LEADER 05304nam 2200625Ia 450 001 9910840659703321 005 20170810192851.0 010 $a1-280-92158-7 010 $a9786610921584 010 $a3-527-61064-2 010 $a3-527-61063-4 035 $a(CKB)1000000000376505 035 $a(EBL)481341 035 $a(OCoLC)182747881 035 $a(SSID)ssj0000107002 035 $a(PQKBManifestationID)11137925 035 $a(PQKBTitleCode)TC0000107002 035 $a(PQKBWorkID)10016664 035 $a(PQKB)10588267 035 $a(MiAaPQ)EBC481341 035 $a(PPN)224797859 035 $a(EXLCZ)991000000000376505 100 $a20060529d2007 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAsymmetric synthesis with chemical and biological methods /$fedited by Dieter Enders and Karl-Erich Jaeger 210 $aWeinheim $cWiley-VCH ;$aChichester $cJohn Wiley [distributor]$d2007 215 $a1 online resource (472 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31473-3 320 $aIncludes bibliographical references and index. 327 $aAsymmetric Synthesis with Chemical and Biological Methods; Foreword; Contents; Preface; List of Contributors; 1 Stoichiometric Asymmetric Synthesis; 1.1 Development of Novel Enantioselective Synthetic Methods; 1.1.1 Introduction; 1.1.2 ?-Silyl Ketone-Controlled Asymmetric Syntheses; 1.1.2.1 Regio- and Enantioselective ?-Fluorination of Ketones; 1.1.2.2 ?-Silyl Controlled Asymmetric Mannich Reactions; 1.1.3 Asymmetric Hetero-Michael Additions; 1.1.3.1 Asymmetric Aza-Michael Additions; 1.1.3.2 Asymmetric Oxa-Michael Additions; 1.1.3.3 Asymmetric Phospha-Michael Additions 327 $a1.1.4 Asymmetric Syntheses with Lithiated ?-Aminonitriles1.1.4.1 Asymmetric Nucleophilic ?-Aminoacylation; 1.1.4.2 Asymmetric Nucleophilic Alkenoylation of Aldehydes; 1.1.5 Asymmetric Electrophilic ?-Substitution of Lactones and Lactams; 1.1.6 Asymmetric Synthesis of ?-Phosphino Ketones and 2-Phosphino Alcohols; 1.1.7 Asymmetric Synthesis of 1,3-Diols and anti-1,3-Polyols; 1.1.8 Asymmetric Synthesis of ?-Substituted Sulfonamides and Sulfonates; 1.2 Asymmetric Synthesis of Natural Products Employing the SAMP/RAMP Hydrazone Methodology; 1.2.1 Introduction; 1.2.2 Stigmatellin A 327 $a1.2.3 Callistatin A1.2.4 Dehydroiridodiol(dial) and Neonepetalactone; 1.2.5 First Enantioselective Synthesis of Dendrobatid Alkaloids Indolizidine 209I and 223J; 1.2.6 Efficient Synthesis of (2S,12 ?R)-2-(12 ?-Aminotridecyl)pyrrolidine, a Defense Alkaloid of the Mexican Bean Beetle; 1.2.7 2-epi-Deoxoprosopinine; 1.2.8 Attenol A and B; 1.2.9 Asymmetric Synthesis of (+)- and (-)-Streptenol A; 1.2.10 Sordidin; 1.2.11 Prelactone B and V; 1.3 Asymmetric Synthesis Based on Sulfonimidoyl-Substituted Allyltitanium Complexes; 1.3.1 Introduction 327 $a1.3.2 Hydroxyalkylation of Sulfonimidoyl-Substituted Allylltitanium Complexes1.3.2.1 Sulfonimidoyl-Substituted Bis(allyl)titanium Complexes; 1.3.2.2 Sulfonimidoyl-Substituted Mono(allyl)tris(diethylamino)titanium Complexes; 1.3.3 Aminoalkylation of Sulfonimidoyl-Substituted Allyltitanium Complexes; 1.3.3.1 Sulfonimidoyl-Substituted Bis(allyl)titanium Complexes; 1.3.3.2 Sulfonimidoyl-Substituted Mono(allyl)tris(diethylamino)titanium Complexes; 1.3.4 Structure and Reactivity of Sulfonimidoyl-Substituted Allyltitanium Complexes; 1.3.4.1 Sulfonimidoyl-Substituted Bis(allyl)titanium Complexes 327 $a1.3.4.2 Sulfonimidoyl-Substituted Mono(allyl)titanium Complexes1.3.5 Asymmetric Synthesis of Homopropargyl Alcohols; 1.3.6 Asymmetric Synthesis of 2,3-Dihydrofurans; 1.3.7 Synthesis of Bicyclic Unsaturated Tetrahydrofurans; 1.3.8 Asymmetric Synthesis of Alkenyloxiranes; 1.3.9 Asymmetric Synthesis of Unsaturated Mono- and Bicyclic Prolines; 1.3.10 Asymmetric Synthesis of Bicyclic Amino Acids; 1.3.11 Asymmetric Synthesis of ?-Amino Acids; 1.3.12 Conclusion; 1.4 The "Daniphos" Ligands: Synthesis and Catalytic Applications; 1.4.1 Introduction; 1.4.2 General Synthesis 327 $a1.4.3 Applications in Stereoselective Catalysis 330 $aEdited by two of the leading researchers in the field, this book provides a deep, interdisciplinary insight into stoichiometric and catalytic reactions in this continuously expanding area. A plethora of top German scientists with an international reputation covers various aspects, from classical organic chemistry to process development, and from the theoretical background to biological methods using enzymes. Throughout the focus is on the development of new synthetic methods in asymmetric synthesis, the synthesis of natural and bioactive compounds and the latest developments in both chemical a 606 $aAsymmetric synthesis 606 $aOrganic compounds$xSynthesis 615 0$aAsymmetric synthesis. 615 0$aOrganic compounds$xSynthesis. 676 $a547.2 701 $aEnders$b Dieter$092731 701 $aJaeger$b Karl-Erich$01728620 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910840659703321 996 $aAsymmetric synthesis with chemical and biological methods$94137437 997 $aUNINA