LEADER 04961nam 2200613Ia 450 001 9910831081903321 005 20170814175352.0 010 $a1-282-46095-1 010 $a9786612460951 010 $a3-527-62754-5 010 $a3-527-62755-3 035 $a(CKB)2550000000006873 035 $a(EBL)482184 035 $a(OCoLC)441875098 035 $a(SSID)ssj0000354505 035 $a(PQKBManifestationID)11245302 035 $a(PQKBTitleCode)TC0000354505 035 $a(PQKBWorkID)10302557 035 $a(PQKB)11663089 035 $a(MiAaPQ)EBC482184 035 $a(PPN)152467815 035 $a(EXLCZ)992550000000006873 100 $a20090218d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern heterogeneous oxidation catalysis$b[electronic resource] $edesign, reactions and characterization /$fedited by Noritaka Mizuno 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley, distributor]$dc2009 215 $a1 online resource (359 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31859-3 320 $aIncludes bibliographical references and index. 327 $aModern Heterogeneous Oxidation Catalysis: Design, Reactions and Characterization; Contents; Preface; List of Contributors; 1 Concepts in Selective Oxidation of Small Alkane Molecules; 1.1 Introduction; 1.2 The Research Field; 1.3 Substrate Activation; 1.4 Active Oxygen Species; 1.5 Catalyst Material Science; 1.6 Conclusion; References; 2 Active Ensemble Structures for Selective Oxidation Catalyses at Surfaces; 2.1 Introduction; 2.2 Chiral Self-Dimerization of Vanadium Schiff-Base Complexes on SiO2 and Their Catalytic Performances for Asymmetric Oxidative Coupling of 2-Naphthol 327 $a2.2.1 Asymmetric Heterogeneous Catalysis Using Supported Metal Complexes2.2.2 Chiral V-Dimer Structure on a SiO2 Surface; 2.2.3 Asymmetric Catalysis for Oxidative Coupling of 2-Naphthol to BINOL; 2.3 Low-Temperature Preferential Oxidation of CO in Excess H2 on Cu-Clusters Dispersed on CeO2; 2.3.1 Preferential Oxidation (PROX) of CO in Excess H2 on Novel Metal Catalysts; 2.3.2 Characterization and Performance of a Novel Cu Cluster/CeO2 Catalyst; 2.4 Direct Phenol Synthesis from Benzene and Molecular Oxygen on a Novel N-Interstitial Re10-Cluster/HZSM-5 Catalyst 327 $a2.4.1 Phenol Production from Benzene with N2O, H2 + O2, and O22.4.1.1 Benzene to Phenol with N2O; 2.4.1.2 Benzene to Phenol with H2 + O2; 2.4.1.3 Benzene to Phenol with O2; 2.4.2 Novel Re/HZSM-5 Catalyst for Direct Benzene-to-Phenol Synthesis with O2; 2.4.3 Active Re Clusters Entrapped in ZSM-5 Pores; 2.4.4 Structural Dynamics of the Active Re10 Cluster; 2.5 Conclusion; References; 3 Unique Catalytic Performance of Supported Gold Nanoparticles in Oxidation; 3.1 Introduction; 3.2 Low-Temperature CO Oxidation; 3.2.1 Low-Temperature CO Oxidation in Air 327 $a3.2.1.1 Junction Perimeter Between Au Particles and the Support3.2.1.2 Selection of Suitable Supports; 3.2.1.3 Sensitivity to the Size of the Gold Particles; 3.2.2 Low-Temperature CO Oxidation in H2; 3.2.3 Mechanism for CO Oxidation Over Supported Gold Nanoparticles; 3.2.3.1 Mechanisms Involving Junction Perimeter Between Gold and the Metal-Oxide Supports; 3.2.3.2 Mechanisms Involving Specific Size or Thickness of Gold Clusters or Thin Layers; 3.2.3.3 Mechanisms Involving Cationic Gold; 3.3 Complete Oxidation of Volatile Organic Compounds 327 $a3.4 Gas-Phase Selective Oxidation of Organic Compounds3.4.1 Gas-Phase Selective Oxidation of Aliphatic Alkanes; 3.4.2 Gas-Phase Selective Oxidation of Alcohols; 3.4.3 Gas-Phase Propylene Epoxidation; 3.4.3.1 Introduction; 3.4.3.2 Gas-Phase Propylene Epoxidation with Hydrogen-Oxygen Mixtures on Au/TiO2; 3.4.3.3 Gas-Phase Propylene Epoxidation with Hydrogen-Oxygen Mixtures on Au/Ti-SiO2; 3.5 Liquid-Phase Selective Oxidation of Organic Compounds; 3.5.1 Oxidation of Mono-Alcohols; 3.5.2 Oxidation of Diols; 3.5.3 Oxidation of Glycerol; 3.5.4 Aerobic Oxidation of Glucose 327 $a3.5.5 Oxidation of Alkanes and Alkenes 330 $aFilling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes.A true must-have for anyone working in this key technology. 606 $aHeterogeneous catalysis 606 $aOxidation 615 0$aHeterogeneous catalysis. 615 0$aOxidation. 676 $a660.28443 701 $aMizuno$b Noritaka$01668853 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910831081903321 996 $aModern heterogeneous oxidation catalysis$94029736 997 $aUNINA