LEADER 05129nam 2200601Ia 450 001 9910841312003321 005 20230829003107.0 010 $a1-280-72348-3 010 $a9786610723485 010 $a3-527-60898-2 010 $a3-527-60844-3 035 $a(CKB)1000000000376405 035 $a(EBL)481966 035 $a(OCoLC)609855492 035 $a(SSID)ssj0000293348 035 $a(PQKBManifestationID)11242854 035 $a(PQKBTitleCode)TC0000293348 035 $a(PQKBWorkID)10274025 035 $a(PQKB)10577771 035 $a(MiAaPQ)EBC481966 035 $a(EXLCZ)991000000000376405 100 $a20060118d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aCyclodextrins and their complexes$b[electronic resource] $echemistry, analytical methods, applications /$fedited by Helena Dodziuk 210 $aWeinheim $cWiley-VCH$dc2006 215 $a1 online resource (509 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31280-3 320 $aIncludes bibliographical references and index. 327 $aCyclodextrins and Their Complexes; Contents; Preface; List of Contributors; 1 Molecules with Holes - Cyclodextrins; 1.1 Introduction; 1.2 Cyclodextrin Properties; 1.3 Cyclodextrin Nonrigidity [94, 95]; 1.4 Models of Chiral Recognition by Cyclodextrins; References; 2 Modification Reactions of Cyclodextrins and the Chemistry of Modified Cyclodextrins; 2.1 Scope of This Chapter; 2.2 Modification Reactions of Cyclodextrins; 2.2.1 Modification Reactions at the Primary Side; 2.2.1.1 Mono-modification at the C6-Position; 2.2.1.2 Per-modification at the C6-Position 327 $a2.2.1.3 Multi-modification at the C6-Position2.2.2 Modification Reactions at the Secondary Side; 2.2.2.1 Mono-modification at the C2-Position; 2.2.2.2 Mono-modification at Any One of the C2-, C3-, or C6-Positions; 2.2.2.3 Per-modification at the C3-, C2-, or C6-Position; 2.2.3 Per-modification Reactions at All Three Positions; 2.2.4 Enzymatic Modification Reactions of Cyclodextrins; 2.2.5 Construction Reactions for Cyclodextrin Ring Formation; 2.3 Chemistry of Modified Cyclodextrins; 2.3.1 Cyclodextrin Dimers and Trimers; 2.3.2 Charged Cyclodextrins 327 $a2.3.3 Chemosensors Using Modified Cyclodextrins2.3.4 Cyclodextrin Analogues; 2.3.5 Cyclodextrins Conjugated with Other Kinds of Hosts; 2.3.6 Cyclodextrin-Peptide Conjugates; 2.3.7 Cyclodextrin-Saccharide Conjugates; 2.3.8 Metallocavitands Using Modified Cyclodextrins; References; 3 Polymers Involving Cyclodextrin Moieties; 3.1 Supramolecular Polymers Formed by Cyclodextrin Derivatives; 3.1.1 Introduction; 3.1.2 Preparation of Mono-substituted Cyclodextrins; 3.1.3 Formation of Inclusion Complexes [30, 31]; 3.1.4 Polymer Formation by Intermolecular Interactions; 3.1.5 Supramolecular Dimers 327 $a3.1.6 Formation of Supramolecular Trimers3.1.7 Cyclic Daisy Chain [31, 42]; 3.1.8 Supramolecular Polymers [45]; 3.1.9 Poly[2]rotaxanes (Daisy Chain); 3.1.10 Helical Supramolecular Polymers [45, 46]; 3.1.11 Alternating ?-, ?-Cyclodextrin Supramolecular Polymers [47]; 3.1.12 Supramolecular [2]rotaxane Polymer [43]; 3.1.13 Conclusion; 3.2 Supramolecular Complexes of Polymers Bearing Cyclodextrin Moieties with Guest Molecules; References; 4 Cyclodextrin Catalysis; 4.1 Introduction; 4.2 Covalent Catalysis; 4.3 General Acid-Base Catalysis by OH Groups; 4.4 Noncovalent Catalysis 327 $a4.4.1 Regulation of the Mutual Conformation of Reactants4.4.2 Regulation of Photoreactions; 4.4.3 Use of the CyD Cavity as a Specific Reaction Field; 4.5 Catalysis by Chemically Modified CyD; 4.6 Phase-transfer Catalysis; 4.7 Conclusion; References; 5 Chromatographic Studies of Molecular and Chiral Recognition; 5.1 Introduction; 5.2 Determination of the Stoichiometry and Stability of the Complexes; 5.3 Thermodynamics; References; 6 The Application of Cyclodextrins for Enantioseparations; 6.1 Introduction; 6.2 Gas Chromatography 327 $a6.3 High-performance Liquid Chromatography and Related Techniques 330 $aOffering comprehensive and up-to-date know-how in one compact book, an experienced editor and top authors cover every aspect of these important molecules from molecular recognition to cyclodextrins as enzyme models.Chapters include reactivity and chemistry, chromatography, X-ray, NMR plus other physicochemical methods, as well as model calculations, rotaxane and catenane structures, and applications in the pharmaceutical industry. The book also discusses other applications such as in the cosmetics, toiletries, textile and wrapping industries, agrochemistry, electrochemical sensors, and dev 606 $aCyclodextrins 606 $aChemistry, Technical 615 0$aCyclodextrins. 615 0$aChemistry, Technical. 676 $a547.78 701 $aDodziuk$b Helena$0563740 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910841312003321 996 $aCyclodextrins and their complexes$94138460 997 $aUNINA