LEADER 05399nam 2200673Ia 450 001 9910841396803321 005 20170810181624.0 010 $a1-282-47229-1 010 $a9786612472299 010 $a3-527-62870-3 010 $a3-527-62871-1 035 $a(CKB)2550000000000636 035 $a(EBL)481256 035 $a(SSID)ssj0000359490 035 $a(PQKBManifestationID)11275450 035 $a(PQKBTitleCode)TC0000359490 035 $a(PQKBWorkID)10308665 035 $a(PQKB)10505267 035 $a(MiAaPQ)EBC481256 035 $a(PPN)197085938 035 $a(OCoLC)587391497 035 $a(EXLCZ)992550000000000636 100 $a20000327d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aEpoxy polymers$b[electronic resource] $enew materials and innovations /$fedited by Jean-Pierre Pascault and Roberto J.J. Williams 210 $aWeinheim $cWiley-VCH Verlag GmbH$dc2010 215 $a1 online resource (389 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32480-1 320 $aIncludes bibliographical references and index. 327 $aEpoxy Polymers: New Materials and Innovations; Contents; Preface; List of Contributors; 1: General Concepts about Epoxy Polymers; 1.1 Polymerization Chemistry of Epoxy Monomers; 1.1.1 Typical Epoxy Monomers and Polymer Growth Mechanisms; 1.1.2 Step Growth Polymerization; 1.1.3 Chain Homopolymerization; 1.1.4 Chain Copolymerization; 1.1.5 Dual Polymerization Systems; 1.2 Transformations During the Formation of an Epoxy Network; 1.2.1 General Considerations; 1.2.2 Gelation; 1.2.3 Vitrification; 1.2.4 Reaction-Induced Phase Separation; 1.2.5 Transformation Diagrams 327 $a1.3 General Properties of Epoxy NetworksReferences; Part One: New Polymers/Materials; 2: Thermoplastic Epoxy Polymers; 2.1 Introduction; 2.2 Synthesis and Characterization of Epoxy Thermoplastics; 2.2.1 Poly(hydroxy ethers) and Poly(hydroxy ether sulfides); 2.2.2 Poly(hydroxy ether sulfonamides); 2.2.3 Poly(hydroxy ester ethers); 2.2.4 Poly(hydroxy amino ethers); 2.3 Fundamental Properties of Epoxy Thermoplastics; 2.3.1 Mechanical Behavior; 2.3.2 Adhesive Characteristics; 2.3.3 Optical Properties of Poly(hydroxy amino ether) 19b; 2.3.4 Gas Barrier Properties of Epoxy Thermoplastics 327 $a2.4 ConclusionsAcknowledgments; References; 3: Epoxy Functional Acrylic Polymers for High Performance Coating Applications; 3.1 Introduction; 3.2 Epoxy Functional Acrylic Polymers (Epoxy Acrylates); 3.3 Synthesis of Epoxy Acrylates; 3.3.1 Semi-Batch Process; 3.3.2 Mass Polymerization; 3.3.3 Suspension Polymerization; 3.3.4 Polymerization in Supercritical Carbon Dioxide; 3.4 Design of Epoxy Acrylates as Film-forming Components in Coatings; 3.4.1 Glass Transition Temperature; 3.4.2 Molar Mass; 3.4.3 Choice of Co-monomers; 3.4.4 Epoxy Acrylates with a Dual-Cure 327 $a3.4.5 Structure of the Polymer: Block Copolymers3.4.6 Structure of the Polymer: Branched Epoxy Acrylates; 3.5 Cross-linking Reactions in Coating Systems; 3.5.1 Epoxy Acrylates in Etch-resistant One-Component Liquid Coatings; 3.5.2 Epoxy Acrylates in Powder Coatings; 3.5.3 Epoxy Acrylates in Water - Borne Coatings; 3.6 Conclusions; References; 4: Epoxy Polymers Based on Renewable Resources; 4.1 Introduction; 4.2 Synthesis and Polymerization of Monomers and Macromonomers Bearing Multiple Epoxy Functions; 4.2.1 Vegetable Oils; 4.2.2 Natural Rubber; 4.2.3 Lignin; 4.2.4 Cellulosics and Wood 327 $a4.2.5 Sugars4.2.6 Terpenes; 4.3 Synthesis and Polymerization of Monomers Bearing a Single Epoxy Group; 4.3.1 2-Furyloxirane; 4.3.2 Other Monomers; 4.4 Conclusions; References; Part Two: (Nano)Structured Epoxy Networks; 5: Nanostructured Epoxies by the Use of Block Copolymers; 5.1 Introduction; 5.2 Formation Mechanisms of Nanostructures in Thermosets; 5.2.1 Self-Assembly Approach; 5.2.2 Reaction-Induced Microphase Separation; 5.3 Morphologies of Epoxy Thermosets Modified With Block Copolymers; 5.3.1 Selection of Block Copolymers; 5.3.2 Nanophase Behavior of Epoxies Containing Block Copolymers 327 $a5.3.3 Demixing Behavior of Epoxy-Miscible Blocks Induced by Curing Reaction 330 $aIn the only book to focus on new developments and innovations in this hot field international experts from industry and academia present everything scientists need to know.The first section provides general concepts of the synthesis and properties of epoxy polymers and serves as a basis for the subsequent chapters. The second section includes new types of epoxy polymers recently commercialized or not yet present on the market, while the third section includes chapters related to the capacity of generating controlled nanostructures in epoxy-based materials. A fourth section is devoted to in 606 $aEpoxy compounds 606 $aPolymers 615 0$aEpoxy compounds. 615 0$aPolymers. 676 $a620.192 676 $a668.4226 686 $a660$2sdnb 686 $aVK 8000$2rvk 686 $aZM 5300$2rvk 701 $aPascault$b Jean-Pierre$f1943-$01730264 701 $aWilliams$b Robert J. J$01730265 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910841396803321 996 $aEpoxy polymers$94141127 997 $aUNINA