LEADER 05185nam 2200601 a 450 001 9910830940203321 005 20230725023227.0 010 $a1-282-68781-6 010 $a9786612687815 010 $a3-527-62972-6 010 $a3-527-62973-4 035 $a(CKB)2670000000014584 035 $a(EBL)513902 035 $a(OCoLC)609862155 035 $a(SSID)ssj0000363085 035 $a(PQKBManifestationID)11267707 035 $a(PQKBTitleCode)TC0000363085 035 $a(PQKBWorkID)10381555 035 $a(PQKB)11196256 035 $a(MiAaPQ)EBC513902 035 $a(EXLCZ)992670000000014584 100 $a20100601d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMembrane reactors$b[electronic resource] $edistributing reactants to improve selectivity and yield /$fedited by Andreas Seidel-Morgenstern 210 $aWeinheim $cWiley-VCH Verlag GmbH & Co.$d2010 215 $a1 online resource (294 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32039-3 320 $aIncludes bibliographical references and index. 327 $aMembrane Reactors: Distributing Reactants to Improve Selectivity and Yield; Contents; Preface; List of Contributors; 1: Basic Problems of Chemical Reaction Engineering and Potential of Membrane Reactors; 1.1 Challenges in Chemical Reaction Engineering; 1.2 Concepts of Membrane Reactors; 1.3 Available Membranes; 1.4 Illustration of the Selectivity Problem; 1.5 Reaction Rate, Conversion, Selectivity and Yield; 1.5.1 Reaction Rates; 1.5.2 Conversion; 1.5.3 Mass Balance of a Plug Flow Tubular Reactor; 1.5.4 Selectivity and Yield; 1.6 Distributed Dosing in Packed-Bed and Membrane Reactors 327 $a1.6.1 Adjusting Local Concentrations to Enhance Selectivities1.6.2 Optimization of Dosing Profiles; 1.7 Kinetic Compatibility in Membrane Reactors; 1.8 Current Status of Membrane Reactors of the Distributor Type; Notation used in this Chapter; Greek Symbols; Superscripts and Subscripts; Abbreviations; References; 2: Modeling of Membrane Reactors; 2.1 Introduction; 2.2 Momentum, Mass and Heat Balances; 2.3 Transport Kinetics; 2.3.1 Fluid-Filled Regions; 2.3.1.1 Molecular Transport of Momentum; 2.3.1.2 Heat Conduction; 2.3.1.3 Molecular Diffusion; 2.3.2 Porous Domains 327 $a2.3.2.1 Molecular Diffusion2.3.2.2 K nudsen Diffusion; 2.3.2.3 Viscous Flow; 2.3.2.4 Models for Description of Gas Phase Transport in Porous Media; 2.4 Reduced Models; 2.5 Solvability, Discretization Methods and Fast Solution; 2.6 Implementation in FLUENT, MooNMD, COMSOL and ProM oT; 2.6.1 Application of FLUENT; 2.6.2 Application of MooNMD; 2.6.3 Application of ProM oT; 2.7 Conclusion; Notation used in this Chapter; Latin Notation; Greek Notation; Super- and Subscripts; References; 3: Catalysis and Reaction Kinetics of a Model Reaction; 3.1 Introduction 327 $a3.2 The Reaction Network of the Oxidative Dehydrogenation of Ethane3.3 Catalysts and Structure-Activity Relations; 3.3.1 Catalyst Preparation and Characterization; 3.3.2 Mechanistic Aspects: Correlation Between Structure and Activity; 3.4 Derivation of a Kinetic Model; 3.4.1 Experimental; 3.4.1.1 Catalyst; 3.4.1.2 Set-Up; 3.4.1.3 Procedures; 3.4.2 Qualitative Trends; 3.4.2.1 Overall Catalyst Performance; 3.4.2.2 Evaluation of Intraparticle Mass Transfer Limitations; 3.4.3 Quantitative Evaluation; 3.4.3.1 Simplified Reactor Model and Data Analysis; 3.4.3.2 Kinetic Models 327 $a3.4.3.3 Parameter Estimation3.4.4 Suggested Simplified Model; Special Notation not Mentioned in Chapter 2; Latin Notation; Greek Notation; References; 4: Transport Phenomena in Porous Membranes and Membrane Reactors; 4.1 Introduction; 4.2 Aspects of Discretizing Convection-Diffusion Equations; 4.3 Velocity Fields in Membrane Reactors; 4.4 Determination of Transport Coefficients and Validation of Models; 4.4.1 Mass Transport Parameters of Multilayer Ceramic Membranes-Precursors Available; 4.4.1.1 Task and Tools; 4.4.1.2 Identification by Single Gas Permeation 327 $a4.4.1.3 Validation by Isobaric Diffusion and by Transient Diffusion 330 $aThis authoritative work represents a broad treatment of the field, including the basic principles of membrane reactors, a comparative study of these and conventional fixed-bed reactors or multi-tube reactors, modeling, industrial applications, and emerging applications -- all based on case studies and model reactions with a stringent mathematical framework. The significant progress made over the last few years in this inherently hot multidisciplinary field is summarized in a competent manner, such that the novice can grasp the elementary concepts, while professionals can familiarize themse 606 $aMembrane reactors 606 $aBioreactors 615 0$aMembrane reactors. 615 0$aBioreactors. 676 $a660.2832 701 $aSeidel-Morgenstern$b Andreas$01608866 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830940203321 996 $aMembrane reactors$94098926 997 $aUNINA