LEADER 05304nam 2200649 a 450 001 9910830923403321 005 20230721032706.0 010 $a1-281-75213-4 010 $a9786611752132 010 $a0-470-38405-0 010 $a0-470-38404-2 035 $a(CKB)1000000000537152 035 $a(EBL)353567 035 $a(OCoLC)246160195 035 $a(SSID)ssj0000204959 035 $a(PQKBManifestationID)11184232 035 $a(PQKBTitleCode)TC0000204959 035 $a(PQKBWorkID)10188068 035 $a(PQKB)11012078 035 $a(MiAaPQ)EBC353567 035 $a(EXLCZ)991000000000537152 100 $a20080225d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMolecular recognition and polymers$b[electronic resource] $econtrol of polymer structure and self-assembly /$fedited by Vincent M. Rotello, S. Thayumanavan 210 $aHoboken, N.J. $cWiley$dc2008 215 $a1 online resource (492 p.) 300 $aDescription based upon print version of record. 311 $a0-470-27738-6 320 $aIncludes bibliographical references and index. 327 $aMOLECULAR RECOGNITION AND POLYMERS; CONTENTS; Preface; Acknowledgments; List of Contributors; List of Figures; List of Tables; Editor Biographies; PART I FUNDAMENTALS OF SUPRAMOLECULAR POLYMERS; 1. A BRIEF INTRODUCTION TO SUPRAMOLECULAR CHEMISTRY IN A POLYMER CONTEXT; 1.1. Introduction and Background; 1.2. Main-Chain Versus Side-Chain Supramolecular Polymers; References; 2. MOLECULAR RECOGNITION USING AMPHIPHILIC MACROMOLECULES; 2.1. Introduction; 2.2. Amphiphilic Block Copolymers; 2.2.1. Nonspecific Interactions; 2.2.2. Specific Interactions; 2.3. Amphiphilic Homopolymers 327 $a2.3.1. Container Properties2.3.2. Recognition of Protein Surfaces; 2.3.3. Protein Sensing; 2.3.4. Recognition and Detection of Peptides; 2.4. Amphiphilic Dendrimers; 2.5. Conclusions; Acknowledgment; References; 3. SUPRAMOLECULAR CONTROL OF MECHANICAL PROPERTIES IN SINGLE MOLECULES, INTERFACES, AND MACROSCOPIC MATERIALS; 3.1. Introduction and Background; 3.2. Mechanical Properties of Linear SPs; 3.3. Mechanical Properties of SP Networks; 3.4. Mechanical Properties in SPs at Interfaces; 3.5. Mechanical Forces and Supramolecular Interactions; 3.6. Conclusions; References 327 $aPART II POLYMER FORMATION AND SELF-ASSEMBLY4. HYDROGEN BOND FUNCTIONALIZED BLOCK COPOLYMERS AND TELECHELIC OLIGOMERS; 4.1. Scientific Rationale and Perspective; 4.2. Hydrogen Bonding Interactions in Macromolecular Design; 4.2.1. Fundamentals of Hydrogen Bonding; 4.2.2. Performance Advantages of Hydrogen Bond Containing Polymers; 4.3. Hydrogen Bond Containing Block Copolymers; 4.3.1. Block Copolymers Involving Single Hydrogen Bonding Groups; 4.3.2. Nucleobase Containing Hydrogen Bonding Block Copolymers; 4.3.3. Block Copolymers Containing DNA Oligonucleotides 327 $a4.3.4. Block Copolymers Containing Other Hydrogen Bonding Arrays4.3.5. Order-Disorder Transitions (ODTs) in Hydrogen Bonding Block Copolymers; 4.4. Telechelic Hydrogen Bond Functional Polymers; 4.5. Combining Hydrogen Bonding with Other Noncovalent Interactions; 4.6. Reversible Attachment of Guest Molecules via Hydrogen Bonding; 4.7. Conclusions and Summary; References; 5. NONCOVALENT SIDE CHAIN MODIFICATION; 5.1. Introduction; 5.1.1. Supramolecular Polymers; 5.2. Strategies Toward Noncovalent Side Chain Functionalization of Polymeric Scaffolds 327 $a5.2.1. Side Chain Functionalization Using Hydrogen Bonding5.2.2. Side Chain Functionalization Using Metal Coordination; 5.2.3. Side Chain Functionalization Using Coulombic Interactions; 5.3. Noncovalent Multifunctionalization of the Side Chains of Polymeric Scaffolds; 5.3.1. Combination of Hydrogen Bonding and Metal Coordination Interactions; 5.3.2. Combination of Hydrogen Bonding and Coulombic Charges; 5.3.3. Multiple Hydrogen Bonding Interactions: Self-Sorting on Polymers 327 $a5.3.4. Terpolymer Functionalization Strategies: Combing Hydrogen Bonding, Metal Coordination, and Pseudorotaxane Formation 330 $aState-of-the-art techniques for tapping the vast potential of polymersThe use of specific non-covalent interactions to control polymer structure and properties is a rapidly emerging field with applications in diverse disciplines. Molecular Recognition and Polymers covers the fundamental aspects and applications of molecular recognition-in the creation of novel polymeric materials for use in drug delivery, sensors, tissue engineering, molecular imprinting, and other areas. This reference begins by explaining the fundamentals of supramolecular polymers; it progresses to cover poly 606 $aBiomimetic polymers 606 $aMolecular recognition 606 $aSupramolecular chemistry 615 0$aBiomimetic polymers. 615 0$aMolecular recognition. 615 0$aSupramolecular chemistry. 676 $a547 676 $a547.1226 701 $aRotello$b Vincent M$01691118 701 $aThayumanavan$b S$g(Sankaran)$01691119 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830923403321 996 $aMolecular recognition and polymers$94067283 997 $aUNINA