halomethoxy-s-triazines; (4) Mixed Methyl Esters; B. Ethyl Esters; (1) Triethyl Ester 327 $a(2) Dimethyl Ester 330 $aChemistry of Heterocyclic Compounds publishes articles, letters to the Editor, reviews, and minireviews on the synthesis, structure, reactivity, and biological activity of heterocyclic compounds including natural products. The journal covers investigations in heterocyclic chemistry taking place in scientific centers of all over the world, including extensively the scientific institutions in Russia, Ukraine, Latvia, Lithuania and Belarus. 410 0$aChemistry of heterocyclic compounds. 606 $aTriazines 606 $aHeterocyclic compounds 615 0$aTriazines. 615 0$aHeterocyclic compounds. 676 $a547 676 $a547/.59/05 700 $aSmolin$b Edwin M$0958298 701 $aRapoport$b Lorence$f1919-1999.$0958299 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910876692503321 996 $aS-Triazines and derivatives$92171200 997 $aUNINA