LEADER 05237nam 2200673Ia 450 001 9910841348803321 005 20230721022543.0 010 $a1-282-68358-6 010 $a9786612683589 010 $a3-527-62705-7 010 $a3-527-62706-5 035 $a(CKB)1000000000790149 035 $a(EBL)481402 035 $a(SSID)ssj0000335699 035 $a(PQKBManifestationID)11273394 035 $a(PQKBTitleCode)TC0000335699 035 $a(PQKBWorkID)10276897 035 $a(PQKB)11181664 035 $a(MiAaPQ)EBC481402 035 $a(OCoLC)705353464 035 $a(EXLCZ)991000000000790149 100 $a20011031d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aChemically modified electrodes$b[electronic resource] /$fedited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (281 p.) 225 1 $aAdvances in electrochemical science and engineering ;$v11 300 $aDescription based upon print version of record. 311 $a3-527-31420-2 320 $aIncludes bibliographical references and index. 327 $aAdvances in Electrochemical Science and Engineering; Contents; Preface; List of Contributors; 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications; 1.1 Introduction; 1.2 High Surface Area Electrodes; 1.2.1 Attachment of Nanoparticles onto Electrodes; 1.2.2 Templating using Membranes; 1.2.3 Templating using Lyotropic Liquid Crystals; 1.2.4 Colloidal Templates; 1.3 Catalytic Properties; 1.4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules; 1.4.1 Plugging Nanomaterials into Proteins - Nanoparticles 327 $a1.4.2 Plugging Nanomaterials into Proteins - Carbon Nanotubes1.4.3 Plugging Nanomaterials into Proteins - Molecular Wires; 1.4.3.1 Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules; 1.4.3.2 Nanostructuring Electrodes using Rigid Molecules; 1.4.3.3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications; 1.5 Switchable Surfaces; 1.5.1 Switching Properties of Monolayer Systems; 1.5.2 Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes 327 $a1.6 ConclusionsReferences; 2 Electrochemically Active Polyelectrolyte-Modified Electrodes; 2.1 Introduction; 2.1.1 Chemically Modified Electrodes; 2.1.2 Redox Hydrogels; 2.1.3 Redox Polyelectrolyte Monolayers; 2.1.4 Redox Polymer Brushes and Grafted DNA; 2.1.5 Layer-by-Layer Polyelectrolyte Multilayers; 2.2 Structure; 2.2.1 Polyelectrolye Interpenetration; 2.2.2 Compensation of Polyelectrolyte Charges; 2.2.3 Film Inner Structure; 2.2.4 Effect of the Assembly pH; 2.2.5 Theoretical Description; 2.3 Electrochemical Response; 2.3.1 Ideal Response; 2.3.2 Peak Position and Donnan Potential 327 $a2.3.3 Coupling Between the Acid-Base and Redox Equilibria2.3.4 Peak Width; 2.3.5 Nonreversible Electrochemistry: Charge Transport; 2.4 Dynamics of Solvent and Ion Exchange; 2.4.1 Ion Exchange; 2.4.2 Solvent Exchange; 2.4.3 Specific Ionic Effects; 2.4.4 Break-In; 2.5 Molecular Description of Redox Polyelectrolyte-Modified Electrodes; 2.5.1 Formulation of the Molecular Theory; 2.5.2 Comparison with Phenomenological Models, Advantages and Limitations; 2.6 Applications; 2.6.1 Amperometric Enzymatic Electrodes; 2.6.2 Electrochromic Devices; 2.7 Conclusions; References 327 $a3 Electrochemistry on Carbon-Nanotube-Modified Surfaces3.1 Introduction; 3.2 Structure and Properties of Carbon Nanotubes; 3.2.1 Structure and Electronic Properties; 3.2.2 Chemical Properties; 3.2.3 Electrochemical Properties; 3.3 Towards the Design of CNT-Modified Electrodes; 3.3.1 Synthesis of CNTs; 3.3.2 CNT Purification Methods; 3.3.3 Chemical and Biochemical Functionalization; 3.3.3.1 Covalent Modification; 3.3.3.2 Noncovalent Modification; 3.3.3.3 Chemical Modification for CNT Sorting; 3.3.3.4 Chemical Doping, Intercalation and Artificial Defects 327 $a3.3.4 CNT Deposition on Electrode Surfaces 330 $aWith contributions from an international group of expert authors, this book includes the latest trends in tailoring interfacial properties electrochemically. The chapters cover various organic and inorganic compounds, with applications ranging from electrochemistry to nanotechnology and biology.Of interest to physical, surface and electrochemists, materials scientists and physicists. 410 0$aAdvances in electrochemical science and engineering ;$v11. 606 $aElectrodes 606 $aElectrochemistry 615 0$aElectrodes. 615 0$aElectrochemistry. 676 $a541.3724 676 $a660.297 701 $aAlkire$b R. C.$f1941-$01278456 701 $aKolb$b Dieter M$0884241 701 $aLipkowski$b Jacek$01613178 701 $aRoss$b P. N$g(Philip N.)$092313 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910841348803321 996 $aChemically modified electrodes$94144422 997 $aUNINA