LEADER 05422nam 2200673Ia 450 001 9910840958603321 005 20170810182604.0 010 $a1-119-99028-9 010 $a1-283-37398-X 010 $a9786613373984 010 $a0-470-97923-2 010 $a0-470-97922-4 035 $a(CKB)3400000000000315 035 $a(EBL)661810 035 $a(OCoLC)705355139 035 $a(SSID)ssj0000477685 035 $a(PQKBManifestationID)11296866 035 $a(PQKBTitleCode)TC0000477685 035 $a(PQKBWorkID)10514056 035 $a(PQKB)11365083 035 $a(MiAaPQ)EBC661810 035 $a(PPN)197117112 035 $a(EXLCZ)993400000000000315 100 $a20101027d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMicrofluidic reactors for polymer particles$b[electronic resource] /$fEugenia Kumacheva and Piotr Garstecki 210 $aChichester, West Sussex ;$a[Hoboken, N.J.] $cWiley$d2011 215 $a1 online resource (246 p.) 300 $aDescription based upon print version of record. 311 $a0-470-05773-4 320 $aIncludes bibliographical references and index. 327 $aMicrofluidic Reactors for Polymer Particles; Contents; Preface; 1 Applications of Polymer Particles; References; 2 Methods for the Generation of Polymer Particles; 2.1 Conventional Methods Used for Producing Polymer Particles; 2.2 Microfluidic Generation of Polymer Particles; References; 3 Introduction to Microfluidics; 3.1 Microfluidics; 3.2 Droplet Microfluidics; References; 4 Physics of Microfluidic Emulsification; 4.1 Energy of the Interfaces Between Immiscible Fluids; 4.2 Surfactants; 4.3 Interfacial Tension; 4.4 Laplace Pressure; 4.5 Rayleigh-Plateau Instability 327 $a4.6 Wetting of a Solid Surface4.7 Analysis of Flow; 4.8 Flow in Networks of Microchannels; 4.9 Dimensional Groups; References; 5 Formation of Droplets in Microfluidic Systems; 5.1 Introduction; 5.1.1 Geometrical Confinement; 5.1.2 The Cost of Confinement; 5.2 Microfluidic Generators of Droplets and Bubbles; 5.3 T-Junction; 5.3.1 Parameters that Determine the Dynamics; 5.3.2 First Reports; 5.3.3 Mechanism of Operation of the T-Junction System; 5.3.4 Variations of the Geometry of the T-Junction; 5.3.5 Summary of the Mechanism of Breakup in the T-Junction 327 $a5.3.6 Maximum Throughput of a Single Junction5.4 Formation of Droplets and Bubbles in Microfluidic Flow- Focusing Devices; 5.4.1 First Reports and Observations; 5.4.2 Dynamics of Flow-Focusing Systems at Low Contrast of Viscosities; 5.4.2.1 Formation of Bubbles; 5.4.2.2 Formation of Droplets; 5.4.3 Flow Focusing: Formation of Viscous Droplets; 5.5 Practical Guidelines for the Use of Microfluidic Devices for Formation of Droplets; 5.5.1 Types of Fluids; 5.5.2 Surfactants; 5.5.3 Wetting; 5.5.4 Size of the Droplets; 5.5.5 Supplying the Liquids; 5.6 Designing Droplets 327 $a5.6.1 Control of the Interface of Homogeneous Droplets5.6.2 Heterogeneous Droplets; 5.6.3 Multiple Emulsions; 5.7 Conclusions; References; 6 High-Throughput Microfluidic Systems for Formation of Droplets; 6.1 Introduction; 6.2 Effects that Modify the Pressure Distribution; 6.3 Hydrodynamic Coupling; 6.4 Integrated Systems; 6.5 Parallel Formation of Droplets of Distinct Properties; 6.6 Conclusions; References; 7 Synthesis of Polymer Particles in Microfluidic Reactors; 7.1 Introduction; 7.2 Particles Synthesized by Free-Radical Polymerization; 7.2.1 Polymerization in Multi-Phase Flow 327 $a7.2.1.1 Emulsification of Polymerizable Liquids7.2.2 Synthesis in Single-Phase Flow; 7.3 Polymer Particles Synthesized by Polycondensation; 7.4 Combination of Free-Radical Polymerization and Polycondensation Reactions; 7.5 General Considerations on the Use of Other Polymerization Mechanisms; 7.6 Important Aspects of Microfluidic Polymerization of Polymer Particles; 7.6.1 Modes of Microfluidic Polymerization; 7.6.2 Achieving High Conversion in Microfluidic Polymerization; 7.6.3 In Situ Polymerization of Monomer Droplets; 7.7 Synthesis of Composite Particles; 7.7.1 Copolymer Particles 327 $a7.7.2 Polymer Particles Loaded with Low-Molecular Weight Organic Additives 330 $aThe manipulation of fluids in channels with dimensions in the range from tens to hundreds of micrometers - microfluidics - has recently emerged as a new field of science and technology. Microfluidics has applications spanning analytical chemistry, organic and inorganic synthesis, cell biology, optics and information technology. One particularly promising application is the microfluidic synthesis of polymer particles with precisely controlled dimensions, and a variety of shapes, morphologies and compositions. Written as a comprehensive introduction for scientists and engineers working in micr 606 $aEmulsion polymerization 606 $aMicrofluidic devices 606 $aMicroreactors 615 0$aEmulsion polymerization. 615 0$aMicrofluidic devices. 615 0$aMicroreactors. 676 $a620.106 676 $a668.9 700 $aKumacheva$b Eugenia$01727848 701 $aGarstecki$b Piotr$01727849 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910840958603321 996 $aMicrofluidic reactors for polymer particles$94135686 997 $aUNINA