LEADER 03754nam 2200445 450 001 9910830965203321 005 20230629234155.0 010 $a3-527-82286-0 010 $a3-527-34642-2 010 $a3-527-82285-2 035 $a(CKB)4100000011248753 035 $a(MiAaPQ)EBC6527623 035 $a(Au-PeEL)EBL6527623 035 $a(OCoLC)1244629507 035 $a(EXLCZ)994100000011248753 100 $a20211014d2021 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aDiarylethene molecular photoswitches $econcepts and functionalities /$fMasahiro Irie 210 1$aWeinheim, Germany :$cWiley-VCH GmbH,$d[2021] 210 4$dİ2021 215 $a1 online resource (239 pages) 311 $a3-527-34640-6 320 $aIncludes bibliographical references and index. 327 $aCover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction -- 1.1 General Introduction -- 1.2 Discovery of Diarylethene Molecular Photoswitches -- References -- Chapter 2 Reaction Mechanism -- 2.1 Basic Concepts -- 2.2 Theoretical Study -- 2.3 Reaction Dynamics -- 2.3.1 Cyclization Reaction -- 2.3.2 Cycloreversion Reaction -- References -- Chapter 3 Photoswitching Performance -- 3.1 Quantum Yield -- 3.1.1 Photocyclization Quantum Yield -- 3.1.2 Solvent Effect on Cyclization Quantum Yield -- 3.1.3 Photocycloreversion Quantum Yield -- 3.2 Thermal Stability -- 3.3 Fatigue Resistance -- 3.4 Fluorescence Property -- 3.4.1 Turn?Off Mode Photoswitching -- 3.4.2 Turn?On Mode Photoswitching -- 3.5 Chiral Property -- References -- Chapter 4 Photoswitchable Crystals -- 4.1 Dichroism -- 4.2 X?Ray Crystallographic Analysis -- 4.3 Quantum Yield -- 4.4 Multicolored Systems and Nano?Layered Periodic Structures -- 4.5 Fluorescent Crystals -- 4.6 Photomechanical Response -- 4.6.1 Surface Morphology Change -- 4.6.2 Reversible Shape Change -- 4.6.3 Bending Response of Mixed Crystals -- References -- Chapter 5 Memory -- 5.1 Single?Molecule Memory -- 5.2 Near?Field Optical Memory -- 5.3 Three?Dimensional Optical Memory -- 5.4 Readout Using Infrared Absorption, Raman Scattering, and Refractive Index Changes -- References -- Chapter 6 Switches -- 6.1 Single?Molecule Conductance Photoswitch -- 6.2 Optical Switch Based on Refractive Index Change -- 6.3 Magnetism -- References -- Chapter 7 Surface Properties -- 7.1 Surface Wettability -- 7.2 Selective Metal Deposition -- 7.3 Subwavelength Nanopatterning -- References -- Chapter 8 Polymers and Liquid Crystals -- 8.1 Polymers -- 8.2 Liquid Crystals -- References -- Chapter 9 Applications -- 9.1 Organic Field?Effect Transistors (OFETs) -- 9.2 Metal Organic Frameworks (MOFs). 327 $a9.3 Super?Resolution Fluorescence Microscopy -- 9.3.1 Control of Cycloreversion Quantum Yield -- 9.3.2 Fatigue Resistance -- 9.3.3 Photoswitching with Single?Wavelength Visible Light -- 9.3.4 Super?Resolution Bioimaging -- 9.4 Chemical Reactivity Control -- 9.5 Biological Activity -- 9.6 Color Dosimeters -- References -- Appendix A Synthesis Procedures of Typical Diarylethenes -- A.1 1,2?Bis(2,4?dimethyl?5?phenyl?3?thienyl)perfluorocyclopentene (7) [5-7] -- A.2 1,2?Bis(2?ethyl?6?phenyl?1?benzothiophene?1,1? dioxide?3?yl)?perfluorocyclopenetene (11) [8-10] -- References -- Index -- EULA. 606 $aMolecular machinery 615 0$aMolecular machinery. 676 $a547.7 700 $aIrie$b Masahiro$01607169 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830965203321 996 $aDiarylethene molecular photoswitches$93933335 997 $aUNINA