LEADER 05179nam 2200637Ia 450 001 9910831177403321 005 20170809164509.0 010 $a1-281-76401-9 010 $a9786611764012 010 $a3-527-61296-3 010 $a3-527-61297-1 035 $a(CKB)1000000000294602 035 $a(EBL)481844 035 $a(OCoLC)261223015 035 $a(SSID)ssj0000155232 035 $a(PQKBManifestationID)11149802 035 $a(PQKBTitleCode)TC0000155232 035 $a(PQKBWorkID)10098432 035 $a(PQKB)11775606 035 $a(MiAaPQ)EBC481844 035 $a(PPN)242599362 035 $a(EXLCZ)991000000000294602 100 $a20010822e20022001 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFine chemicals through heterogenous catalysis$b[electronic resource] /$fRoger Arthur Sheldon, Hermann van Bekkum 210 $aWeinheim ;$aToronto $cWiley-VCH$d2002, c2001 215 $a1 online resource (639 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29951-3 320 $aIncludes bibliographical references and index. 327 $aFine Chemicals through Heterogeneous Catalysis; Contents; 1 Introduction; 1.1 What are Fine Chemicals?; 1.2 The Environmental Factor; 1.3 The Development of Organic Synthesis and Catalysis; 1.4 Why Heterogeneous Catalysis?; 1.5 Types of Catalysts and Reactions; 1.5.1 Solid-Acid Catalysis; 1.5.2 Solid-Base Catalysis; 1.5.3 Catalytic Hydrogenation; 1.5.4 Catalytic Oxidations; 1.5.5 Catalytic C-C Bond Formation; 1.6 Alternative Approaches; 1.7 Heterogeneous Catalysis in Multi-step Synthesis: Vanillin; 2 Basic Principles/General; 2.1 General Considerations and Types of Catalyst 327 $a2.1.1 Introduction2.1.2 Catalytically Active Surface Area; 2.1.3 Reactors Employed in the Fine-chemical Industry; 2.1.4 Slurry-phase Catalysts; 2.1.5 Fixed-bed Catalysts; 2.1.6 Integration of the Catalyst and the Reactor; 2.1.7 Solid Catalysts Employed in the Fine-chemical Industry; 2.1.8 Metal Catalysts; 2.1.9 Solid-Acid Catalysts; 2.2 Preparation of Solid Catalysts; 2.2.1 Demands on Solid Catalysts; 2.2.2 Preparation Procedures [2]; 2.2.3 Conclusions; 2.3 Characterization of Solid Catalysts; 2.3.1 Total Surface Area and Pore-size Distribution 327 $a2.3.2 Catalytically Active Surface Area Per Unit Weight of Catalyst2.3.3 Extent of Reduction of Metal Catalysts; 2.3.4 Solid-acid Catalysts; 2.3.5 Dispersion of Active Component(s) Over the Support; 2.3.6 Conclusions; 2.4 Reactors; 2.4.1 Introduction; 2.4.2 Three-phase Catalytic Reactions (G-L-S); 2.4.3 Characteristics of Three-phase Catalytic Reactors for Fine-chemicals Production; 2.4.3.1 Reactors with Moving Catalyst; 2.4.3.2 Reactors with a Fixed Bed of Catalyst; 2.4.3.3 Comparison-Reactor Choice; 2.4.4 Design Aspects of Stirred Tank Batch Reactor 327 $a2.4.5 Scale-up of Stirred-Tank Batch Reactors-Runaway Reactions3 Solid-acid Catalysts-General; 3.1 Acidic Clays; 3.1.1 Introduction; 3.1.2 Structure; 3.1.3 Main Properties and Catalytic Applications; 3.1.4 Pillared Interlayer Clays (PILC); 3.1.5 Conclusions; 3.2 Zeolites as Catalysts; 3.2.1 Introduction; 3.2.2 Acid Zeolites; 3.2.2.1 Framework Composition; 3.2.2.2 Extra-framework Composition; 3.2.3 Basicity in Zeolites; 3.2.3.1 Basic Zeolites-Framework Composition; 3.2.3.2 Basic Zeolites-Extra-framework Composition; 3.2.4 Redox Molecular Sieves; 3.2.4.1 Oxidation Sites in Framework Positions 327 $a3.2.4.2 Oxidation Sites in Extra-framework Positions3.2.5 Conclusions; 3.3 Sulfonated Polysiloxanes; 3.3.1 Motivation and Expected Advantages; 3.3.2 Synthetic Approaches; 3.3.2.1 Grafting of Silanes to Silica; 3.3.2.2 Copolycondensation and Sol-Gel Processing; 3.3.2.3 Sulfonation of Arylsiloxanes; 3.3.2.4 Oxidation of Sulfur-functionalized Siloxanes; 3.3.3 Characterization of the Polysiloxanes; 3.3.3.1 General; 3.3.3.2 Analytical Determination of Capacity; 3.3.3.3 NMR Spectroscopy; 3.3.3.4 Thermal Stability; 3.3.4 Applications and Reactions; 3.3.5 Summary; 3.4 Silica-occluded Heteropolyacids 327 $a3.4.1 Introduction 330 $aNowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production.With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field. 606 $aHeterogeneous catalysis 606 $aOrganic compounds$xSynthesis 615 0$aHeterogeneous catalysis. 615 0$aOrganic compounds$xSynthesis. 676 $a541.395 676 $a660.2995 700 $aSheldon$b Roger A$0605461 701 $aBekkum$b Herman van$0518783 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910831177403321 996 $aFine chemicals through heterogenous catalysis$94040369 997 $aUNINA