LEADER 05364nam 2200649Ia 450 001 9910876635303321 005 20200520144314.0 010 $a1-282-68623-2 010 $a9786612686238 010 $a3-527-62840-1 010 $a3-527-62378-7 035 $a(CKB)1000000000707864 035 $a(EBL)481468 035 $a(OCoLC)316803727 035 $a(SSID)ssj0000168330 035 $a(PQKBManifestationID)11184183 035 $a(PQKBTitleCode)TC0000168330 035 $a(PQKBWorkID)10192045 035 $a(PQKB)11776905 035 $a(MiAaPQ)EBC481468 035 $a(PPN)152354220 035 $a(EXLCZ)991000000000707864 100 $a20080625d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aHandbook of ring-opening polymerization /$fedited by Philippe Dubois, Olivier Coulembier, and Jean-Marie Raquez 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (428 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31953-0 320 $aIncludes bibliographical references and index. 327 $aHandbook of Ring-Opening Polymerization; Contents; Preface; List of Contributors; 1: Thermodynamics and Kinetics of Ring-Opening Polymerization; 1.1 Introduction; 1.2 Thermodynamics of the Ring-Opening Polymerization; 1.2.1 Equilibrium Monomer Concentration: Ceiling/Floor Temperatures; 1.2.2 Selected Particular Cases; 1.2.2.1 Polymerization in Heterogeneous Systems; 1.2.2.2 Monomer-Polymer-Solvent Interactions; 1.2.2.3 Thermodynamics of Oligomerization; 1.2.3 Thermodynamics of Macrocyclization; 1.2.4 Equilibrium Copolymerization; 1.2.5 Molar Mass Distribution in the Equilibrium Polymerization 327 $a1.3 Kinetics of Ring-Opening Polymerization1.3.1 Thermodynamic and Kinetic Polymerizability; 1.3.2 Kinetics of Living Polymerization; 1.3.2.1 Kinetic Criteria of Living Polymerization; 1.3.2.2 Active Center Interconversions and the Determination of Absolute Rate Constants; 1.3.2.3 Departure from Livingness: Kinetics of Selected Side Reactions; 1.3.2.4 Kinetics of Copolymerization; 1.4 Concluding Remarks; References; 2: General Mechanisms in Ring-Opening Polymerization; 2.1 Introduction; 2.2 Anionic Ring-Opening Polymerization; 2.2.1 General Mechanism; 2.2.2 Activated Monomer Mechanism 327 $a2.3 Cationic Ring-Opening Polymerization2.3.1 General Mechanism; 2.3.2 Activated Monomer Mechanism; 2.3.3 Isomerization Polymerization; 2.4 Radical Ring-Opening Polymerization; 2.5 Summary and Prospects; References; 3: Siloxane-Containing Polymers; 3.1 Introduction; 3.2 Polydimethylsiloxanes; 3.2.1 Anionic Polymerization; 3.2.1.1 General Considerations; 3.2.1.2 Recent Advances; 3.2.2 Cationic Polymerization; 3.2.2.1 General Considerations; 3.2.2.2 Recent Advances; 3.2.3 Emulsion Polymerization; 3.2.3.1 General Considerations; 3.2.3.2 Recent Advances; 3.2.4 Other Processes 327 $a3.3 Functional Silicones3.3.1 Anionic Polymerization; 3.3.1.1 Homopolymerization of Symmetrical Cyclosiloxanes; 3.3.1.2 Homopolymerization of Asymmetrical Cyclosiloxanes; 3.3.1.3 Copolymerization; 3.3.2 Cationic Polymerization; 3.3.2.1 Homopolymerization of Symmetrical Cyclosiloxanes; 3.3.2.2 Homopolymerization of Asymmetrical Cyclosiloxanes; 3.3.2.3 Copolymerization; 3.3.3 Emulsion Polymerization; 3.4 Polycarbosiloxanes; 3.4.1 Five-Atom Rings; 3.4.2 Larger Cyclocarbosiloxanes; 3.5 Summary and Prospects; Acknowledgments; References; 4: Sulfur-Nitrogen-Phosphorus-Containing Polymers 327 $a4.1 Introduction4.2 Mechanism and Methods in Ring-Opening Polymerization (ROP) of Halogenated Cyclotriphosphazenes; 4.3 Ring-Opening Polymerization and Chemistry of Nonhalogenated Phosphazene Rings; 4.4 Incorporation of Sulfur into Phosphazene Ring Systems, and Their Polymerization Chemistry; 4.4.1 Thiophosphazenes; 4.4.2 Thionylphosphazenes; 4.5 Summary and Prospects; Acknowledgments; References; 5: Polymerization of Cyclic Depsipeptides, Ureas and Urethanes; 5.1 Introduction; 5.2 Polydepsipeptides; 5.3 Monomers; 5.4 Ring-Opening Polymerization; 5.5 Enzymatic Polymerization 327 $a5.6 Ring Expansion 330 $aThis comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the 606 $aRing-opening polymerization$vHandbooks, manuals, etc 606 $aPolymers 615 0$aRing-opening polymerization 615 0$aPolymers. 676 $a547.28 676 $a547.7 701 $aDubois$b Philippe$cProf.$091900 701 $aCoulembier$b Olivier$01752757 701 $aRaquez$b Jean-Marie$01752758 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910876635303321 996 $aHandbook of ring-opening polymerization$94188149 997 $aUNINA