LEADER 05451nam 2200673 a 450 001 9910841154403321 005 20230617021506.0 010 $a1-280-55826-1 010 $a9786610558261 010 $a3-527-60626-2 010 $a3-527-60052-3 035 $a(CKB)1000000000019350 035 $a(EBL)481675 035 $a(OCoLC)609855399 035 $a(SSID)ssj0000307678 035 $a(PQKBManifestationID)11205711 035 $a(PQKBTitleCode)TC0000307678 035 $a(PQKBWorkID)10250546 035 $a(PQKB)11751112 035 $a(MiAaPQ)EBC481675 035 $a(EXLCZ)991000000000019350 100 $a20030324d2003 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aReactive distillation$b[electronic resource] $estatus and future directions /$fKai Sundmacher and Achim Kienle (eds.) 210 $aWeinheim $cWiley-VCH$dc2003 215 $a1 online resource (309 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30579-3 320 $aIncludes bibliographical references and index. 327 $aReactive Distillation Status and Future Directions; Contents; Preface; List of Contributors; Part I Industrial Applications; 1 Industrial Applications of Reactive Distillation; 1.1 Introduction; 1.2 Etherification: MTBE, ETBE, and TAME; 1.3 Dimerization, Oligomerization, and Condensation; 1.4 Esterification: Methyl Acetate and Other Esters; 1.5 Hydrolysis of Esters; 1.6 Hydration; 1.7 Hydrogenation/Hydrodesulfurization/Hydrocracking; 1.7.1 Benzene to Cyclohexane; 1.7.2 Selective Hydrogenation of C(4) Stream; 1.7.3 Hydrogenation of Pentadiene; 1.7.4 C(4) Acetylene Conversion 327 $a1.7.5 Hydrodesulfurization, Hydrodenitrogenation, and Hydrocracking1.7.6 Miscellaneous Hydrogenations; 1.8 Chlorination; 1.9 Acetalization/Ketalization; 1.10 Recovery and Purification of Chemicals; 1.11 Difficult Separations; 1.12 Chemical Heat Pumps; 1.13 RD with Supercritical Fluids; 1.14 Conclusions; 2 Reactive Distillation Process Development in the Chemical Process Industries; 2.1 Introduction; 2.2 Process Synthesis; 2.3 Process Design and Optimization; 2.4 Limitations of the Methods for Synthesis and Design: the Scale-Up Problem; 2.5 Choice of Equipment 327 $a2.6 Some Remarks on the Role of Catalysis2.7 Conclusions; 2.8 Acknowledgments; 2.9 Notation; 3 Application of Reactive Distillation and Strategies in Process Design; 3.1 Introduction; 3.2 Challenges in Process Design for Reactive Distillation; 3.2.1 Feasibility Analysis; 3.2.2 Catalyst and Hardware Selection; 3.2.3 Column Scale-Up; 3.3 MTBE Decomposition via Reactive Distillation; 3.3.1 Conceptual Design; 3.3.2 Model Development; 3.3.2.1 Catalyst Selection and Reaction Kinetics; 3.3.2.2 Phase Equilibrium Model; 3.3.2.3 Steady-State Simulation; 3.3.3 Lab-Scale Experiments 327 $a3.3.4 Pilot-Plant Experiments3.4 Conclusions; Part II Physicochemical Fundamentals; 4 Thermodynamics of Reactive Separations; 4.1 Introduction; 4.2 Process Models for Reactive Distillation; 4.2.1 Outline; 4.2.2 Case Study: Methyl Acetate; 4.3 Equilibrium Thermodynamics of Reacting Multiphase Mixtures; 4.4 Fluid Property Models for Reactive Distillation; 4.4.1 Outline; 4.4.2 Examples; 4.4.2.1 Hexyl Acetate: Sensitivity Analysis; 4.4.2.2 Methyl Acetate: Prediction of Polynary Vapor-Liquid Equilibria; 4.4.2.3 Butyl Acetate: Thermodynamic Consistency 327 $a4.4.2.4 Ethyl Acetate: Consequences of Inconsistency4.4.2.5 Formaldehyde + Water + Methanol: Intrinsically Reactive Complex Mixture; 4.5 Experimental Studies of Phase Equilibria in Reacting Systems; 4.5.1 Outline; 4.5.2 Reactive Vapor-Liquid Equilibria; 4.5.2.1 Batch Experiments; 4.5.2.2 Flow Experiments; 4.5.2.3 Recirculation Experiments; 4.6 Conclusions; 4.7 Acknowledgments; 4.8 Notation; 5 Importance of Reaction Kinetics for Catalytic Distillation Processes; 5.1 Introduction; 5.2 Reactive Ideal Binary Mixtures; 5.2.1 Reaction-Distillation Process with External Recycling 327 $a5.2.1.1 (,)-Analysis 330 $aIn a reactive distillation column, both the chemical conversion and the distillative separation of the product mixture are carried out simultaneously. Through this integrative strategy, chemical equilibrium limitations can be overcome, higher selectivities can be achieved and heat of reaction can be directly used for distillation. Increased process efficiency and reduction of investments and operational costs are the direct results of this approach.Highly renowned international experts from both industry and academia review the state-of-the-art and the future directions in application, 606 $aDistillation$vCongresses 606 $aDistillation apparatus$xDesign and construction$vCongresses 606 $aReactivity (Chemistry)$xIndustrial applications$vCongresses 615 0$aDistillation 615 0$aDistillation apparatus$xDesign and construction 615 0$aReactivity (Chemistry)$xIndustrial applications 676 $a660 676 $a660.28425 676 $a660/.28425 701 $aSundmacher$b Kai$0923327 701 $aKienle$b Achim$01728470 712 12$aInternational Workshop on Reactive Distillation 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910841154403321 996 $aReactive distillation$94137042 997 $aUNINA